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The parallel solution-phase synthesis of more than 230 substituted thieno[2,3-d]pyrimidin-2-ylmethanamines has been accomplished. This strategy is based on the cyclization of 2-aminothiophen-3-carboxylates with chloroacetonitrile to construct the thieno[2,3-d]pyrimidine core with two diversity points. Derivatization of the active chlorine and functionalization of C-4 position of the pyrimidine ring allow the introduction of other diversity points. The products containing ester groups at the 6-position of the thieno[2,3-d]pyrimidine were used in amide synthesis. Simple manual techniques for parallel reactions, coupled with simple purification procedures, gave highly pure final products. The scope and limitations of the approach are discussed.  相似文献   
264.
We report the scanning tunnelling microscopy (STM) observation of a self-organization of 4-cyano-4′-n-decylbiphenyl (10CB) molecules on the reconstructed Au(111) surface. The self-organized monolayers were obtained by the deposition from a liquid. We revealed a row-like dimer structure with regularly arranged kinks within each dimer row. The separation between neighbor kinks is equal to 4 or 5 intermolecular distances. STM-images with intramolecular resolution showed that the association of molecules in dimers is due to the interaction between cyano groups. The obtained results are discussed in terms of the balance between the molecule-molecule and molecule-substrate interactions and are supported by the results of DFT calculations.  相似文献   
265.
Secondary photorefractive centers in Sb-doped Sn2P2S6 have a lifetime comparable to the formation time of the space-charge grating. This considerably affects the dynamics of two-beam coupling and results in a new type of transient gain enhancement for preilluminated samples.  相似文献   
266.
Interaction of copper(II) acetate with benzoic acid (benzene-1,3,5-tricarboxylic acid = H3-btc and 3,5-dinitro-benzoic acid = H-dnb) and pyridine (Py) resulted in two mononuclear square-planar complexes with the compositions [Cu(H2-btc)2(Py)2] (1) and [Cu(dnb)2(Py)2] (2). The recrystallization of 2 from dimethylsulfoxide (DMSO) yielded the square-bipyramidal complex [Cu(dnb)2(DMSO)2(H2O)2] (3). Crystal structures of 1-3 were determined by single crystal X-ray diffraction at 100 K. The square-planar Cu(II) geometry with the Cu-O and Cu-N distances of 1.924(2), 1.925(2) and 2.024(3) and 2.025(3) Å in 1, and 1.930(4) and 2.033(5) Å in 2 was found. The extended H-bonding system in 1 built on the robust carboxylic synthons is giving rise to the high-ordered porous layered structure. Insight into metal center environment and stabilizing intramolecular short interactions is obtained through quantum theory of atoms in molecules (QTAIM). As revealed by QTAIM, in octahedral complex 3 Cu-dnb and Cu-DMSO bonds are stronger than Cu-N bonds in 1 and 2.  相似文献   
267.
The independence number of a hypergraph H is the size of a largest set of vertices containing no edge of H. In this paper, we prove that if Hn is an n‐vertex ‐uniform hypergraph in which every r‐element set is contained in at most d edges, where , then where satisfies as . The value of cr improves and generalizes several earlier results that all use a theorem of Ajtai, Komlós, Pintz, Spencer and Szemerédi (J Comb Theory Ser A 32 (1982), 321–335). Our relatively short proof extends a method due to Shearer (Random Struct Algorithms 7 (1995), 269–271) and Alon (Random Struct Algorithms 9 (1996), 271–278). The above statement is close to best possible, in the sense that for each and all values of , there are infinitely many Hn such that where depends only on r. In addition, for many values of d we show as , so the result is almost sharp for large r. We give an application to hypergraph Ramsey numbers involving independent neighborhoods.Copyright © 2012 Wiley Periodicals, Inc. Random Struct. Alg., 44, 224‐239, 2014  相似文献   
268.
Five random copolymers comprising styrene and styrene with pendant fluorophore moieties, namely pyrene, naphthalene, phenanthrene, and triphenylamine, in molar ratios of 10:1, were synthesized and employed as fluorescent sensors. Their photophysical properties were investigated using absorption and emission spectral analyses in dichloromethane solution and in solid state. All copolymers possessed relative quantum yields up to 0.3 in solution and absolute quantum yields up to 0.93 in solid state, depending on their fluorophore components. Fluorescence studies showed that the emission of these copolymers is highly sensitive towards various nitroaromatic compounds, both in solution and in the vapor phase. The detection limits of these fluorophores for nitroaromatic compounds in dichloromethane solution proved to be in the range of 10−6 to 10−7 mol/L. The sensor materials for new hand-made sniffers based on these fluorophores were prepared by electrospinning and applied for the reliable detection of nitrobenzene vapors at 1 ppm in less than 5 min.  相似文献   
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Chemistry of Heterocyclic Compounds - 1,3-Dipolar cycloaddition reactions of 3,3,3-trifluoropropene derivatives containing a sulfonyl, sulfamide, or sulfoximine substituent in position 1 with...  相似文献   
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