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41.
Abe K Abt I Ash WW Aston D Bacchetta N Baird KG Baltay C Band HR Barakat MB Baranko G Bardon O Barklow T Bazarko AO Ben-David R Benvenuti AC Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Cassell R Castaldi R Castro A Cavalli-Sforza M Church E Cohn HO Coller JA Cook V Cotton R Cowan RF Coyne DG D'Oliveira A Damerell CJ Dasu S De Sangro R De Simone P 《Physical review D: Particles and fields》1994,50(9):5580-5590
42.
P. J. Castro J. J. Barroso R. A. Correa 《International Journal of Infrared and Millimeter Waves》1993,14(2):383-395
A study of selective properties of coaxial open cylindrical resonators have been conducted experimentally and compared with theory. The resonator consists of an inner circular cylinder symmetrically located inside an outer weakly irregular open waveguide. Several fundamental TE modes were identified over the range 9 to 17 GHz through measurements of the resonant frequencies and the associated loaded quality factors. It has been verified that the structure and the number of resonant modes are both strongly dependent on the diameter of the coaxial insert. Such an electrodynamical system proves to be useful in guided wave applications requiring, for example, filters, frequency-tunable resonators and devices for analyzing the modal composition of a signal. 相似文献
43.
Abe F Albrow M Amidei D Anway-Wiese C Apollinari G Atac M Auchincloss P Azzi P Baden AR Bacchetta N Badgett W Bailey MW Bamberger A de Barbaro P Barbaro-Galtieri A Barnes VE Barnett BA Bauer G Baumann T Bedeschi F Behrends S Belforte S Bellettini G Bellinger J Benjamin D Benlloch J Bensinger J Beretvas A Berge JP Bertolucci S Biery K Bhadra S Binkley M Bisello D Blair R Blocker C Bodek A Bolognesi V Booth AW Boswell C Brandenburg G Brown D Buckley-Geer E Budd HS Busetto G Byon-Wagner A 《Physical review D: Particles and fields》1993,48(3):998-1008
44.
Abe K Abt I Acton PD Agnew G Ash WW Aston D Bacchetta N Baird KG Baltay C Band HR Baranko G Bardon O Battiston R Bazarko AO Bean A Belcinski RJ Ben-David R Benvenuti AC Biasini M Bienz T Bilei GM Bisello D Blaylock G Bogart JR Bolton T Bower GR Brau JE Breidenbach M Bugg WM Burke D Burnett TH Burrows PN Busza W Calcaterra A Caldwell DO Calloway D Camanzi B Carpinelli M Carr J Cassell R Castaldi R Castro A Cavalli-Sforza M Chadwick GB Chen L Church E Claus R Cohn HO Coller JA Cook V Cotton R 《Physical review letters》1993,71(16):2528-2532
45.
Two methods of determining trace levels of platinum and gold in aqueous solutions with high concents of total dissolved solids were investigated. The first involves preconcentration and separation of the precious metals from the interfering matrix by solvent extraction, followed by graphite furnace atomic absorption spectrometry (GFAAS) with Zeeman effect background correction. The direct determination of Pt and Au in solutions of high ionic strength by GFAAS is not desirable because of interference between elements in the matrix and the analyte, increased imprecision of analysis, greatly increased background absorbance leading to increased detection limits and rapid deterioration of the graphite tube. All the extraction methods for gold examined in this study resulted in decreased imprecision, increased sensitivity and lower background absorbance compared with direct measurements on the aqueous solution. All techniques also exhibited good recoveries (> 8%) and reproducibilities (relative standard deviation < 10%). The highest sensitivities for gold extraction from distilled water were obtained for dibutyl sulfide (DBS)—toluene and the lowest for cyanide—dibutyl ketone. The degree of extraction of Au was, however, dependent on the composition of the solution, indicating that standard and sample matrices should be closely matched even when employing solvent extraction. Solvent extraction was generally less successful for Pt. In order to obtain an acceptable imprecision in the Pt extractions, it was found that the use of SnCl2 as a labilizing agent is essential for most of the techniques investigated.The second method was direct measurement by inductively coupled plasma mass spectrometry (ICP—MS). ICP—MS offers the advantages of a very low detection limit (100 ng l?1 or better) without preconcentration and a large dynamic range. However, severe matrix effects can occur in concentrated solutions. Whereas high concentrations in solution of both sodium perchlorate and sodium chloride decrease the sensitivity, the presence of sulfide and natural organic (fulvic) acid increase the sensitivity for Pt and Au by a factor of up to 4. Sulfate, on the other hand, decreases the sensitivity of ICP-MS for Pt. The method of standard additions or isotope dilution is recommended for routine use to circumvent this problem, especially when the nature of the matrix is unknown or cannot be easily matched in the standards. 相似文献
46.
