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981.
Amandine Kolleth Simona Müller Alexandre Lumbroso Gamze Tanriver Saron Catak Sarah Sulzer-Mossé Alain De Mesmaeker 《Tetrahedron letters》2018,59(34):3242-3248
We described a general approach to 3-aminobenzothiophenes and 3-aminothiophenes fused to 5-membered heteroaromatic rings as thiophenes, furans and pyrroles through a 6π-elctrocyclization reaction of keteniminium salts. We investigated various substituents not only on the aromatic rings, but also at C-2 and on the nitrogen atom of the keteniminium salt. In particular, we have determined the electronic requirements of the nitrogen substitution to secure the efficient formation of the corresponding keteniminium salt. A clear relation between the pKa of the amine leading to the formation of the keteniminium salt and the yield obtained for benzothiophene is established and should find broad application to other reactions involving these intermediates. Additional insight on the ease of this 6π-electrocyclization reaction was gained through competition reactions and DFT calculations. 相似文献
982.
P. Legay J. L. Benchimol F. Alexandre J. C. Harmand 《Journal of Crystal Growth》1995,150(1-4):394-398
In order to optimize the shape of chemical beam epitaxy (CBE) selective area growth, growth rates on (100), (111)B, (111)A and (110) substrate orientations have been examined for GaAs and InP materials. (111)B GaAs growth rate appears to be drastically enhanced at low V/III ratio, which has been applied to grow selective GaAs patterns limited by vertical sidewalls. Concerning InP, high growth rates were obtained on all orientations. This was used to perfectly fill a rectangular groove by selective embedded InP growth. 相似文献
983.
The compound 5-amino-1,3,4-thiadiazole-thiol (ATT) was anchored onto silica gel surfaces by homogeneous and heterogeneous routes. Both silica modification methodologies resulted in similar products, named SiCTT and SiATT, respectively. These materials were characterized by infrared and Raman spectroscopies, superficial area and elemental analysis as well as 13C and 29Si NMR spectroscopy. Elemental analysis proved that the material SiCTT presented a higher ATT immobilization than SiATT, with values of 0.73 and 0.65 mmol g−1, respectively. NMR, Raman and infrared spectroscopy corroborate to confirm the immobilization of ATT on both surfaces. Raman spectroscopy showed that the reaction of the ATT with silylant agent or pre-modified silica occurred by the thiol group, resulting in a surface with two sulfur groups and one free amine group able to complex soft and hard acids. 相似文献
984.
J. L. Benchimol X. Q. Zhang Y. Gao G. Le Roux H. Thibierge F. Alexandre 《Journal of Crystal Growth》1992,120(1-4):189-194
AlxGa1−xAs and AlxIn1−xAs alloys were grown on GaAs and InP, respectively, by chemical beam epitaxy, using trimethylamine alane (TMAA) as the source of aluminium. TMAA could be used properly only after some problems had been solved. Low carbon and oxygen concentrations were obtained in both alloys, leading to residual hole concentrations of 2 × 1016 cm-3 in Al0.3Ga0.7As. The abruptness of the AlGaAs/GaAs interface proved the absence of TMAA memory effect. The control of AlxIn1−xAs solid composition was more difficult than for GaxIn1−xAs, but was less sensitive to growth temperature. Photoluminescence intensities of Al0.3Ga0.7As and Al0.48In0.52As grown at 510°C were similar to those of MBE grown materials. 相似文献
985.
Foundations of Computational Mathematics - In this paper, we investigate the approximation of a diffusion model problem with contrasted diffusivity for various nonconforming approximation methods.... 相似文献
986.
By potential theoretic methods involving the Cartan fine topology a recent result by two of the authors is extended as follows: The Riesz charge of the lower envelope of a family of 3 or more -subharmonic functions (no longer supposed continuous) in the plane equals the infimum of the charges of the lower envelopes of all pairs of functions from the family. As a key to this it is shown in two different ways that the (fine) harmonic measures of any 3 pairwise disjoint finely open planar sets have Borel supports with empty intersection. One proof of this uses the Jordan curve theorem and the fact that the set of inaccessible points of the fine boundary of a fine domain is Borel and has zero harmonic measure; the other involves Carleman-Tsuji type estimates together with a fine topology version of a recent result of P. Jones and T. Wolff on harmonic measure and Hausdorff dimension. 相似文献
987.
