全文获取类型
收费全文 | 225篇 |
免费 | 16篇 |
国内免费 | 2篇 |
专业分类
化学 | 153篇 |
力学 | 2篇 |
数学 | 52篇 |
物理学 | 36篇 |
出版年
2024年 | 1篇 |
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 6篇 |
2020年 | 6篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2016年 | 7篇 |
2015年 | 13篇 |
2014年 | 14篇 |
2013年 | 10篇 |
2012年 | 20篇 |
2011年 | 10篇 |
2010年 | 12篇 |
2009年 | 12篇 |
2008年 | 12篇 |
2007年 | 17篇 |
2006年 | 9篇 |
2005年 | 12篇 |
2004年 | 3篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1986年 | 4篇 |
1985年 | 1篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1974年 | 1篇 |
1970年 | 3篇 |
1969年 | 8篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1941年 | 2篇 |
排序方式: 共有243条查询结果,搜索用时 15 毫秒
241.
We catalogue the primitive ideals of the Cuntz–Krieger algebra of a row-finite higher-rank graph with no sources. Each maximal tail in the vertex set has an abelian periodicity group of finite rank at most that of the graph; the primitive ideals in the Cuntz–Krieger algebra are indexed by pairs consisting of a maximal tail and a character of its periodicity group. The Cuntz–Krieger algebra is primitive if and only if the whole vertex set is a maximal tail and the graph is aperiodic. 相似文献
242.
Garate JA English NJ Singh A Ryan KM Mooney DA MacElroy JM 《Langmuir : the ACS journal of surfaces and colloids》2011,27(22):13506-13513
Molecular mechanisms of electrophoretic deposition (EPD) of poly(3-decylthiophene) (P3DT) molecules onto vertically aligned cadmium selenide arrays have been studied using large-scale, nonequilibrium molecular dynamics (MD), in the absence and presence of static external electric fields. The field application and larger polymer charges accelerated EPD. Placement of multiple polymers at the same lateral displacement from the surface reduced average deposition times due to "crowding", giving monolayer coverage. These findings were used to develop and validate Brownian dynamics simulations of multilayer polymer EPD in scaled-up systems with larger inter-rod spacings, presenting a generalized picture in qualitative agreement with random sequential adsorption. 相似文献
243.
N‐(3‐Ferrocenyl‐2‐naphthoyl) dipeptide ethyl esters 1–4 and N‐(6‐ferrocenyl‐2‐naphthoyl) dipeptide ethyl esters 5–8 were prepared by coupling either 3‐ferrocenylnaphthalene‐2‐carboxylic acid or 6‐ferrocenylnaphthalene‐2‐carboxylic acid to the dipeptide ethyl esters GlyGly(OEt) (1, 5), AlaGly(OEt) (2, 6), GlyPhe(OEt) (3, 7) and GlyLeu(OEt) (4, 8), using the standard N‐(3‐dimethylaminopropyl)‐N'‐ethylcarbodiimide hydrochloride, 1‐hydroxybenzotriazole protocol. Electrospray ionization mass spectrometry (ESI‐MS) and laser desorption ionization mass spectrometry (LDI‐MS) were employed in conjunction with tandem mass spectrometry in the analysis of N‐(3‐ferrocenyl‐2‐naphthoyl) dipeptide ethyl esters 1–4 and N‐(6‐ferrocenyl‐2‐naphthoyl) dipeptide ethyl esters 5–8. Radical cations, [M]+? and [M + H]+ species were both observed in the mass spectra. Intense sodium [M + Na]+ and potassium [M + K]+ adducts were also present. An important diagnostic ion at m/z [M–65]+ was observed in both the MS and MS/MS spectra of the N‐(3‐ferrocenyl‐2‐naphthoyl) dipeptide derivatives. Sequence‐specific ions were generally not observed in the MS/MS spectra of the N‐(3‐ferrocenyl‐2‐naphthoyl) series due to formation of the diagnostic [M–65]+ ion. Sequence‐specific ions were observed in the MS/MS spectra of the N‐(6‐ferrocenyl‐2‐naphthoyl) dipeptide esters with charge retention on the derivatized N‐terminal of the dipeptide. Both series of compounds could be successfully analyzed by MALDI without the use of a matrix (LDI). Copyright © 2011 John Wiley & Sons, Ltd. 相似文献