Sánchez-Moreno MJ Gómez-Coca RB Fernández-Botello A Ochocki J Kotynski A Griesser R Sigel H 《Organic & biomolecular chemistry》2003,1(10):1819-1826
The synthesis of (1H-benzimidazol-2-yl-methyl)phosphonic acid, H2(Bimp)+/-, is described: 2-chloromethylbenzimidazole was reacted with ethylchloroformate to give 1-carboethoxy-2-chloromethylbenzimidazole which was treated with trimethyl phosphite and after hydrolysis with aqueous HBr H2(Bimp)+/- was obtained. In H2(Bimp)+/- one proton is at the N-3 site and the other at the phosphonate group; both acidity constants were determined in aqueous solution by potentiometric pH titrations (25 degrees C; I = 0.1 M, NaNO3) and this furnished the pKa values of 5.37 +/- 0.02 and 7.41 +/- 0.02, respectively. The acidity constant for the release of the primary proton from the P(O)(OH)2 group of H3(Bimp)+ was estimated: pKa = 1.5 +/- 0.2. Moreover, Bimp2- can be further deprotonated at its neutral (N-1/N-3)H site to give the benzimidazolate residue, but this reaction occurs only in strongly alkaline solution (KOH); application of the H_ scale developed by G. Yagil (J. Phys. Chem., 1967, 71, 1034) together with UV spectrophotometric measurements gave pKa = 14.65 +/- 0.12. Comparisons with acidity constants taken from the literature show that this latter pKa value is far too large and this allows the conclusion that an intramolecular hydrogen bond is formed between the (N-1/N-3)H site and the phosphonate group of Bimp2-; the formation degree of this hydrogen-bonded isomer is estimated to be 98 +/- 2%. The general relevance of this and the other results are shortly discussed and the species distribution for the Bimp system in dependence on pH is provided. 相似文献
47.
Vilas-Boas M Freire C de Castro B Christensen PA Hillman AR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2001,7(1):139-150
Electrogenerated polymers based on the nickel(II) complex 2,3-dimethyl-N,N'-bis(salicylidene)butane-2,3-diaminatonickel(II), poly[Ni(saltMe)], were characterised by in situ FTIR and UV/Vis spectroscopy and ex-situ EPR spectroscopy in order to gain insights into film structure, electronic states and charge conduction. The role of the nickel ions during film oxidation was probed by using EPR to study naturally abundant Ni and 61Ni-enriched polymers. The data from all the spectroscopic techniques are consistent, and clearly indicate that polymerisation and redox switching are associated with oxidative ligand based processes; coulometry suggests that one positive charge was delocalised through each monomer unit. EPR provided evidence for the non-direct involvement of the metal in polymer oxidation: the polymer is best described as a polyphenylene-type compound (conducting polymer), rather than an aggregation of nickel complexes (redox polymer), and the main charge carriers are identified as polarons. An explanation for the high electrochemical stability and conductivity of poly[Ni(saltMe)] with respect to that of poly[Ni(salen)] is proposed. based on stereochemical repulsion between monomeric units; this can impose a less compact supramolecular structure on polymers with bulkier substituents. 相似文献
48.