Alexandre Joel Chorin 《Journal of statistical physics》1992,69(1-2):67-78
Simple lattice vortex models are presented that exhibit vortex percolation along lines in a temperature/chemical potential plane. Parts of these lines can be identified with the percolation threshold at the inertial range of turbulence, and other parts are analogous to the transition in a three-dimensionalXY model that may model the . transition in superfluidity. Flory exponents at percolation are calculated; for nonnegative temperatures, their values approximate the standard Flory value, and are approximately constant along the transition lines, in agreement with recent conjectures. Conclusions regarding coherent structures in turbulence are also reached. 相似文献
988.
Alexandre Joel Chorin 《Communications in Mathematical Physics》1985,99(4):501-515
A linkage algorithm is presented for evaluating the partition function of a union of finite lattice blocks in terms of the partition functions of the component blocks. This algorithm leads to: (i) A fast enumeration method for evaluating the partition function of a finite lattice (for Ising spins in two dimensions, the number of terms needed to evaluate the partition function for a block ofL spins if reduced from 2
L
to
); (ii) a recursive factorization procedure that accelerates the rate at which quantities evaluated on a finite lattice converge to their thermodynamic limit, and (iii) a scaling procedure that further accelerates the convergence to the thermodynamic limit. The scaling procedure is similar to a method previously used in turbulence calculations.Supported in part by the Applied Mathematics Subprogram of the Office of Energy Research, U.S. Department of Energy, under contract DE-AC03-76SF0098, and in part by the Office of Naval Research under contract N00014-76-C-0316 相似文献
989.
Edimar DeOliveira Rafael L. Quirino Paulo A.Z. Suarez Alexandre G.S. Prado 《Thermochimica Acta》2006,450(1-2):87-90
The obtained heats of combustion were 46.65 ± 0.20; 38.09 ± 0.31; 39.67 ± 0.22; 41.88 ± 0.31; 37.86 ± 0.46; 39.89 ± 0.09; 41.28 ± 0.31 MJ/kg for diesel, transesterified soybean oil, pyrolysed soybean oil and crude soybean oil, transesterified palm tree oil (Elaeis sp.), pyrolysed palm tree oil, crude palm tree oil, respectively. The results show the heats of combustion of biofuels are approximately 17% smaller than traditional diesel. The data also show the heats of combustion depend on the methodology used for the biofuel production. Addition of biofuels to traditional diesel fuel results in a linear decrease of the heat of combustion with the amount of the alternative fuel added to the diesel. However, for blends with 5% biofuels, which is the limit demanded by Brazilian legislation, no significant decrease of the heat of combustion of the commercial diesel was observed. 相似文献
990.
Juillerat A Gronemeyer T Keppler A Gendreizig S Pick H Vogel H Johnsson K 《Chemistry & biology》2003,10(4):313-317
We report here the generation of mutants of the human O(6)-alkylguanine-DNA alkyltransferase (hAGT) for the efficient in vivo labeling of fusion proteins with synthetic reporter molecules. Libraries of hAGT were displayed on phage, and mutants capable of efficiently reacting with the inhibitor O(6)-benzylguanine were selected based on their ability to irreversibly transfer the benzyl group to a reactive cysteine residue. Using synthetic O(6)-benzylguanine derivatives, the selected mutant proteins allow for a highly efficient covalent labeling of hAGT fusion proteins in vivo and in vitro with small molecules and therefore should become important tools for studying protein function in living cells. In addition to various applications in proteomics, the selected mutants also yield insight into the interaction of the DNA repair protein hAGT with its inhibitor O(6)-benzylguanine. 相似文献