Characterization of Coupled Ground State and Excited State Equilibria by Fluorescence Spectral Deconvolution

Fluorescence probes with multiparametric response based on the relative variation in the intensities of several emission bands are of great general utility. An accurate interpretation of the system requires the determination of the number, positions and intensities of the spectral components. We have developed a new algorithm for spectral deconvolution that is applicable to fluorescence probes exhibiting a two-state ground-state equilibrium and a two-state excited-state reaction. Three distinct fluorescence emission bands are resolved, with a distribution of intensities that is excitation-wavelength-dependent. The deconvolution of the spectrum into individual components is based on their representation as asymmetric Siano-Metzler log-normal functions. The application of the algorithm to the solvation response of a 3-hydroxychromone (3HC) derivative that exhibits an H-bonding-dependent excited-state intramolecular proton transfer (ESIPT) reaction allowed the separation of the spectral signatures characteristic of polarity and hydrogen bonding. This example demonstrates the ability of the method to characterize two potentially uncorrelated parameters characterizing dye environment and interactions.     

Einstein and Brans–Dicke Frames in Multidimensional Cosmology

Inhomogeneous multidimensional cosmological models with a higher-dimensional space-time manifold _{0 i=1} ⁿ M_i (n 1) are in stigated under dimensional reduction to a D ₀-dimensional effective non-minimally coupled -model which generalizes the familiar Brans–Dicke model. The general form of the Einstein frame representation of multidimensional solutions known in the Brans–Dicke frame is given with respect to cosmic synchronous time. As an example, the transformation is demonstrated explicitly for the generalized Kasner solutions where it is shown that solutions in the Einstein frame show no inflation of the external space although they can undergo deflation after the cosmic synchronous time inversion.     

Single-shot extreme ultraviolet laser imaging of nanostructures with wavelength resolution

We have demonstrated near-wavelength resolution microscopy in the extreme ultraviolet. Images of 50 nm diameter nanotubes were obtained with a single ~1 ns duration pulse from a desktop-size 46.9 nm laser. We measured the modulation transfer function of the microscope for three different numerical aperture zone plate objectives, demonstrating that 54 nm half-period structures can be resolved. The combination of near-wavelength spatial resolution and high temporal resolution opens myriad opportunities in imaging, such as the ability to directly investigate dynamics of nanoscale structures.     

A hidden analytic structure of the Rabi model

The Rabi model describes the simplest interaction between a cavity mode with a frequency ω_c${\omega }_c$ and a two-level system with a resonance frequency ω₀${\omega }_0$. It is shown here that the spectrum of the Rabi model coincides with the support of the discrete Stieltjes integral measure in the orthogonality relations of recently introduced orthogonal polynomials. The exactly solvable limit of the Rabi model corresponding to Δ=ω₀/(2ω_c)=0$\Delta ={\omega }_0/\left(2{\omega }_c\right)=0$, which describes a displaced harmonic oscillator, is characterized by the discrete Charlier polynomials in normalized energy ?$?$, which are orthogonal on an equidistant lattice. A non-zero value of Δ$\Delta$ leads to non-classical discrete orthogonal polynomials ?_k(?)${?}_k\left(?\right)$ and induces a deformation of the underlying equidistant lattice. The results provide a basis for a novel analytic method of solving the Rabi model. The number of ca. 1350 calculable energy levels per parity subspace obtained in double precision (cca 16 digits) by an elementary stepping algorithm is up to two orders of magnitude higher than is possible to obtain by Braak’s solution. Any first n$n$ eigenvalues of the Rabi model arranged in increasing order can be determined as zeros of ?_N(?)${?}_N\left(?\right)$ of at least the degree N=n+n_t$N=n+n_t$. The value of n_t>0$n_t>0$, which is slowly increasing with n$n$, depends on the required precision. For instance, n_t?26$n_t?26$ for n=1000$n=1000$ and dimensionless interaction constant κ=0.2$\kappa =0.2$, if double precision is required. Given that the sequence of the l$l$th zeros x_nl$x_{nl}$’s of ?_n(?)${?}_n\left(?\right)$’s defines a monotonically decreasing discrete flow with increasing n$n$, the Rabi model is indistinguishable from an algebraically solvable model in any finite precision. Although we can rigorously prove our results only for dimensionless interaction constant κ<1$\kappa <1$, numerics and exactly solvable example suggest that the main conclusions remain to be valid also for κ≥1$\kappa \ge 1$.     

Association Phenomena of Poly(arylene ether sulfone)s in Dimethylformamide

Three poly(arylene ether sulfone)s (two polymers and one copolymer) containing diphenylfluorene, phenolphthalein and 2,4-bis[(4-chlorophenyl)sulfonyl]-1-(phenyltio) benzene)] units were synthesized by the classical Williamson polyetherification reaction. The association phenomenon in N,N-dimethylformamide (DMF) was investigated by different methods: gel permeation chromatography (GPC), viscosity, atomic force microscopy (AFM), fluorescence spectroscopy and dynamic light scattering (DLS). Both AFM and DLS measurements evidenced the formation of aggregates with spherical or ellipsoidal shape at a concentration around 0.05 wt.%. This behavior could be explained by dipole-dipole interactions between macromolecular chains, probably with the participation of solvent molecules, and by H-bonds involving hydroxyl end groups.     

Separation of particles in time-dependent focusing billiards

We consider a family of stadium-like billiards with time-dependent boundaries. Two different cases of time dependence are studied: (i) the fixed boundary approximation and (ii) the exact model which takes into account the motion of the boundary. It is shown that when the billiards possess strong chaotic properties, the sequence of their boundary perturbations is the Fermi acceleration phenomenon which is three times larger than in the case of the fixed boundary approximation. However, weak mixing in such billiards leads to particle separation. Depending on the initial velocity three different things occur: (i) the particle ensemble may accelerate; (ii) the average velocity may stay constant or (iii) it may even decrease.     

Experimental study of the stability and optimization of multipulse passive mode locking

We present an experimental study of the stability of passively mode-locked pulses against noise in multipulse operation of an erbium-doped fiber laser. The laser properties are determined by two dimensionless combinations of the laser parameters. Measurements of the pulses' destabilization threshold as a function of those laser parameters show the optimal regions that maximize the mode-locked pulse stability. We find good agreement between the experimental observations and the theoretical predictions.     

Observation of a centrality-dependent dijet asymmetry in lead-lead collisions at sqrt[S(NN)] =2.76 TeV with the ATLAS detector at the LHC

By using the ATLAS detector, observations have been made of a centrality-dependent dijet asymmetry in the collisions of lead ions at the Large Hadron Collider. In a sample of lead-lead events with a per-nucleon center of mass energy of 2.76 TeV, selected with a minimum bias trigger, jets are reconstructed in fine-grained, longitudinally segmented electromagnetic and hadronic calorimeters. The transverse energies of dijets in opposite hemispheres are observed to become systematically more unbalanced with increasing event centrality leading to a large number of events which contain highly asymmetric dijets. This is the first observation of an enhancement of events with such large dijet asymmetries, not observed in proton-proton collisions, which may point to an interpretation in terms of strong jet energy loss in a hot, dense medium.