全文获取类型
收费全文 | 287篇 |
免费 | 13篇 |
专业分类
化学 | 131篇 |
晶体学 | 2篇 |
力学 | 7篇 |
数学 | 60篇 |
物理学 | 100篇 |
出版年
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 3篇 |
2020年 | 9篇 |
2019年 | 6篇 |
2018年 | 8篇 |
2017年 | 9篇 |
2016年 | 15篇 |
2015年 | 10篇 |
2014年 | 5篇 |
2013年 | 17篇 |
2012年 | 6篇 |
2011年 | 20篇 |
2010年 | 14篇 |
2009年 | 12篇 |
2008年 | 21篇 |
2007年 | 14篇 |
2006年 | 16篇 |
2005年 | 13篇 |
2004年 | 8篇 |
2003年 | 9篇 |
2002年 | 5篇 |
2001年 | 10篇 |
2000年 | 9篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 2篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 3篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1974年 | 2篇 |
1971年 | 1篇 |
1970年 | 2篇 |
排序方式: 共有300条查询结果,搜索用时 15 毫秒
71.
Semanur Parlayan Aysel Başoğlu Yasemin Göbel Miraç Ocak Hakan Alp Halit Kantekin Ümmühan Ocak 《Journal of inclusion phenomena and macrocyclic chemistry》2010,67(3-4):451-460
A new 14-membered crown ether with nitrogen–sulfur donor atom carrying two anthryl groups was designed and synthesized by the reaction of the corresponding macrocyclic compound and 9-(chloromethyl) anthracene. The influence of metal cations such as Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ on the spectroscopic properties of the ligand was investigated in acetonitrile–dioxane solution (1/1) by means of absorption and emission spectrometry. The results of spectrophotometric titration experiments disclosed the complexation stoichiometry and complex stability constant of the novel ligand with Fe2+, Fe3+, Al3+, Cd2+, Cu2+, Zn2+, Pb2+ and Hg2+ cations. Absorption spectra show isobestic points in the spectrophotometric titration of these cations. The presence of excess of Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ cations caused an enhancement of anthryl fluorescence. Especially, the enhancement in case of the interaction of Hg2+ and Al3+ cations with the ligand was pronounced. 相似文献
72.
Semanur Parlayan Aysel Başoğlu Miraç Ocak Hakan Alp Halit Kantekin Ümmühan Ocak 《Journal of inclusion phenomena and macrocyclic chemistry》2010,67(1-2):133-140
A new crown ether carrying two anthryl groups with nitrogen–sulfur donor atom was designed and synthesized by the reaction of the corresponding macrocyclic compound and 9-chloromethyl anthracene. The influence of metal cations such as Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ on the spectroscopic properties of the ligand was investigated in acetonitrile–tetrahydofuran solution (1/1) by means of absorption and emission spectrometry. Absorption spectra show isosbestic points in the spectrophotometric titration of Fe2+, Fe3+, Al3+, Cu2+ and Hg2+. The results of spectrophotometric titration experiments disclosed the complexation stoichiometry and complex stability constant of the novel ligand with Fe2+, Fe3+, Al3+, Cu2+and Hg2+cations. The presence of excess amounts of Al3+, Zn2+, Fe2+, Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Cd2+, Hg2+ and Pb2+ cations caused an enhancement of anthryl fluorescence. The ligand showed good sensitivity for Zn2+ with respect to other metal cations with linear range and detection limit of 1.4 × 10?7 to 4.1 × 10?6 M and 1.0 × 10?8 M respectively. 相似文献
73.
Kathryn R. Rebecchi Jamie L. Wenke Eden P. Go Heather Desaire 《Journal of the American Society for Mass Spectrometry》2009,20(6):1048-1059
We demonstrate herein a method for quantifying glycosylation changes on glycoproteins. This novel method uses MS data of characterized
glycopeptides to analyze glycosylation profiles, and several quality control tests were done to demonstrate that the method
is reproducible, robust, applicable to different types of glycoproteins, and tolerant of instrumental variability during ionization
of the analytes. This method is unique in that it is the first label-free quantitative method specifically designed for glycopeptide
analysis. It can be used to monitor changes in glycosylation in a glycosylation site-specific manner on a single glycoprotein,
or it can be used to quantify glycosylation in a glycoprotein mixture. During mixture analysis, the method can discriminate
between changes in glycosylation of a given protein, and changes in the glycoprotein’s concentration in the mixture. This
method is useful for quantitative analyses in biochemical studies of glycoproteins, where changes in glycosylation composition
can be linked to functional differences; it could also be implemented in the pharmaceutical industry, where glycosylation
profiles of glycoprotein-based therapeutics must be quantified. Finally, quantification of glycopeptides is an important aspect
of glycopeptide-based biomarker discovery, and our quantitative approach could be a valuable asset to this field as well,
provided the compositions of the glycopeptides to be quantified are identifiable using other methods. 相似文献
74.
