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991.
J. A. Van Allan J. F. Stenberg G. A. Reynolds 《Journal of heterocyclic chemistry》1979,16(8):1663-1665
Certain chromones and benzoxanthones were prepared by heating at 300–325° a mixture of 1-or 2-naphthol with either phenyl o-hydroxybenzoate or o-hydroxynaphthoate or a β-ketoester. The yields and purity of the products are superior to those obtained by the published procedures. 相似文献
992.
993.
994.
The synthesis of 5-(6-mercaptohexyloxy)-1,3-dihydroxybenzene and the formation of a self-assembled monolayer on polycrystalline gold using this compound are described. Methyltrichlorosilane and (tridecafluoro-1,1,2,2-tetrahydrooctyl)trichlorosilane were attached to the 3,5-dihydroxyphenyl terminus of the monolayer. The modified surfaces were studied by contact angle measurement, XPS, and cyclic voltammetry. High contact angles of 119 degrees -128 degrees were observed for the semifluoroalkylsilyl-functionalized monolayer. These high contact angles were maintained after subjecting the surface to, e.g., boiling in water or heating in air to 300 degrees C. Characterization of the silane-modified monolayers by XPS indicated more than one layer of silane present at the top of the monolayer. The thickness was reduced after boiling the cross-linked monolayers in H(2)O, however, maintaining high contact angles. Cyclic voltammetry studies revealed that the semifluoroalkylsilyl-functionalized surface showed a higher blocking capability and a higher electrochemical stability than the parent monolayer. 相似文献
995.
A new and potentially highly generalizable technique for synthesizing molecular fragments of binary solids is demonstrated through application to selected transition metal chalcogenides. Employing a metal atom reactor, the solids are evaporated with a tungsten heating boat, and the resulting vapor is co-condensed with triethylphosphine. Major cluster products identified from a survey of first-row transition metal sulfides include the known species Cr6S8(PEt3)6, Co6S8(PEt3)6, and Cu12S6(PEt3)8, as well as the unprecedented species Fe4S4(PBun3)4, Ni4S4(PEt3)8, and Cu6S4(PEt3)4. Reactions utilizing Cu2Se resulted in the much larger clusters Cu26Se13(PEt3)14 and Cu70Se35(PEt3)21. The core of the former has a Th-symmetry structure featuring a body-centered icosahedron of Se2- anions, while the latter adopts a triangular structure based on three hexagonal closest packed layers of Se2- anions. In both cases, the Cu+ cations occupy distorted tetrahedral or trigonal planar sites similar to those encountered in Cu2Se; however, emergence of the face-centered cubic anion lattice of the bulk solid is not yet apparent at these cluster sizes. 相似文献
996.
Price JR Fainerman-Melnikova M Fenton RR Gloe K Lindoy LF Rambusch T Skelton BW Turner P White AH Wichmann K 《Dalton transactions (Cambridge, England : 2003)》2004,(21):3715-3726
Structure-function relationships underlying the interaction of progressively N-benzylated N(4)O(2)-donor macrocycles with cobalt(II), nickel(II), copper(II), zinc(II), cadmium(II), silver(I) and lead(II) have been probed using a range of techniques that include X-ray diffraction, DFT computations, solvent extraction, potentiometric stability constant determinations and competitive membrane transport experiments. Collectively, the results indicate that N-benzylation of the secondary amine donor groups of the parent macrocyclic ring results in an enhanced tendency towards selectivity for silver(I) relative to the other six metals investigated. The observed behaviour serves as additional exemplification of the previously proposed concept of selective 'detuning' as a mechanism for metal ion discrimination. 相似文献
997.
[reaction: see text] A new asymmetric halo aldol reaction has been developed by reacting cyclopropyl carbonyl derived enolates with aldehydes. The absolute structure was unambiguously confirmed by X-ray structural analysis. Eight examples were reported with good yields and up to complete control of diastereomeric excesses. These halo aldol products have been readily cyclized in the presence of weak bases to produce chiral 2,3-disubstituted tetrahydrofuran derivatives in good yield without any observed epimerization. 相似文献
998.
Akdas H Graf E Hosseini MW De Cian A Bilyk A Skelton BW Koutsantonis GA Murray I Harrowfield JM White AH 《Chemical communications (Cambridge, England)》2002,(10):1042-1043
Tetra- and hexa-nuclear mercury(II) complexes have been obtained from tetrathiacalix[4]arene and tetramercaptotetrathiacalix[4]arene, respectively, and structurally characterised in the solid state; the complexes provide new digonal and trigonal receptors of the koiland type. 相似文献
999.
Let Y be a compact Riemannian manifold. Let X be locally compact and paracompact. It is shown that every uniform homotopy and every homotopy of bounded width from X to Y may be approximated by a Lipschitz homotopy. Applications to the study of uniform homotopy and homotopies of bounded width are given. 相似文献
1000.
Allan Línek 《Czechoslovak Journal of Physics》1954,4(1):26-32
The paper deals with a method for finding the temperature factor when determining crystal structures. 相似文献