Magnetic silica colloids for catalysis

Monodisperse magnetizable colloidal silica particles in a stable dispersion have been functionalized with a homogeneous catalyst: a PCP–pincer Pd-complex. In a proof-of-principle experiment we demonstrate the catalytic activity of the colloids in a C–C bond formation reaction. Advantages of the magnetic silica carriers are the large surface-to-volume ratio and the easy recovery by magnetic separation. After magnetic separation, the catalyst-loaded particles are readily redispersed for further use.     

Yttrium aluminate crystals for slabs

The methods of growing YAG:Nd crystals with a flat interface and YAP:Nd crystals with a sharp conical interface are described. The form of the interface was controlled by the He and H₂O content in the reducing atmosphere composed mainly of Ar and H₂ as well as by axial temperature gradient above the melt level. The crystals of 120–180 mm in length were machined to the high-quality slabs.     

Nd3+ near UV and visible fluorescence in YAP:Nd

The present paper summarizes detailed investigations of Nd³⁺ fluorescence spectra in YAP:Nd laser crystal in the broad spectral range of 370–1100 nm at liquid nitrogen temperature. Especially, Nd³⁺ near UV and visible fluorescence spectra were studied for the first time in this crystal. The Nd³⁺ near UV and visible fluorescence spectra of this crystal consist of many narrow lines (up to 50). The Nd³⁺ near UV and visible fluorescence lines arise mainly from⁴D_3/2 and²P_3/2 Nd³⁺ terms (transitions from⁴D_3/2,²P_3/2 to lower lying Nd³⁺ levels are responsible for their appearance). At room temperature the fluorescence spectra consist of broad bands with narrow lines (mainly⁴D_3/2⁴F_3/2,⁴F_5/2 and²H_9/2 transitions).     

Non-steady state homogeneous nucleation in glass-forming systems: Dimensionless kinetic equation

The kinetic equation of the classical homogeneous nucleation theory is rewritten in dimensionless form and it is shown that the numerical computation of the dimensionless kinetic equation is approximately 20 times faster in comparison with the original kinetic equation. The results are compared with known analytical results and with previous numerical results in the case of the constant and variable temperature for the model Li₂O.2 SiO₂ melt. It is shown, e.g., that under non-isothermal conditions the nucleation rate is greater than the quasistationary nucleation rate and the cluster distribution function is greater than the corresponding quasiequilibrium cluster distribution function.     

On an application of Hall's representatives theorem to a finite geometry problem

It is well-known thatn points not belonging to a hyperplane determine at leastn hyperplanes. The possible configurations of hyperplanes in the case when the number of hyperplanes is equal ton are known, too. In this paper we obtain these results by means of Hall's representatives theorem. The setting is that of a finite geometry.     

Un théorème de Choquet-Deny pour les groupes moyennables

Résumé SoitG un groupe moyennable connexe, locallement compact, à base dénombrable. Soit une mesure positive sur les boréliens deG. Nous étudions les fonctions boréliennes positivesh vérifiant: g G, . Sous de bonnes hypothèses sur , nous obtenons, pour ces fonctions, une représentation intégrale à l'aide d'exponentielles.

---

Summary LetG be a connected locally compact separable amenable group. Let be a positive measure on the Borel -field ofG. We study the positive Borel functionsh onG which satisfy: g G, . Under smooth assumptions on , we establish an integral representation of these functions in term of exponentials.

     

Laser properties of coactivated YAP: Nd free of colour centres

YAP:Nd, Cr grown under Ar-H₂ or Ar-He-H₂ atmosphere possesses good energy transfer from Cr³⁺ to Nd³⁺ but suffers from the colour centre formation. The centre formation was completely prevented using further admixture of Ce³⁺ and 10^–4–10^–3 wt. % Fe. Small luminescence quenching of Cr³⁺ or Nd³⁺ due to iron ions is negligible in the presence of Ce³⁺. The crystals may be also heavily doped with Nd³⁺ because the increased pumping efficiency compensates the shortening of the luminescence lifetime. YAP: Nd, Ce, Cr, Fe is advisible active laser material particularly for all the types of pulsed lasers.