Monocyclopentadienyl titanium(IV) alkyl xanthate complexes

Titanium(IV) alkyl xanthates of the types CpTi(S₂COR)Cl₂, CpTi(S₂COR)₂Cl and CpTi(S₂COR)₃, where R = CH₃, C₂H₅, C₃H₇, C₄H₉ and C₅H₁₁, have been prepared by the reaction of monocyclopentadienyl titanium(IV) trichloride with potassium alkyl xanthates in anhydrous dichloromethane. Conductance and infrared studies suggest that these complexes are non-electrolytes in which all of the xanthate ligands are bidentate. Proton nmr spectra of these complexes indicate that there is rapid rotation of the cyclopentadienyl ring about the metal-ring axis and for the CpTi(S₂COR)₃ complexes non-equivalence of the alkylxanthate ligands was observed.     

A class of exact solutions and physical behaviour of magnetic field lines in plasma column

Using hodograph and Legendre transformation functions the basic equations are recast in terms of this function, and the conditions which this function should satisfy are stated. Several applications of this method are considered, and the geometry of magnetic field lines is discussed.     

Microestimation of explosives present in different compositions

Summary High explosives having the sameR _f values on a thin-layer chromatogram and difficult to separate are readily resolved as their coloured -complexes with aromatic amines. After liberation from their complexes on the plate, up to 1.5 g of the explosives can be conveniently estimated at their characteristic absorption maxima.

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Zusammenfassung Hochexplosive Substanzen mit gleichenR _f -Werten auf Dünnschichtchromatogrammen, die sich schlecht trennen lassen, werden als gefärbte -Komplexe mit aromatischen Aminen gut voneinander getrennt. Nach Freisetzung aus den Komplexen auf der Platte können bis zu 1,5 g der Explosivstoffe bei ihrem charakteristischen Absorptionsmaximum auf übliche Weise bestimmt werden.

     

Fourier-transform infrared spectroscopic studies of dithia tetraphenylporphine

We present here infrared absorption spectra of dithia tetraphenylporphine and its cation in the 450–1600 and 2900–3400 cm⁻¹ regions. Most of the allowed IR bands are observed in pairs due to overallD _2h point group symmetry of the molecule. The observed bands have been assigned to the porphyrin skeleton and phenyl ring modes. Some weak bands, which are forbidden underD _2h , also appear in the spectra due to the distortion of the molecule from planarity-caused by the out-of-plane positioned N and S atoms. Increased intensity of some phenyl ring bands compared to free-base tetraphenylporphine is explained on the basis of rotation of phenyl rings towards the mean molecular plane. Contrary to the point group symmetry of cation of dithia tetraphenylporphine, certain bands are observed to be degenerate due to identical bonding arrangements in pyrrole rings of the cation     

Decay instability in a plasma channel

Near the critical layer, a large-amplitude laser beam creates a transverse plasma channel due to the ponderomotive force. The axis of the channel is normal to the ambient density gradient. Inside the channel, the laser beam decays into counter-propagating ion acoustic and Langmuir waves. A nonlocal theory of the process is developed for a parabolic density profile. The growth rate of the instability is significantly reduced due to the nonlocal effects     

Electron impact optical excitation of helium-like ions in Coulomb-Glauber approximation

The Coulomb-Glauber approximation is applied to evaluate the electron-impact excitation integrated cross sections for 1¹ S —n ¹ P (n=2, 3) transitions in helium-like ions, C⁴⁺, N⁵⁺, O⁶⁺ and Ne⁸⁺. The results are presented in terms of scaled collision strengthn ³ Z ² k _i ² σ and scaled integrated cross-sectionZ ⁴σ. Our values when compared with other available theoretical results are found to be larger than the Coulomb-Born and distorted wave polarised orbital (DWPO) values.     

A comparison between microscopic and empirical estimates of the density dependence of effective interactions

The effective interaction W which was recently deduced empirically from saturation considerations as an addition to the Sussex matrix elements is compared with earlier estimates of corrections arising from an assumed short-range repulsion and from the tensor force in second order.     

Self distortion of a Gaussian electromagnetic pulse in a plasma

On the basis of perturbation theory, the phenomenon of nonlinear self distortion of an electromagnetic pulse (Gaussian in time) in a collisional plasma has been studied. The nonlinearity appears through the modulation of electron collision frequency by the power absorption from the wave. At moderate energies of the pulse, considerable distortion in the amplitude envelope has been predicted.     

Phonon spectrum and Kohn anomaly in platinum

The phonon frequencies of platinum are calculated using a model potential approach. The results are in fair agreement with the experimental data but do not show any Kohn anomaly or any kink, as revealed experimentally. The magnitude of the anomaly has been theoretically estimated and comes out to be very small.