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31.
Timur Zharnikov Alexander Yakovlev Semion Kuchanov 《Journal of Polymer Science.Polymer Physics》2003,41(9):892-902
The problem of finding conditions of the loss of thermodynamic stability by the reaction system was solved on the basis of the developed theory of living free‐radical copolymerization. The spinodal's calculations were carried out for a significant number of systems differing in the values of kinetic, stoichiometric, and thermodynamic parameters. Analysis of the results of such calculations revealed some regularities in the spinodal curves' behavior and permitted us to classify their possible topological types. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 892–902, 2003 相似文献
32.
Alexander J. Zaslavski 《Journal of Mathematical Analysis and Applications》2007,335(2):962-973
The Tonelli existence theorem in the calculus of variations and its subsequent modifications were established for integrands f which satisfy convexity and growth conditions. In this paper we consider a large class of optimal control problems which is identified with a complete metric space of integrands without convexity assumptions and show that for a generic integrand the corresponding optimal control problem possesses a unique solution and this solution is Lipschitzian. 相似文献
33.
Alexander Semenov Aurélia Charlot Rachel Auzély-Velty Marguerite Rinaudo 《Rheologica Acta》2007,46(5):541-568
Dynamics of associating polymer solutions above the reversible gelation point are studied. Each macromolecule consists of
a soluble backbone (B) and a small fraction of specific strongly interacting groups (A or C stickers) attached to B. A mixture
of B–A and B–C associating polymers with 1:1 stoichiometric ratio is considered. As a result of AC association, the polymers
reversibly gelate above the overlap concentration. It is shown that (1) the network strands are linear complexes (double chains)
of B–A and B–C; (2) “diffusion” of the network junction points is characterized by an apparent activation energy, which can
be significantly higher than the energy of one AC bond; (3) most importantly, the randomness of sticker distribution along
the chain can significantly slow down the network relaxation leading to a markedly non-Maxwellian viscoelastic behavior. The
theory elucidates the most essential features of rheological behavior of polysaccharide associating systems (with A = adamantyl
moiety, C = β-cyclodextrin, B = either chitosan or hyaluronan) including similar behavior of G
′ and G
″ in a wide frequency range, strong temperature dependence of the characteristic frequency ω
x
, and an extremely strong effect of added free stickers (fC) on the dynamics.
This paper was presented at Annual European Rheology Conference (AERC) held in Hersonisos, Crete, Greece, April 27–29, 2006. 相似文献
34.
Characterization of spherical particles using high-order neural networks and scanning flow cytometry
Vladimir V. Berdnik Alexander Shvalov Valeri Maltsev Valery A. Loiko 《Journal of Quantitative Spectroscopy & Radiative Transfer》2006,102(1):62-72
We retrieve the radius R, real n and imaginary k parts of the refractive index of homogeneous spherical particles using angular distribution of the light-scattering intensity. To solve the inverse light-scattering problem we use a high-order neural-network technique. The effect of network parameters on optimization is examined. The technique is evaluated for noise-corrupted input data at 0.6 μm<R<10.6 μm, 1.02<n<1.38, and 0<k<0.03. The errors of retrieval for nonabsorbing particles do not exceed 0.05 μm for radius and 0.015 for refractive index. The experimental verification is fulfilled by experimental data retrieved by means of a scanning flow cytometer. The light-scattering profiles of polystyrene beads and spherized red blood cells are processed with the high-order neural networks and a non-linear regression at Mie theory. The parameters retrieved by the high-order neural networks correlate well with the parameters retrieved by the least-square method. 相似文献
35.
Alexander Ya. Kruger 《Set-Valued Analysis》2006,14(2):187-206
The paper continues investigations of stationarity and regularity properties of collections of sets in normed spaces. It contains
a summary of different characterizations (both primal and dual) of regularity and a list of sufficient conditions for a collection
of sets to be regular. 相似文献
36.
37.
Alexander G. Stepanov Sergei S. Arzumanov Horst Ernst Dieter Freude 《Chemical physics letters》2006,420(4-6):574-576
It has been demonstrated that 1H MAS NMR spectroscopy can be used as a tool for in situ monitoring the reaction kinetics of 13C-labeled carbon scrambling in alkane molecules adsorbed on zeolite catalysts at the reaction temperature of 540–570 K. The accuracy of the results and the time resolution are improved compared to 13C MAS NMR spectroscopy. 相似文献
38.
Alexander O. Smirnov 《Letters in Mathematical Physics》2006,76(2-3):297-316
We find a new class of Fuchsian equations, with algebro-geometric solutions associated to a hyperelliptic curve. A method for calculating its arithmetic genus and branching points is suggested. Numerous examples are given. 相似文献
39.
40.