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11.
García-Orozco I López-Cortés JG Ortega-Alfaro MC Toscano RA Penieres-Carrillo G Alvarez-Toledano C 《Inorganic chemistry》2004,43(26):8572-8576
The paper describes the synthesis and structural characterization of four novel copper(I) complexes [CuL(PPh(3))(2)] (L = 3-hydroxy-3-(p-R-phenyl)-2-propenedithioate). In addition, a tautomeric equilibrium in solution was found and Hammett correlations with (13)C NMR parameters were studied. The structure of one complex was fully established by X-ray diffraction analysis. 相似文献
12.
Bonini BF Comes-Franchini M Mazzanti G Ricci A Sala M 《The Journal of organic chemistry》1996,61(21):7242-7243
13.
Alvisi D Blart E Bonini BF Mazzanti G Ricci A Zani P 《The Journal of organic chemistry》1996,61(20):7139-7146
The palladium-catalyzed desilylation-arylation of substituted vinylsilanes by p-iodoanisole in the presence of bidentate phosphine ligands is described. Apart from enhancing the rate of the reaction considerably, heteroatom-based functional groups in the vinylsilane moiety have a profound influence on the regiochemistry. A catalytic cycle for the chelation-controlled desilylation-arylation reaction involving five- and six-membered chelate rings is proposed. 相似文献
14.
Lainez A del Burgo P Junquera E Aicart E 《Langmuir : the ACS journal of surfaces and colloids》2004,20(14):5745-5752
Speed of sound, density, conductivity, and fluorescence spectroscopy experiments were run to analyze the mixed aggregation process of a nonionic-cationic surfactant system in aqueous media at 298.15 K. The mixed system comprises a nonionic surfactant, n-octyl-beta-D-glucopyranoside (OBG), and a cationic surfactant, tetradecyltrimethylammonium bromide (C14TAB), with 8 and 14 carbon atoms on the hydrophobic tails, respectively. From these data, the total and partial critical micellar concentrations, the total and partial aggregation numbers, apparent molar volumes and isentropic compressibilities, hydration numbers, and the corresponding changes in the latest properties due to the mixed aggregation process were determined. Pure and mixed micelles were analyzed from a geometrical point of view by determining the packing parameter of the aggregates. Furthermore, the experimental characterization of both the monomeric and micellar phases was completed with a theoretical study of the mixed micellization phenomena studied herein, by means of some of the most relevant theoretical models. 相似文献
15.
Numerical solution of delay differential equations by uniform corrections to an implicit Runge-Kutta method 总被引:3,自引:0,他引:3
Summary In this paper we develop a class of numerical methods to approximate the solutions of delay differential equations. They are essentially based on a modified version, in a predictor-corrector mode, of the one-step collocation method atn Gaussian points. These methods, applied to ODE's, provide a continuous approximate solution which is accurate of order 2n at the nodes and of ordern+1 uniformly in the whole interval. In order to extend the methods to delay differential equations, the uniform accuracy is raised to the order 2n by some a posteriori corrections. Numerical tests and comparisons with other methods are made on real-life problems.This work was supported by CNR within the Progetto Finalizzato Informatica-Sottopr. P1-SOFMAT 相似文献
16.
The dynamic behaviour of [Pt(/gh3-allyl){P(cyclohexyl)3}2]+[PF6]- has been reinvestigated, and the earlier interpretation of restricted rotation about the Pt—P endorsed. The activation parameters were obtained. [Pt(/gh3-allyl)(PPri3)2]+[PF6]- behaves similarly, while it has not prove possible to stop the rotation in [Pt(/gh3-allyl){P(CH2Ph)3}2]+[PF6]-. 相似文献
17.
Marchante-Gayón JM González JM Fernández ML Blanco E Sanz-Medel A 《Analytical and bioanalytical chemistry》1996,355(5-6):615-622
A novel High Performance Liquid Chromatography (HPLC) method for the separation of selenium species with specific detection by off-line Electrothermal Atomization Atomic Absorption Spectrometry (ETAAS) or on-line focused microwave digestion (MW) Hydride Generation Atomic Absorption Spectrometry (HG-AAS) is described. Vesicular mobile phases of the cationic surfactant didodecyldimethylammonium bromide (DDAB) have been evaluated for the liquid chromatographic separation of inorganic selenium (selenite and selenate) and different selenoaminoacids (selenocystine, selenomethionine and selenoethionine) on a C(18) reversed-phase column modified by DDAB molecules. The effects of different parameters (pH, buffer and vesicle concentrations) of the mobile phase on the retention times have been determined. The detection limit for selenium with the proposed off-line HPLC-ETAAS method has been found to be 5 microg/L of Se. The detection limit using HPLC-"on line" focused microwave digestion-HG-AAS has been found to be 1 microg/L of Se, with a precision (repeatability) better than +/- 5%. The latter proved to be an exceptional on-line real-time chromatographic detector for selenium speciation purposes. 相似文献
18.
