Biosensors based on cholinesterase inhibition for insecticides, nerve agents and aflatoxin B1 detection (review)

The present review reports the research carried out during last 9 years on biosensors based on cholinesterase inhibition for nerve agents, organophosphorus and carbammic insecticides, and aflatoxin B₁ detection. Relative applications in environmental and food areas are also reported. Special attention is paid to the optimization of parameters such as enzyme immobilization, substrate concentration, and incubation time in the case of reversible inhibition by aflatoxin B₁ or irreversible inhibition by organophosphorus and carbamic insecticides, and nerve agents in order to optimize and improve the analytical performances of the biosensor. Evaluation of selectivity of the system is also discussed.     

耐盐吸附树脂对增塑剂DIBP生产废水预处理的研究

采用耐盐吸附树脂NDA-66预处理增塑剂DIBP生产废水,研究了不同吸附剂对DIBP生产废水中主要污染物邻苯二甲酸的吸附脱附效果。实验结果表明,5种吸附剂中,NDA-66树脂对邻苯二甲酸处理效果最好,且符合Freundlich方程和Langmuir方程;动态吸附脱附过程中,单柱吸附量为7BV,最佳流速为1.5BV/h,最佳脱附剂为1BV 8%Na OH+2BV蒸馏水,温度为328K,脱附率能达到99%以上;放大实验过程中,NDA-66耐盐吸附树脂对增塑剂DIBP生产废水中邻苯二甲酸吸附稳定性较好。     

On von Neumann regular elements in <Emphasis Type="Italic">f</Emphasis>-rings

Let B be an Archimedean reduced f-ring. A positive element \({\omega}\) in B is said to satisfy the property \({(\ast)}\) if for every f-ring A with identity e and every \({\ell}\)-group homomorphism \({\gamma : A \rightarrow B}\) with \({\gamma(e) = \omega}\), there exists a unique \({\ell}\)-ring homomorphism \({\rho: B \rightarrow B}\) such that \({\gamma = \omega \rho}\) and \({\rho(e)^{\perp \perp} = \omega^{\perp \perp}}\). Boulabiar and Hager proved that any (positive) von Neumann regular element in B satisfies the property \({(\ast)}\) and proved that the converse holds in the C(X)-case. In this regard, they asked about this converse in the general case. Our main purpose in this note is to prove, via a counter-example, that the converse in question fails in general. In addition, we shall take the opportunity to extend the direct result obtained by Boulabiar and Hager, and to get the C(X)-case we were talking about in an easier way.     

Independent components analysis coupled with 3D-front-face fluorescence spectroscopy to study the interaction between plastic food packaging and olive oil

Olive oil is one of the most valued sources of fats in the Mediterranean diet. Its storage was generally done using glass or metallic packaging materials. Nowadays, plastic packaging has gained worldwide spread for the storage of olive oil. However, plastics are not inert and interaction phenomena may occur between packaging materials and olive oil. In this study, extra virgin olive oil samples were submitted to accelerated interaction conditions, in contact with polypropylene (PP) and polylactide (PLA) plastic packaging materials. 3D-front-face fluorescence spectroscopy, being a simple, fast and non destructive analytical technique, was used to study this interaction. Independent components analysis (ICA) was used to analyze raw 3D-front-face fluorescence spectra of olive oil. ICA was able to highlight a probable effect of a migration of substances with antioxidant activity. The signals extracted by ICA corresponded to natural olive oil fluorophores (tocopherols and polyphenols) as well as newly formed ones which were tentatively identified as fluorescent oxidation products. Based on the extracted fluorescent signals, olive oil in contact with plastics had slower aging rates in comparison with reference oils. Peroxide and free acidity values validated the results obtained by ICA, related to olive oil oxidation rates. Sorbed olive oil in plastic was also quantified given that this sorption could induce a swelling of the polymer thus promoting migration.     

