排序方式: 共有69条查询结果,搜索用时 46 毫秒
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[Cu2(Gly-GlyO)2(4,4''''-bpy)(OH)2]·10H2O配合物的合成、晶体结构和分子结构研究 总被引:1,自引:0,他引:1
合成了以4,4'-bpy为中继基、Gly-GlyO为螯环的新型双核铜配合物.经X射线单晶结构分析确定该配位化合物晶体的化学式为[(H2NCH2CONHCH2COO)Cu(OH)(C10H8N2)Cu(OH)-(H2NCH2CONHCH2COO)]·10H2O.晶体属三斜晶系,Pl空间群,晶胞参数a=0.712 4(2)nm,b=1.140 5(10)nm,c=1.143 4(10)nm,α=67.55°,β=79.02°,γ=77.97°,V=0.834(3)nm3,Z=1.最终一致性因子R为0.072 7. 相似文献
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TiO2表面包覆SiO2和Al2O3的机理和结构分析 总被引:54,自引:1,他引:53
在二氧化钛的表面上包覆一层保护膜,使二氧化钛的表面和周围介质之间产生屏障,从而降低二氧化钛的光化学活性,有利于提高二氧化钛的分散性、耐光性、耐候性和抗粉化性. 相似文献
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The reactions of [MIII(CN)6]3? (M = Cr or Co) with CuII complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu4(aemp)4(H2O)2][Cr(CN)6]Cl (1) and [Cu3(aemp)3(H2O)][Co(CN)6]·2H2O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)6]3? moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 cm?1. 相似文献
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ZHENG Lei NI Zhong-Hai LI Wen-Lu ZHANG Li-Fang GE Chun-Hua CUI Ai-Li KOU Hui-Zhong 《结构化学》2008,27(7):793-796
A new p-PhDTA bridged Cu(II) complex [Cu2(p-PhDTA)(DMSO)2]·4DMSO (p-PhDTA = p-phenylenediamine-N,N,N,N'-tetraacetic acid) has been synthesized and structurally characterized. The crystal belongs to orthorhombic, space group Pca21 with a = 19.572(4), b = 19.552(4), c = 10.156(2)A, C26H48N2O14CU2S6, Mr = 932.10, V = 3886.4(13)A3, Z = 4, Dc = 1.593 g/cm^3, F(000) = 1936, λ(MoKa) = 0.71073A,μ = 1.480, R = 0.0487 and wR = 0.1151 for 8464 observed reflections (I 〉2σ(I)). In the complex, the oxygen atoms of carboxylate of p-PhDTA connect the Cu atoms in a syn-anti type, giving one-dimensional chains which are further linked by the benzene groups ofp-PhDTA to form a novel two-dimensional structure. 相似文献
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以质子化2-丙胺为阳离子合成了铜(Ⅱ)配合物[(CH3)2CHNH3]CuBr3-xClx(x=0~3), 该系列配合物是卤离子桥联的一维链状结构. 磁性研究表明, 配合物为反铁磁相互作用, 其χmT在高温时出现突跃, 对应于结构相变. Cu(Ⅱ)配离子在高温呈拉长八面体结构, 在低温呈四方锥结构, 伴随着桥连方式的改变, 配合物从低温相的反铁磁性变为高温相的铁磁性. 根据晶体场理论分析, 由于配位X-的不同导致晶体场分裂能发生变化, 相转变温度伴随着氯离子所占比例不同呈现规律性变化. 通过配合物[(CH3)2CHNH3]CuX3(X-=Br-或Cl-)的磁性比较提出了[(CH3)2CHNH3]CuBr3-xClx(x=1, 2)的可能结构, 并使用铁磁均匀一维链模型对高温相配合物磁性进行了拟合. 相似文献
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Our goal is to propose four versions of modified Marder–Weitzner methods and to present the implementation of the new-type methods with incremental unknowns for solving nonlinear eigenvalue problems. By combining with compact schemes and modified Marder–Weitzner methods, six schemes well suited for the calculation of unstable solutions are obtained. We illustrate the efficiency of the new algorithms by using numerical computations and by comparing them with existing methods for some two-dimensional problems. 相似文献