The reactions 4-methylphenyl 4-nitrophenyl carbonate (MPNPC), 4-chlorophenyl 4-nitrophenyl carbonate (CIPNPC), 4-methylphenyl 2,4-dinitrophenyl carbonate (MPDNPC), and 4-chlorophenyl 2,4-dinitrophenyl carbonate (CIPDNPC) with a homogeneous series of phenoxide anions are subjected to a kinetic investigation in aqueous solution (25.0 degrees C, ionic strength 0.2 M (KCI)). Under an excess of phenoxide with respect to the substrate, all of these reactions obey pseudo-first-order kinetics and are first order in phenoxide. The Br?nsted-type plots for the nucleophilic rate constants (k(N)) are linear, with slopes beta = 0.48 (MPNPC), 0.67 (ClPNPC), 0.41 (MPDNPC), and 0.32 (ClPDNPC). The magnitude of these slopes and the absence of a curvature in the Br?nsted plot at pK(a) = 7.1 for the CIPNPC reactions are consistent with concerted mechanisms (one step). The carbonates MPDNPC and ClPDNPC are more reactive than MPNPC and CIPNPC, respectively, toward phenoxide nucleophiles. This can be explained by the presence of a second nitro group in the nucleofuge of the dinitro derivatives, which (i) leaves their carbonyl carbon more positively charged, making them better electrophiles, and (ii) makes 2,4-dinitrophenoxide a better leaving group than 4-nitrophenoxide. The 4-chloro derivatives are more reactive than the corresponding 4-methyl derivatives. This should be due to the greater electron withdrawal of 4-chloro than 4-methyl, which makes the former carbonyl more electrophilic. Comparison of the concerted phenolysis of MPNPC with the stepwise reactions of secondary alicyclic amines with the same substrate indicates that substitution of a secondary alicyclic amine group in a zwitterionic tetrahedral intermediate by a phenoxy group greatly destabilizes the intermediate. An equation is deduced for log k(N) in terms of the basicity of the nucleophile, the nonleaving moiety, and the leaving group. This equation shows that for these reactions, the sensitivity of log k(N) to the basicity of the nonleaving moiety (beta(nlg) = -0.27) is very similar to that of the nucleofuge (beta(lg) = -0.25). 相似文献
49.
Cellulose/antimony(III) oxide composites, Cel/Sb(2)O(3), with oxide loadings of 1.7, 5.4, and 9.2 wt% were prepared by reacting the precursor SbCl(3) reagent with cellulose in dry ethanol solution. The reaction of the Lewis acid and the cellulose fibers occurred at the~amorphous domains of the biopolymer, increasing the crystallinity degree of the composite compared with that of the untreated cellulose. The scanning electron microscopy images and metal mapping for all samples showed that the oxide film layer uniformly covered the fiber surfaces with no detectable agglomerates of the oxide particles. The synchrotron X-ray diffraction patterns indicated that the antimony oxide film was obtained as a crystalline phase with orthorombic structure. The atomic ratios of O/Sb, determined by X-ray photoelectron spectroscopy, indicated that, for Cel/Sb(2)O(3) samples with 9.3 wt% loading, the fiber surface is nearly saturated by the oxide layer. The thermal stability of Cel/Sb(2)O(3) compared to that of untreated cellulose is practically unaffected. Copyright 2000 Academic Press. 相似文献
50.
Ignacio Alfonso Covadonga Astorga Vicente Gotor 《Journal of inclusion phenomena and macrocyclic chemistry》2005,53(1-2):131-137
Electrospray ionization mass espectrometry (ESI-MS) has been used for the study of a cyclam derivative noncovalent interactions.
At acidic pH, diprotonated macrocycle bound to different anionic species were observed. The selectivity shown by competitive
experiments is rationalized with the help of semiempirical theoretical calculations. At basic pH, the base peak corresponded
to the macrocycle-alkaline metal complexes, and again competition experiments showed different binding strength. Finally,
experiments carried out in the presence of transition metal salts allowed the detection of the complexes present in the mixture
and revealed their different kinetic behavior. 相似文献