A polarization-/angle-insensitive, bandwidth-optimized, metamaterial absorber in the microwave regime

An enhanced metamaterial absorber based on the circumscribed-cross resonator is introduced in this paper. The new structure is polarization-independent, due to the symmetry of its unit cell, and is proven efficient for the attenuation of obliquely incident waves. The absorption mechanism is thoroughly investigated and is found to be mainly related to the losses of the dielectric substrate. Furthermore, by exploiting the scalability property of metamaterials, the operational bandwidth of our design can be drastically improved by placing unit cells with properly scaled resonators adjacent to each other. In this context, various combinations of three, four, and nine unit cells that can increase the full width at half maximum up to as much as 11.18?%, are developed. The overall performance of the proposed configurations is deemed promising for the realization of microwave metamaterial absorbers for several practical applications.     

Large Eddy Simulation of Separated Flow over a Two-dimensional Hump with and without Control by Means of a Synthetic Slot-jet

Large Eddy Simulations for two flows separating from a two-dimensional hump in a duct are reported and discussed. The flows differ through the presence or absence of a synthetic slot-jet injected in a sinusoidal manner, i.e. at zero net mass-flow rate, close to the location of separation and intended to reduce (“control”) the extent of the separated region. Results reported include instantaneous visualisations, pre-multiplied spectra, wall-pressure distributions, streamfunction fields and profiles of velocity and second moments. For both flows, agreement between the simulations and the experimental results is generally good, especially in respect of the overall control effectiveness of the synthetic jet, despite the use of an approximate wall treatment bridging the viscous sublayer. Proper Orthogonal Decomposition of the velocity field is used to study structural features, and this shows that the most energetic mode in the base flow is representative of large streamwise vortices in the separated region, while in the controlled flow, most of the energetically dominant modes are associated with large spanwise vortices.     

Tensor Calculus in the Free Lie Algebra

In this Letter we characterize Lie elements and the elements of the kernel of the Lie bracketing from right to left mapping, using tensor calculus tools.     

A Homotopy in the Usual Cochain Complex of Free Lie Algebras

In this Letter, we construct a natural contracting homotopy in the usual cochain complex of free Lie algebras. As a consequence, we prove that the triple cohomology of Lie algebras coincides with a slightly different form of the standard cohomology theory.     

On complementary decompositions of the complete graph

We consider decompositionsK _n H, whereH is eitherP ₃ (the path with 3 edges) or the complete bipartite graphK _{1, 3}, with the property that upon taking the complement of each graph in the decomposition one obtains a new decompositionK _n H ^c .Research supported in part by an NSERC postgraduate Scholarship.     

In Silico Investigation of the Biological Implications of Complex DNA Damage with Emphasis in Cancer Radiotherapy through a Systems Biology Approach

Different types of DNA lesions forming in close vicinity, create clusters of damaged sites termed as “clustered/complex DNA damage” and they are considered to be a major challenge for DNA repair mechanisms resulting in significant repair delays and induction of genomic instability. Upon detection of DNA damage, the corresponding DNA damage response and repair (DDR/R) mechanisms are activated. The inability of cells to process clustered DNA lesions efficiently has a great impact on the normal function and survival of cells. If complex lesions are left unrepaired or misrepaired, they can lead to mutations and if persistent, they may lead to apoptotic cell death. In this in silico study, and through rigorous data mining, we have identified human genes that are activated upon complex DNA damage induction like in the case of ionizing radiation (IR) and beyond the standard DNA repair pathways, and are also involved in cancer pathways, by employing stringent bioinformatics and systems biology methodologies. Given that IR can cause repair resistant lesions within a short DNA segment (a few nm), thereby augmenting the hazardous and toxic effects of radiation, we also investigated the possible implication of the most biologically important of those genes in comorbid non-neoplastic diseases through network integration, as well as their potential for predicting survival in cancer patients.     

Mild olefin formation via bio-inspired vitamin B12 photocatalysis

Dehydrohalogenation, or elimination of hydrogen-halide equivalents, remains one of the simplest methods for the installation of the biologically-important olefin functionality. However, this transformation often requires harsh, strongly-basic conditions, rare noble metals, or both, limiting its applicability in the synthesis of complex molecules. Nature has pursued a complementary approach in the novel vitamin B₁₂-dependent photoreceptor CarH, where photolysis of a cobalt–carbon bond leads to selective olefin formation under mild, physiologically-relevant conditions. Herein we report a light-driven B₁₂-based catalytic system that leverages this reactivity to convert alkyl electrophiles to olefins under incredibly mild conditions using only earth abundant elements. Further, this process exhibits a high level of regioselectivity, producing terminal olefins in moderate to excellent yield and exceptional selectivity. Finally, we are able to access a hitherto-unknown transformation, remote elimination, using two cobalt catalysts in tandem to produce subterminal olefins with excellent regioselectivity. Together, we show vitamin B₁₂ to be a powerful platform for developing mild olefin-forming reactions.

Terminal or subterminal olefins can be selectively formed from alkyl electrophiles via bio-inspired vitamin B₁₂ photocatalysis.     

1,3-Dipolar cycloadditions of nitrile oxides with 4-carbethoxymethyleno-4,5,6,7-tetrahydro-6,6-dimethylbenzo[c][1,2,5]oxadiazole

The (E)- and (Z)-α,β-unsaturated esters, 3 and 4 are prepared by applying a Wittig reaction on the ketone 1. Stable nitrile oxides are added to the stable (E)-isomer 3 resulting to the formation of the spiro-derivatives 7 , whereas with the unstable nitrile oxides a second stereoisomer 8 is also formed. Mesitonitrile oxide reacts also with the ketone 1 to give the spiro-cycloadduct 10. The assignment of regio-isomers 7 was deduced from their spectral data as well as from some molecular orbital considerations.     

A New Class of “All‐Metal” Aromatic Hydrido‐Bridged Binary Coinage Metal Heterocycles. A DFT Study

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