全文获取类型
收费全文 | 657篇 |
免费 | 18篇 |
国内免费 | 18篇 |
专业分类
化学 | 301篇 |
晶体学 | 5篇 |
力学 | 4篇 |
数学 | 311篇 |
物理学 | 72篇 |
出版年
2023年 | 3篇 |
2022年 | 10篇 |
2021年 | 23篇 |
2020年 | 12篇 |
2019年 | 17篇 |
2018年 | 10篇 |
2017年 | 10篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 25篇 |
2013年 | 48篇 |
2012年 | 53篇 |
2011年 | 49篇 |
2010年 | 38篇 |
2009年 | 37篇 |
2008年 | 47篇 |
2007年 | 41篇 |
2006年 | 37篇 |
2005年 | 25篇 |
2004年 | 26篇 |
2003年 | 24篇 |
2002年 | 13篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 9篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 4篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 3篇 |
1979年 | 3篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1971年 | 1篇 |
排序方式: 共有693条查询结果,搜索用时 0 毫秒
691.
Joan J. Soldevila-Barreda Andrea Pettenuzzo Maria Azmanova Laia Rafols Amr A. A. Attia Alexandru Lupan Luca Ronconi Nicolas P. E. Barry Anaïs Pitto-Barry 《Helvetica chimica acta》2023,106(8):e202300064
The synthesis by transmetallation and in-depth characterisation by IR spectroscopy of five half-sandwich ruthenium and osmium dithiocarbamato isonipecotamide glycoconjugate complexes are presented herein. The evaluation of their in vitro cytotoxicity and of the zinc precursors’ in vitro cytotoxicity towards ovarian cancer (A2780 and A2780cisR) and normal prostate (PNT2) cells is reported. While the cytotoxicity of the compounds is rather limited, some selectivity is observed. 相似文献
692.
Horia V. Alexandru 《Crystal Research and Technology》1995,30(8):1071-1077
A dual action of impurities becomes evidently in growth kinetic of prismatic faces of KDP. At higher supersaturation two-dimensional nucleation mechanism due to impurities prevails. At smaller supersaturation the blocking effect of the steps created by the dislocation mechanism of growth become efficient. The limit of the “dead” growth zone depending on the impurity's concentration and the solution pH is a result of this last effect and agrees with the Cabrera-Vermilyea mechanism. 相似文献
693.
Loredana Elena Nita Alexandra Croitoriu Alexandru M. Serban Maria Bercea Alina G. Rusu Alina Ghilan Maria Butnaru Liliana Mititelu-Tartau Aurica P. Chiriac 《Macromolecular bioscience》2023,23(3):2200451
Short aromatic peptide derivatives, i.e., peptides or amino acids modified with aromatic groups, such as 9-fluorenylmethoxycarbonyl (Fmoc), can self-assemble into extracellular matrix-like hydrogels due to their nanofibrillar architecture. Among different types of amino acids, lysine (Lys) and glycine (Gly) are involved in multiple physiological processes, being key factors in the proper growth of cells, carnitine production, and collagen formation. The authors have previously successfully presented the possibility of obtaining supramolecular gels based on Fmoc-Lys-Fmoc and short peptides such as Fmoc-Gly-Gly-Gly in order to use them as a substrate for cell cultures. This paper investigates how the introduction of a gelling polymer can influence the properties of the network as well as the compatibility of the resulting materials with different cell types. A series of hydrogel compositions consisting of combinations of Fmoc-Lys-Fmoc and Fmoc-Gly-Gly-Gly with Agarose and Phytagel are thus obtained. All compositions form structured gels as shown by rheological studies and scanning electron microscopy. Fourier transform infrared spectroscopy analysis evidences the formation of H-bonds between the polysaccharides and amino acids or short peptides. Moreover, all gels exhibit good cell viability on fibroblasts as demonstrated by a live-dead staining test and good in vivo biocompatibility, which highlights the great potential of these biomaterials for biomedical applications. 相似文献