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81.
Frequency and voltage-dependent electrical and dielectric properties of Al/Co-doped PVA/p-Si structures at room temperature 下载免费PDF全文
In order to investigate of cobalt-doped interracial polyvinyl alcohol (PVA) layer and interface trap (Dit) effects, A1/p- Si Schottky barrier diodes (SBDs) are fabricated, and their electrical and dielectric properties are investigated at room temperature. The forward and reverse admittance measurements are carded out in the frequency and voltage ranges of 30 kHz-300 kHz and -5 V-6 V, respectively. C-V or er-V plots exhibit two distinct peaks corresponding to inversion and accumulation regions. The first peak is attributed to the existence of Dit, the other to the series resistance (Rs), and interfacial layer. Both the real and imaginary parts of dielectric constant (er and err) and electric modulus (Mr and Mrr), loss tangent (tan~), and AC electrical conductivity (aac) are investigated, each as a function of frequency and applied bias voltage. Each of the M~ versus V and Mrr versus V plots shows a peak and the magnitude of peak increases with the increasing of frequency. Especially due to the Dit and interfacial PVA layer, both capacitance (C) and conductance (G/w) values are strongly affected, which consequently contributes to deviation from both the electrical and dielectric properties of A1/Co-doped PVA/p-Si (MPS) type SBD. In addition, the voltage-dependent profile of Dit is obtained from the low-high frequency capacitance (CLF-CHF) method. 相似文献
82.
Congjun Yu Bünyamin Özkaya Prof. Dr. Frederic W. Patureau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(11):3682-3687
A mild and green electro-oxidative protocol to construct aromatic esters from methylarenes and alcohols is herein reported. Importantly, the reaction is free of metals, chemical oxidants, bases, acids, and operates at room temperature. Moreover, the design of the electrolyte was found critical for the oxidation state and structure of the coupling products, a rarely documented effect. This electro-oxidative coupling process also displays exceptional tolerance of many fragile easily oxidized functional groups such as hydroxy, aldehyde, olefin, alkyne, as well as neighboring benzylic positions. The enantiomeric enrichment of some chiral alcohols is moreover preserved during this electro-oxidative coupling reaction, making it overall a promising synthetic tool. 相似文献
83.
M. Emin Çorman Nilay Bereli Serpil Özkara Lokman Uzun Adil Denizli 《Biomedical chromatography : BMC》2013,27(11):1524-1531
As alternative hydrophobic adsorbent for DNA adsorption, supermacroporous cryogel disks were synthesized via free radical polymerization. In this study, we have prepared two kinds of cryogel disks: (i) poly(2‐hydroxyethyl methacrylate‐N‐methacryloyl‐l ‐tryptophan) [p(HEMA‐MATrp)] cryogel containing specific hydrophobic ligand MATrp; and (ii) monosize p(HEMA‐MATrp) particles synthesized via suspension polymerization embedded into p(HEMA) cryogel structure to obtain p(HEMA‐MATrp)/p(HEMA) composite cryogel disks. These cryogel disks containing hydrophobic functional group were characterized via swelling studies, Fourier transform infrared spectroscopy, elemental analysis, surface area measurements and scanning electron microscopy. DNA adsorption onto both p(HEMA‐MATrp) cryogel and p(HEMA‐MATrp)/p(HEMA) composite cryogels was investigated. Maximum adsorption of DNA on p(HEMA‐MATrp) cryogel was found to be 15 mg/g polymer. Otherwise, p(HEMA‐MATrp)/p(HEMA) composite cryogels significantly increased the DNA adsorption capacity to 38 mg/g polymer. Composite cryogels could be used repeatedly without significant loss on adsorption capacity after 10 repetitive adsorption–desorption cycles. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
84.
We report highly convenient Pd catalysts for the aerobic oxidation of alcohols, which are generated in situ by combining commercially available catalyst precursors. Systematic optimizations of the L- and X-type ligand environment and the employed additive allow the use of air as the sole oxidant without formation of Pd black. The resulting novel protocol provides quantitative yields of a broad variety of ketones and aldehydes. 相似文献
85.
