Solvent Effects on the piezochromism of molybdenum(IV) and tungsten(IV) anions [M(CN)3O(diimine)]−

Solvatochromism of the [Mo(CN)₃O(phen)]⁻ ion has been studied. Solvent effects on pressure dependence (up to 1.25 kbar) of wavelengths of maximum absorption for charge-transfer bands of several molybdenum(IV) and tungsten(IV) complexes, [M(CN)₃O(diimine)]⁻ (M = Mo or W), are described. The effects of applied pressure are larger for less polar unstructured solvents than for highly polar hydrogen-bonded solvents. This revised version was published online in June 2006 with corrections to the Cover Date.     

Study of Lipophilicity and Application of Selected Structural Descriptors in QSAR Analysis of Nicotinic Acid Derivatives. Investigations on RP18WF254 Plates. Part II

JPC – Journal of Planar Chromatography – Modern TLC - Nicotinic acid (NAC) and its derivatives methyl nicotinate (MN), ethyl nicotinate (EN), isopropyl nicotinate (IPN), butyl...     

Surface-templated formation of protein microfibril arrays.

Ordered arrays of collagen microfibrils form rapidly and spontaneously from a solution of monomers deposited onto a mica substrate. These arrays are well-ordered and apparently continuous over the entire substrate. Correlated atomic force microscope images and Laué diffraction patterns indicate that the protein alignment and microfibril formation is controlled by the crystal orientation of the mica substrate rather than fluid flow or drying effects. This surface-induced mechanism allows for immediate, robust, and reproducible pattern formation.     

Invariant sets for a class of perturbed differential equations of retarded type

LetX be a Banach space and leta, b, q be real numbers such thata<b,q>0. Denote byD a locally closed subset ofX. A necessary and sufficient condition for the existence of a mild solutionu∈C([a−q, b ₁],X),a<b ₁<b, to the differential equationdu(t)/dt=Au(t)+f(t, u _t), such thatu:[a,b ₁]→D, u _a=ϕ is given. The linear operatorA is the generator of aC ₀ semigroupT(t), t≧0, withT(t) compact fort>0,f: [a, b)×C([−q,0],D _λ)→X is continuous and ϕ∈C([−q,0],D _λ) with ϕ(0)∈D. D _λ is a neighbourhood ofD. Applications to parabolic partial differential equations with retarded argument are given.     

Photostability and the yield of triplet state generation of bacteriochlorophyll c and bacteriopheophytin c in solution

The paper deals with some fast and slow processes of excitation energy deactivation in bacteriochlorophyll c and bacteriopheophytin c. The experiments were carried out in the air, and in oxygen or nitrogen atmosphere at different temperatures. The parameters such as fluorescence yield, the yield of triplet state generation and photostability were estimated. On the basis of these parameters an attempt was made to preliminary select the pigments best suited for medical applications. It seems that the photosensitive and highly fluorescent bacteriochlorophyll c could be used as a fluorescence probe for diagnosis, whereas its derivative without the magnesium ion is better suited for the photochemical reactions occurring during therapeutic treatment.     

Counting alternating knots by genus

It is shown that the number of alternating knots of given genus g>1 grows as a polynomial of degree 6g−4 in the crossing number. The leading coefficient of the polynomial, which depends on the parity of the crossing number, is related to planar trivalent graphs with a Bieulerian path. The rate of growth of the number of such graphs is estimated.     

Triangular hyperbolic buildings

We construct triangular hyperbolic polyhedra whose links are generalized 4-gons. The universal cover of such a polyhedron is a hyperbolic building, whose apartments are hyperbolic planes tessellated by regular triangles with angles $\pi /4$. The fundamental groups of the polyhedra are hyperbolic, torsion free, with property (T). To cite this article: R. Kangaslampi, A. Vdovina, C. R. Acad. Sci. Paris, Ser. I 342 (2006).     

Copper-coated microsprayer interface for on-line sheathless capillary electrophoresis electrospray mass spectrometry of carbohydrates

A sturdy home-built sheathless CE/ESI-QTOF-MS system was developed and optimized for carbohydrate analysis. The interface and employed methodology provided a simple analytical solution to laborious CE/MS interfacing methods and to problems in characterization of complex carbohydrate mixtures that require high-resolution separation of the components. The CE/ESI interface, feasible in any MS laboratory, consists of a one-piece CE column having the CE terminus in-laboratory shaped as a microsprayer and coated with copper. The CE microsprayer was inserted into an in-house made stainless steel clenching device and the whole assembly was mounted onto a quadrupole TOF mass spectrometer. The analytical potential of the interface in terms of suitability, microsprayer performance, copper coat durability, ionization efficiency, spray stability, and sensitivity was tested first on a simple mixture of standard saccharides, which were separated, resolved, and detected with high separation efficiency. The approach was next assessed for the screening of a biological sample, a complex mixture of O-glycosylated sialylated amino acids from urine of a patient suffering from Schindler disease. Preliminary data allow this method to be considered as one of general applicability in structural glycobiology and glycomics and easy to be implemented for proteomic surveys as well.     

Heat conduction in transversally graded laminates with non-uniform microstructure

Two-component laminates made of conductors distributed non-periodically as laminas along one direction are considered in this note. The macroscopic properties of these laminates are described by continuous slowly-varying functions across laminas. In order to analyse heat conduction, the approach, called the tolerance modelling, is used. The aim of this note is to use averaged equations of the tolerance model for transversally graded laminates to analyse stationary heat conduction across laminas. (© 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)