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91.
92.
Joanne E. Stanley Anthony C. Swain Kieran C. Molloy David W. H. Rankin Heather E. Robertson Blair F. Johnston 《应用有机金属化学》2005,19(5):644-657
Perfluoroalkytin compounds R(4−n)Sn(Rf)n (R = Me, Et, Bu, Rf = C4F9, n = 1; R = Bu, Rf = C4F9, n = 2, 3; R = Bu, Rf = C6F13, n = 1) have been synthesized, characterized by 1H, 13C, 19F and 119Sn NMR, and evaluated as precursors for the atmospheric pressure chemical vapour deposition of fluorine‐doped SnO2 thin films. All precursors were sufficiently volatile in the range 84–136 °C and glass substrate temperatures of ca 550 °C to yield high‐quality films with ca 0.79–2.02% fluorine incorporation, save for Bu3SnC6F13, which incorporated <0.05% fluorine. Films were characterized by X‐ray diffraction, scanning electron microscopy, thickness, haze, emissivity, and sheet resistance. The fastest growth rates and highest quality films were obtained from Et3SnC4F9. An electron diffraction study of Me3SnC4F9 revealed four conformations, of which only the two of lowest abundance showed close F Sn contacts that could plausibly be associated with halogen transfer to tin, and in each case it was fluorine attached to either the γ‐ or δ‐carbon atoms of the Rf chain. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
93.
α-Arylation and Ring Expansion of Annulated Cyclobutanones: Stereoselective Synthesis of Functionalized Tetralones 下载免费PDF全文
Dr. Stanley Chang Dr. Michael Holmes Dr. Jeffrey Mowat Michael Meanwell Prof. Robert Britton 《Angewandte Chemie (International ed. in English)》2017,56(3):748-752
α-Arylcyclobutanones display unique reactivity that makes them valuable synthetic intermediates and target molecules. We describe the preparation of α-aryl- and α-heteroarylcyclobutanones through a direct α-arylation reaction. Problematic fragmentations are avoided by the use of LiOtBu, which promotes a rapid but reversible self-aldol reaction that slowly releases the enolate required for α-arylation. We also demonstrate the ring expansion of α-arylcyclobutanones, a process that is highlighted in the stereoselective synthesis of 1-methoxy coniothyrinone D. 相似文献
94.
Morphine fluorescence spectra were obtained for morphine sulfate in distilled water, in KRP solution, and in KRP solutions with various concentrations of Ca++ and Mg++. No evidence of fluorescence shifting indicative of complex formation was observed. Similar solutions were used in a potentiometric study, and no evidence for complex formation was observed. 相似文献
95.
Nicholas Douglas Charles J. Neef Robert A. Rogers Jake A. Stanley Jacob Armitage Ben Martin Todd W. Hudnall William J. Brittain 《Journal of Physical Organic Chemistry》2013,26(8):688-695
The synthesis and reactivity of a tetrahydrochromeno[2,3‐b]indoles are reported. Evidence for reversible ring‐opening is based on H/D exchange and trapping experiments. These compounds readily undergo reaction with tetra‐n‐butylammonium cyanide. The cyanide reaction is 10–100× faster when the solution is irradiated with 350 nm light. Reaction with trimethylsilyl cyanide occurs only with UV irradiation demonstrating photoreactivity. The rate of tetrahydrochromeno[2,3‐b]indole ring‐opening is greater for (i) Me substitution at the hemiaminal carbon (compared to Ph), and (ii) substitution of fluorine at the 9‐position of the indole. Under acidic conditions, the ring‐opened indolium ion is observed. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
96.
97.
Benjamin Byerly Kevin Kuhn Lisa Colletti Lynn Foster Russ Keller Elmer Lujan Alex Martinez Donivan Porterfield Dan Schwartz Khal Spencer Floyd Stanley Mariam Thomas Lisa Townsend Ning Xu Lav Tandon 《Journal of Radioanalytical and Nuclear Chemistry》2017,312(1):95-104
Thorough physical and chemical characterization of plutonium–beryllium (PuBe) neutron sources is an important capability with applications ranging from material accountancy to nuclear forensics. Characterization of PuBe sources is not trivial owing to range of existing source designs and the need for adequate infrastructure to deal with radiation and protect the analyst. This study demonstrates a method for characterization of three PuBe sources that includes physical inspection and imaging followed by controlled disassembly and destructive analysis. 相似文献
98.
Adrienne N. Dula Daniel F. Gochberg Mark D. Does 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2009,196(2):149-156
Calculations, analytical solutions, and simulations were used to investigate the trade-off of echo spacing and receiver bandwidth for the characterization of bi-exponential transverse relaxation using a multi-echo imaging pulse sequence. The Cramer–Rao lower bound of the standard deviation of the four parameters of a two-pool model was computed for a wide range of component T2 values and echo spacing. The results demonstrate that optimal echo spacing (TEopt) is not generally the minimal available given other pulse sequence constraints. The TEopt increases with increasing value of the short T2 time constant and decreases as the ratio of the long and short time constant decreases. A simple model of TEopt as a function of the two T2 time constants and four empirically derived scalars is presented. 相似文献
99.
100.
W.-S. Jung F. Z. Wang S. Havlin T. Kaizoji H.-T. Moon H. E. Stanley 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(1):113-119
We investigate scaling and memory effects in return intervals between price volatilities above a certain threshold q for the
Japanese stock market using daily and intraday data sets. We find that the distribution of return intervals can be approximated
by a scaling function that depends only on the ratio between the return interval τ and its mean 〈τ〉. We also find memory effects
such that a large (or small) return interval follows a large (or small) interval by investigating the conditional distribution
and mean return interval. The results are similar to previous studies of other markets and indicate that similar statistical
features appear in different financial markets. We also compare our results between the period before and after the big crash
at the end of 1989. We find that scaling and memory effects of the return intervals show similar features although the statistical
properties of the returns are different. 相似文献