Rodríguez-Cea A de la Campa MR Sanz-Medel A 《Analytical and bioanalytical chemistry》2005,381(2):388-393
Cytochromes P-450 are members of a superfamily of hemoproteins involved in the oxidative metabolism of various physiological and xenobiotic compounds in eukaryotes and prokaryotes. The multiplicity of this group of enzymes has been widely studied by chromatographic techniques, mainly high-performance liquid chromatography (HPLC). Because these enzymes are membrane-bound proteins, sample preparation for chromatographic separation of P-450 enzymes requires a solubilization step. The sample-preparation procedures are critical, because detergents affect not only the efficiency of protein solubilization but also their further chromatographic resolution. Trout liver microsomes have been taken here as a model sample to investigate iron speciation in cytochrome P-450. Trouts were treated intraperitoneally with -naphthoflavone, a potent inducer of some P-450 enzymes, and a microsomal suspension containing 7.4±0.1 nmol mL–1 P-450 enzymes was obtained by ultracentrifugation. Lubrol PX was selected as detergent for solubilization, resulting in about 90% solubilization recovery. The solubilized cytochromes P-450 were further separated by AE–FPLC, with UV detection, or coupled to ICP–MS with an octapole reaction system, ICP–(ORS)MS (monitoring Fe signals at masses 54, 56, and 57). A sampling procedure and chromatographic conditions are developed and were successfully applied to iron speciation in trout liver P-450 enzymes. ICP–(ORS)MS detection of P-450 enzymes is Fe-specific and so will give accurate information on the prosthetic group of the protein, which can constitute an advantageous alternative to classical methods for detection of these hemoproteins. 相似文献
19.
Surface tensions (sigma) for [1,3-dioxolane+methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and 1-pentanol] and excess molar volumes (v(E)) for [1,3-dioxolane+methanol, ethanol, 1-propanol, 2-propanol, and 2-butanol] at the temperature 298.15 K and normal atmospheric pressure have been determined as a function of mole fractions. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures. In order to analyze the surface tension behavior, the extended Langmuir (EL) model was used and the results obtained for the systems containing 1,3-dioxolane were compared with those of other formerly published series: [1,4-dioxane+alkanes] and [1,4-dioxane+alcohols]. 相似文献
20.
Blanca San Vicente de la RivaJosé M. Costa-Fernández Wei Jun JinRosario Pereiro Alfredo Sanz-Medel 《Analytica chimica acta》2002,455(2):179-186
A novel method has been developed for the sensitive determination of mercury in aqueous media by room temperature phosphorescence (RTP). The measurement principle is based on the energy transfer (ET) from a phosphor molecule (acting as a donor) to a Hg-sensitive dye (acceptor). To our acknowledgment this is the first RTP method for mercury measurement developed so far. α-Bromonaphthalene (BrN) was selected as the phosphorescent donor molecule (BrN can produce significant RTP emission in aqueous media in a β-cyclodextrin rigid microenvironment without deoxygenation).The absorption spectrum of the complex formed between mercury and the dithizone dye possesses a desirable spectral overlap with the RTP emission spectrum of the donor (BrN), giving rise to a nonradiative ET from the phosphor molecules to the mercury complex. An increase in the concentration of Hg(II) causes an increase on the concentration of the dithizone complex (acceptor) with the subsequent increase of the absorbance and, therefore, resulting in a decrease of the RTP emission. Both, RTP intensities and triplet lifetimes of the BrN decreased with increases on the Hg(II) concentration.Possible interferences present in natural waters, including different cations and anions, which could affect the analytical response, were evaluated and the analytical performance characteristics investigated. The use of phosphorescence measurements (low background noise signals) resulted in an improvement on the sensitivity of the Hg(II) detection higher than five times as compared to the molecular absorption spectrophotometric method for Hg(II) detection based on dithizone as Hg-indicator. A detection limit (D.L.) of 14 ng ml−1 of Hg(II) was obtained by RTP with a precision of ±4.8% for five replicates of 300 ng ml−1 of Hg(II). The usefulness of the method was successfully evaluated by the determination of Hg(II) in spiked natural water samples. 相似文献