P. Jameson Graber Alpár R. Mészáros 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2018,35(6):1557-1576
In this paper we obtain Sobolev estimates for weak solutions of first order variational Mean Field Game systems with coupling terms that are local functions of the density variable. Under some coercivity conditions on the coupling, we obtain first order Sobolev estimates for the density variable, while under similar coercivity conditions on the Hamiltonian we obtain second order Sobolev estimates for the value function. These results are valid both for stationary and time-dependent problems. In the latter case the estimates are fully global in time, thus we resolve a question which was left open in [23]. Our methods apply to a large class of Hamiltonians and coupling functions. 相似文献
75.
Alp H. Alidedeoglu Adam W. York Dale A. Rosado Charles L. McCormick Sarah E. Morgan 《Journal of polymer science. Part A, Polymer chemistry》2010,48(14):3052-3061
The synthesis of well‐defined carboxylic acid‐functionalized glycopolymers prepared via one‐step postpolymerization modification of poly(N‐[3‐aminopropyl] methacrylamide) (PAPMA), a water‐soluble primary amine methacrylamide, in aqueous medium is demonstrated. PAPMA was first polymerized via aqueous reversible addition‐fragmentation chain transfer polymerization in aqueous buffer using 4‐cyanopentanoic acid dithiobenzoate as the chain transfer agent and 4,4′‐azobis(4‐cyanovaleric acid) (V‐501) as the initiator at 70 °C. The resulting well‐defined PAPMA was then conjugated with D ‐glucuronic acid sodium salt through reductive amination in alkaline medium (pH 8.5) at 45 °C. The successful bioconjugation was proven through proton (1H) and carbon (13C) nuclear magnetic resonance spectroscopy and matrix‐assisted laser desorption/ionization time of flight mass spectrometry analysis, which indicated near quantitative conversion. A similar bioconjugation reaction was conducted with poly(2‐aminoethyl methacrylate) (PAEMA) and poly(2‐aminoethyl methacrylate‐b‐poly(N‐[2‐hydroxypropyl]methacrylamide) (PAEMA‐b‐PHPMA). For the PAEMA homopolymers and block copolymers, however, lower conversion was obtained, most likely because of degradation reactions of PAEMA in alkaline medium. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3052–3061, 2010 相似文献
76.
Svetlana K. Eden Angel Q. An Jeffrey Horner Cathy A. Jenkins Theresa A. Scott 《Computational Statistics》2010,25(4):587-601
Graphical illustration and exploration of atmospheric data, like those from the 2006 ASA Data Exposition, is challenging.
We chose to employ a two-step process, which consisted of exploring the presented data (1) from a ‘global’ view by simultaneously
displaying the spatial and temporal components of individual variables in the data set using a geographic grid of polar coordinate
plots or circular histograms that incorporated elevation as a background color, and (2) from a ‘local’ view by displaying
the relationships between multiple variables at specific geographic locations and/or time points/periods (selected via step
1) using scatterplot matrices. 相似文献
77.
78.
79.
80.
Hakan Alp Zekeriya Biyiklioğlu Gülsev Dilber ÜmmÜhan Ocak Aysel Marap Halit Kantekin 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(3-4):283-288
Synthetic procedures for new N2S4- and N2S5-donor macrocycles (2 and 4) were given. The ligands were prepared by the reaction of NaBH4 with the appropriate macrocyclic diamide in the presence of boron trifluoride ethyl etherate in dry tetrahydrofuran (THF).
Solvent extraction method was used to evaluate metal-ion binding properties of the new ligands. The solvent extraction experiments
suggested that the reduced macrocycles have Ag+ and Hg2+ selectivities compared to Pb2+, Co2+, Zn2+, Ni2+, Cu2+, Mn2+ and Cd2+ ions. The extraction constants (log K
ex) and complex compositions were determined for Ag+ and Hg2+ complex of compound (4). 相似文献