The perfect matchings in the n-cube have earlier been enumerated for n?≤?6. A dynamic programming approach is here used to obtain the total number of perfect matchings in the 7-cube, which is 391 689 748 492 473 664 721 077 609 089. The number of equivalence classes of perfect matchings is further shown to be 336 in the 5-cube, 356 788 059 in the 6-cube and 607 158 046 495 120 886 820 621 in the 7-cube. The techniques used can be generalized to arbitrary bipartite and general graphs. 相似文献
86.
S. Ö. Akdemir S. D. Eryilmaz E. Öztekin 《International journal of quantum chemistry》2012,112(6):1585-1591
In this article, extremely simple analytical formulas are obtained for rotational overlap integrals which occur in integrals over two reduced rotation matrix elements. The analytical derivations are based on the properties of the Jacobi polynomials and beta functions. Numerical results and special values for rotational overlap integrals are obtained by using symmetry properties and recurrence relationships for reduced rotation matrix elements. The final results are of surprisingly simple structures and very useful for practical applications. © 2011 Wiley Periodicals, Inc. Int J Quantum Chem, 2012 相似文献
87.
Emel Önal Cheng Zhang Derya Davarcı Ümit İşci Guillaume Pilet Andrew K. Whittaker Fabienne Dumoulin 《Tetrahedron letters》2018,59(6):521-523
A cyclotriphosphazene substituted with six 3,5-bis(trifluoromethyl) benzyloxy units was designed as a novel 19F MRI contrast agent. The resulting molecule has 36 magnetically equivalent fluorine atoms and exhibited suitable MRI properties with high imaging sensitivity, confirming the proof-of-concept as a convenient scaffold for the production of new 19F MRI contrasts agents. 相似文献
88.
89.
B. Saatçi M. Ari M. Gündüz S. Türktekin F. Meydaneri S. Durmuş M. Özdemir 《Continuum Mechanics and Thermodynamics》2013,25(6):739-748
In this work, the structural and transport properties of Mg-doped Sn-based alloys have been investigated. The temperature-dependent transport and structural properties of Sn–Mg alloys were investigated for five different samples (Pure Sn, Sn-1.0 wt% Mg, Sn-2.0 wt% Mg, Sn-6.0 wt% Mg and Pure Mg). Scanning electron microscopy (SEM), X-ray diffraction and energy dispersive X-ray analysis measurements were carried out in order to clarify the structural properties of the samples. It was found that the samples had tetragonal crystal symmetry, except for pure Mg which had hexagonal crystal symmetry. We also found that the cell parameters changed slightly with the addition of Mg element. The SEM micrographs of the samples showed that they had smooth surfaces with a clear grain boundary. The electrical and thermal conductivity of the samples were measured by four-point probe and the radial heat flow method, respectively. The electrical resistivity of the samples increased almost linearly with the increasing temperature. The thermal conductivity values ranged between 0.60 and 1.00 W/Km, while they decreased slightly with temperature and increased with Mg composition. The thermal conductivity values of the alloys were in between the values of pure Sn and Mg. The thermal conductivity results of the alloys were compared with other available results, and a good agreement was seen between the results. In addition, the temperature coefficients of electrical resistivity and thermal conductivity were determined; these were independent of the composition of the alloying elements. 相似文献
90.
Efficient and modular syntheses of chiral 2-(2-hydroxyaryl)alcohols (HAROLs), novel 1,4-diols carrying one phenolic and one alcohol hydroxyl group, have been developed which led to generation of a small library of structurally diverse HAROLs in enantiomerically pure form. Of the different HAROLs examined, a HAROL based on the indan backbone exhibited the highest activity and enantioselectivity in the 1,2-addition of certain organometallic compounds to aldehydes in the presence of Ti(OiPr)4 (up to 97% y, 88% ee) and performed as a hydrogen-bond donor organocatalyst in the Morita-Baylis-Hillman reaction, promoted by trialkylphosphines. 相似文献