Temperature‐ and Voltage‐Induced Ligand Rearrangement of a Dynamic Electroluminescent Metallopolymer

A dynamic‐covalent metal‐containing polymer was synthesized by the condensation of linear diamine and dialdehyde subcomponents around copper(I) templates in the presence of bidentate phosphine ligands. In solution, the red polymers undergo a sol–gel transition upon heating to form a yellow gel, a process that can be either reversible or irreversible depending on the solvent used. When fabricated into a light‐emitting electrochemical cell (LEC), the polymer emits infrared light at low voltage. As the voltage is increased, a blue shift in the emission wavelength is observed until yellow light is emitted, a process which is gradually reversed over time upon lowering the voltage. The mechanism underlying these apparently disparate responses is deduced to be due to loss of the copper phosphine complex from the polymer.     

Fuzzy optimality based decision making under imperfect information without utility

In the realm of decision making under uncertainty, the general approach is the use of the utility theories. The main disadvantage of this approach is that it is based on an evaluation of a vector-valued alternative by means of a scalar-valued quantity. This transformation is counterintuitive and leads to loss of information. The latter is related to restrictive assumptions on preferences underlying utility models like independence, completeness, transitivity etc. Relaxation of these assumptions results into more adequate but less tractable models. In contrast, humans conduct direct comparison of alternatives as vectors of attributes’ values and don’t use artificial scalar values. Although vector-valued utility function-based methods exist, a fundamental axiomatic theory is absent and the problem of a direct comparison of vectors remains a challenge with a wide scope of research and applications. In the realm of multicriteria decision making there exist approaches like TOPSIS and AHP to various extent utilizing components-wise comparison of vectors. Basic principle of such comparison is the Pareto optimality which is based on a counterintuitive assumption that all alternatives within a Pareto optimal set are considered equally optimal. The above mentioned mandates necessity to develop new decision approaches based on direct comparison of vector-valued alternatives. In this paper we suggest a fuzzy Pareto optimality (FPO) based approach to decision making with fuzzy probabilities representing linguistic decision-relevant information. We use FPO concept to differentiate “more optimal” solutions from “less optimal” solutions. This is intuitive, especially when dealing with imperfect information. An example is solved to show the validity of the suggested ideas.     

Persistence and coexistence of infinite attractors in a fractal Josephson junction resonator with unharmonic current phase relation considering feedback flux effect

Josephson junction resonators are the devices which exhibit complex behaviours as a consequence of their inductive properties. Even though the insulating medium between Josephson junctions (JJs) is normally considered homogeneous, the fact that lithography is used to form the layer, it has fractal substrates. Such JJs are identified as fractal Josephson junctions (FJJs). In this paper, a new chaotic oscillator based on memristor and FJJ has been investigated. Superconductor properties can dramatically change its operating points especially voltage and heat that are related to Josephson tunnelling. Some changes in the operating points can cause the Josephson tunnelling junctions to oscillate in different oscillation modes in very high frequencies. This can be achieved by considering the potential across the junction with its flux feedback. In order to model the magnetic flux effect, we use a memristor whose memductance function is considered as an exponential function. By varying the type of the bias current, we could observe the property of infinitely coexisting attractors in the memristor-fractal Josephson junction oscillator, which is considered as a rare phenomenon in physical circuits. The proposed Josephson-Memristor circuit model is developed, and its equilibrium points, bifurcation and Lyapunov exponents are computed. As an engineering application, modelling the trajectories of the moving object has been realized. First, the SURF algorithm, which is not affected by the scale and rotations of the object, is used in the images to identify an object that tracks the states of the proposed Josephson-Memristor circuit. In this way, the coordinates of the orbits on which the object moves were determined on the image. In order to reproduce the orbits of the specified object, the coordinate information of the object has been trained to the artificial neural network model and the orbits of the object have been reproduced.

     

Hollow BiOBr/reduced graphene oxide hybrids encapsulating hemoglobin for a mediator-free biosensor

Journal of Solid State Electrochemistry - For the construction of a mediator-free biosensor, hollow BiOBr microspheres (H-BiOBr MS) were hydrothermally synthesized and combined with reduced...     

