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71.
72.
Adriano B. Pangelinan R. L. McCullough Michael J. Kelley 《Journal of Polymer Science.Polymer Physics》1994,32(14):2383-2394
An analytic model based on a random-walk formulation for absorbing barriers is presented. The range of applicability of the model is established from results derived from Monte Carlo simulations. The model takes into account the influences of neutral, repulsive, and attractive polymer-surface interactions on the spatial variation of species concentrations in the vicinity of a surface. The model predicts that the lower molecular weight species of a polydisperse mixture will accumulate in the vicinity of a surface to create an interphase region. The extent of this surface-perturbed interphase region is on the order of three times the radius of gyration of the longest species of the mixture. The degree of molecular weight segregation is dependent upon the breadth of the molecular weight distribution. © 1994 John Wiley & Sons. Inc. 相似文献
73.
74.
75.
Liquid hydrogen in protonic chabazite 总被引:2,自引:0,他引:2
Zecchina A Bordiga S Vitillo JG Ricchiardi G Lamberti C Spoto G Bjørgen M Lillerud KP 《Journal of the American Chemical Society》2005,127(17):6361-6366
Due to its fully reversible nature, H(2) storage by molecular adsorption could represent an advantage with respect to dissociative processes, where kinetic effects during the charging and discharging processes are present. A drawback of this strategy is represented by the extremely weak interactions that require low temperature and high pressure. High surface area materials hosting polarizing sites can represent a viable way toward more favorable working conditions. Of these, in this contribution, we have studied hydrogen adsorption in a series of zeolites using volumetric techniques and infrared spectroscopy at 15 K. We have found that in H-SSZ-13 zeolite the cooperative role played by high surface area, internal wall topology, and presence of high binding energy sites (protons) allows hydrogen to densify inside the nanopores at favorable temperature and pressure conditions. 相似文献
76.
Numerische Mathematik - 相似文献
77.
Gribov EN Cocina D Spoto G Bordiga S Ricchiardi G Zecchina A 《Physical chemistry chemical physics : PCCP》2006,8(10):1186-1196
The adsorption of Ar, H2, O2, N2 and CO on (H,Na)-Y zeolite (Si/Al = 2.9, H+/Na+ approximately 5) has been studied at variable-temperature (90-20 K) and sub-atmospheric pressure (0-40 mbar) by FTIR spectroscopy. Unprecedented filling conditions of the zeolite cavities were attained, which allowed the investigation of very weakly adsorbed species and of condensed, liquid-like or solid-like, phases. Two pressure regimes were singled out, characterized by: (i) specific interaction at low pressure of the probe molecules (P) with the internal Br?nsted and Lewis sites, and (ii) multilayer adsorption at higher pressure. In the case of CO the perturbation of the protonic sites located inside the sodalite cages was also observed. As the molecule is too large to penetrate the sodalite cage, the perturbation is thought to involve a proton jump tunneling mechanism. The adsorption energy for the (HF)OH...P (P = Ar, H2, O2, N2 and CO) specific interaction involving the high frequency Br?nsted acid sites exposed in the supercages was derived following the VTIR (variable temperature infrared spectroscopy) method described by E. Garrone and C. Otero Areán (Chem. Soc. Rev., 2005, 34, 846). 相似文献
78.
Patrícia S. Peixoto Ildikó V. Tóth Luisa Barreiros Ana Machado Adriano A. Bordalo José L. F. C. Lima 《International journal of environmental analytical chemistry》2019,99(3):258-269
Fluoroquinolones are in the order of the day concerning environmental contamination through anthropogenic activities, resulting in increased risk for antibiotic resistance dissemination. In this context, accessible, low-cost analytical methods are required for implementation of comprehensive surveillance and screening schemes. In this work, we propose a down-scaled disk-based solid-phase extraction system from which the eluate can be first screened by miniaturized fluorimetric reading, followed by individual determination of target fluoroquinolones (ciprofloxacin, norfloxacin, and enrofloxacin) by liquid chromatography combined to tandem mass spectrometry. The fluorimetric measurement is based on the intrinsic fluorescence of fluoroquinolones. Disk-based retention was performed after sample acidification (pH 4.0) by mixed-mode cation exchange using polystyrene divinylbenzene sulphonated sorbent. Sample loading was precisely controlled in a dedicated flow system operating at 4.0 mL min?1. Different eluent compositions were tested, with elution performed by 1.00 mL of methanol-ammonium hydroxide (98:2, v/v), with subsequent reading of eluate in both detectors. Quantification was attained for 2–25 µg L?1 range, with LOD values at 1 µg L?1. The proposed approach was successfully applied to estuarine waters from the Douro River, with comparable results to a conventional SPE-LC-MS/MS procedure. 相似文献
79.
Carlo Lamberti Carmelo Prestipino Francesca Bonino Luciana Capello Silvia Bordiga Giuseppe Spoto Adriano Zecchina Sofia Diaz Moreno Barbara Cremaschi Marco Garilli Andrea Marsella Diego Carmello Sandro Vidotto Giuseppe Leofanti 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2002,114(13):2447-2450
80.
Josepha Yohanna de Jesus Eliane Santos de Carvalho Dantas Mairim Russo Serafini Paula dos Passos Menezes Juliana Cordeiro Cardoso Ricardo Luiz Cavalcanti Albuquerque-Jr Jivaldo do Rosário Matos Juliana Ferreira de Oliveira Irwin Rose Alencar de Menezes Francilene Amaral da Silva Adriano Antunes de Souza Araújo 《Journal of Thermal Analysis and Calorimetry》2016,123(3):2003-2012