DBU-catalyzed transprotection of N-Fmoc-cysteine di- and tripeptides into S-Fm-cysteine di- and tripeptides

The transprotection of N-Fmoc-cysteine containing di- and tripeptides possessing a free SH group to produce the corresponding S-Fm-cysteine di- and tripeptides bearing a free amino group is accomplished efficiently with DBU in dry THF. The N-Fmoc to S-Fm transformation mechanism is discussed. S-Fm-Cysteine di- and tripeptides readily form amide bonds on coupling with N-(Pg-α-aminoacyl)benzotriazoles and N-(Pg-α-dipeptidoyl)benzotriazoles to give larger peptides.     

Rational solutions of the Diophantine equations $$f(x)^2 \pm f(y)^2=z^2$$ f ( x ) 2 ± f ( y ) 2 = z 2

Periodica Mathematica Hungarica - We discuss the rational solutions of the Diophantine equations $$f(x)^2 \pm f(y)^2=z^2$$ . This problem can be solved either by the theory of elliptic curves or by...     

A note on random walk in random scenery

We consider a random walk in random scenery {Xn=η(S₀)+?+η(Sn),n∈N}, where a centered walk {Sn,n∈N} is independent of the scenery {η(x),x∈Zd}, consisting of symmetric i.i.d. with tail distribution P(η(x)>t)∼exp(−cαtα), with 1?α<d/2. We study the probability, when averaged over both randomness, that {Xn>ny} for y>0, and n large. In this note, we show that the large deviation estimate is of order exp(−ca(ny)), with a=α/(α+1).     

Graph-theoretical methods in general function theoryThéorie des graphes dans la théorie generale des fonctions

Consider two maps f and g from a set E into a set F such that f(x)≠g(x) for every x in E. What is the maximal cardinal of a subset A of E such that the images of the restriction of f and g to A are disjoint? Mekler, Pelletier and Taylor have shown that it is card(E) when the set E is infinite; in the finite case, we have proved that it is greater than or equal to card(E)/4. In this paper, using graph theoretical technics, we find these results as a direct application of a lemma of Erdös. Moreover, we show that if $\text{E=F=}\text{R}$, then there exists a countable partition {E_n}_n?1 of $\text{R}$ such that f(E_n)∩g(E_n)=φ, for every n?1. To cite this article: A. El Sahili, C. R. Acad. Sci. Paris, Ser. I 335 (2002) 859–861.     

A finite-element approach in stream-tube method for solving fluid and solid mechanics problems

This paper presents a theoretical formulation in which the stream-tube method (STM) is examined through a variational approach for solving solid strain and fluid flow problems with finite elements. The analysis considers a reference domain, used as computational domain, related to the physical domain by an unknown transformation function to be determined numerically. Mass conservation is automatically verified by STM. The variational approach leads to eliminate the pressure in fluid problems and avoids to set up a mixed displacement–pressure procedure in the case of incompressible solids. Examples are given for fluid flows, applications and comparisons are also provided in the bending problem in elasticity.     

Ion conductive characteristics of cross-linked network polysiloxane-based solid polymer electrolytes

A series of cross-linked network polysiloxanes containing oligoethylene oxide units, (OCH₂CH₂)_n, as internal free chains have been synthesized by performing hydrosilylation of partially PEO-substituted polysiloxane precursor with , ω-diallyl terminated poly(ethylene glycol). The polymer electrolytes were formed by complexing with LiN(CF₃SO₂)₂ electrolyte salt and exhibited superior conductive property. The σ_RT of the network polymer electrolytes is in the range of 2.50×10⁻⁵ to 1.62×10⁻⁴ S/cm and depends on the cross-linking density (in terms of Si–H amount of the siloxane precursor), repeating unit number of internal oligoethylene oxide and chain length of the cross-linker. The significant enhancement of the conductivity was observed when low molecular weight dimethyl poly(ethylene glycol) was added as plasticizer. The temperature dependence of the ionic conductivity was also studied, following the Vogel–Tamman–Fulcher (VTF) equation.