Wet 3‐D printing of epoxy cross‐linked chitosan/carbon microtube composite

Over the last decays, the use of conductive biopolymer composites has been growing in areas such as biosensors, soft robotics, and wound dressing applications. They are generally soft hydrophilic materials with good elastic recovery and compatible with biological environments. However, their application and removal from the host are still challenging mainly due to poor mechanical strength. This work displays a technique for the fabrication of complex‐shaped conductive structures with improved mechanical strength by wet three‐dimensional (3‐D) printing, which uses a coagulation bath to quickly solidify an epoxy cross‐linked chitosan/carbon microtube composite ink. The fabricated conductive structure demonstrated higher elongation strength and improved elastic stability upon the introducing of polypropylene glycol diglycidyl ether (PPGDGE) as the epoxy cross‐linker, which can be due to the formation of networks between oxiran groups of PPGDGE and chitosan amino groups.     

Equivalent dynamic thermoviscoelastic modeling of ionic polymers

Ionic polymers have attracted considerable attention due to their interesting sensing and actuating behavior which make them a proper choice for use in a wide range of applications including biomimetic robots and biomedical devices. The complicated electro‐chemo‐mechanical dynamics of ionic polymer actuators is a drawback for their applications in functional devices. Therefore, establishing a mathematical model which could effectively predict the actuators' dynamic behavior is of great interest. In this paper, a mathematical model, named equivalent dynamic thermoviscoelastic (EDT) model, based on thermal analogy and beam theory is proposed for dynamic analysis of bending‐type ionic polymer actuators. Then, the developed model is extended for analyzing the performance of the actuator in finite element software. The finite element analysis of the actuator enables consideration of material and geometric nonlinearities and facilitates modeling of functional devices based on the ionic polymer actuators. The proposed modeling approach is validated using experimental data. Copyright © 2015 John Wiley & Sons, Ltd.     

Continuous cytometric bead processing within a microfluidic device for bead based sensing platforms

A microfluidic device for continuous biosensing based on analyte binding with cytometric beads is introduced. The operating principle of the continuous biosensing is based on a novel concept named the "particle cross over" mechanism in microfluidic channels. By carefully designing the microfluidic network the beads are able to "cross-over" from a carrier fluid stream into a recipient fluid stream without mixing of the two streams and analyte dilution. After crossing over into the recipient stream, bead processing such as analyte-bead binding may occur. The microfluidic device is composed of a bead solution inlet, an analyte solution inlet, two washing solution inlets, and a fluorescence detection window. To achieve continuous particle cross over in microfluidic channels, each microfluidic channel is precisely designed to allow the particle cross over to occur by conducting a series of studies including an analogous electrical circuit study to find optimal fluidic resistances, an analytical determination of device dimensions, and a numerical simulation to verify microflow structures within the microfluidic channels. The functionality of the device was experimentally demonstrated using a commercially available fluorescent biotinylated fluorescein isothiocyanate (FITC) dye and streptavidin coated 8 microm-diameter beads. After, demonstrating particle cross over and biotin-streptavidin binding, the fluorescence intensity of the 8 microm-diameter beads was measured at the detection window and linearly depends on the concentration of the analyte (biotinylated FITC) at the inlet. The detection limit of the device was a concentration of 50 ng ml(-1) of biotinylated FITC.     

Cu(II) and Pd(II) complexes of N-(2-hydroxybenzyl)aminopyridines

N-(2-Hydroxybenzyl)aminopyridines (Lⁱ) react with Cu(II) and Pd(II) ions to form complexes in the compositions Cu(Lⁱ)₂(CH₃COO)₂ · nH₂O (n = 0, 2, 4), Pd(Lⁱ)₂Cl₂ · nC₂H₅OH (n = 0, 2) and Pd(L²)₂Cl₂ · 2H₂O. In the complexes, the ligands are neutral and monodentate which coordinate through pyridinic nitrogen. Crystal data of the complexes obtained from 2-amino pyridine derivative have pointed such a coordinating route and comparison of the spectral data suggests the validity of similar complexation modes of other analog ligands. Cu(II) complex of N-(2-hydroxybenzyl)-2-aminopyridine (L¹), [Cu(L¹)₂(CH₃COO)₂] has slightly distorted square planar cis-mononuclear structure which is built by two oxygen atoms of two monodentate carboxylic groups disposed in cis-position and two nitrogen atoms of two pyridine rings. The remaining two oxygen atoms of two carboxylic groups form two Cu and H bridges containing cycles which joint at same four coordinated copper(II) ion. IR and electronic spectral data and the magnetic moments as well as the thermogravimetric analyses also specify on mononuclear octahedric structure of complexes [Cu(L²)₂(CH₃COO)₂ · 2H₂O] and [Cu(L³)₂(CH₃COO)₂ · 4H₂O] where L² and L³ are N-(2-hydroxybenzyl)-2- or 3-aminopyridines, respectively.