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The salient point arising out of a consideration of some seemingly independent topics in representation theory, combinatorics and the theory of numerical polynomials turns out to be a result involving characters of representations of wreath products. The topics are: symmetrized inner products of representations, irreducible characters of wreath products, Frobenius' formula for the irreducible ordinary characters of symmetric groups, the Pólya-Redfield theory of enumeration under group action in combinatorics and results of Rudvalis and Snapper that certain polynomials arising from generalized cycleindices of permutation groups are numerical.  相似文献   
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In the present paper we describe the use of group actions, double cosets and homomorphisms in the constructive theory of discrete structures, as we found it useful from both a theoretical and a practical point of view. By means of examples we should like to demonstrate that these methods are useful both as unifying principles and as efficient methods for applications.  相似文献   
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The effect of additions of pure and modified montmorrilonite on the polypropylene crystallization rate was studied within the framework of Avrami model. In the presence of these fillers in amounts of 2.5–5.0 wt %, both the crystallization rate and the degree of crystallinity increase, and at the content of these fillers increased to 10% and higher values these parameters decrease. Introduction of fillers enhances the mechanical properties of polypropylene, which allows the developed material to be recommended for the production of packaging film.  相似文献   
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CdII is a major genotoxic agent that readily displaces ZnII in a multitude of zinc proteins, abrogates redox homeostasis, and deregulates cellular metalloproteome. To date, this displacement has been described mostly for cysteine(Cys)-rich intraprotein binding sites in certain zinc finger domains and metallothioneins. To visualize how a ZnII-to-CdII swap can affect the target protein's status and thus understand the molecular basis of CdII-induced genotoxicity an intermolecular ZnII-binding site from the crucial DNA repair protein Rad50 and its zinc hook domain were examined. By using a length-varied peptide base, ZnII-to-CdII displacement in Rad50’s hook domain is demonstrated to alter it in a bimodal fashion: 1) CdII induces around a two-orders-of-magnitude stabilization effect (log =20.8 vs. log =22.7), which defines an extremely high affinity of a peptide towards a metal ion, and 2) the displacement disrupts the overall assembly of the domain, as shown by NMR spectroscopic and anisotropy decay data. Based on the results, a new model explaining the molecular mechanism of CdII genotoxicity that underlines CdII’s impact on Rad50’s dimer stability and quaternary structure that could potentially result in abrogation of the major DNA damage response pathway is proposed.  相似文献   
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3,4-Dilithio-2,5-dimethyl-2,4-hexadiene ( 4a ) rearranges to the cross-conjugated 2,5-dimethylhexadienediyl dianion 11a . A mechanistic investigation proves the intermolecularity of this rearrangement, which is also observed when starting from 4b . The 3-lithio-2,5-dimethylhexadienyl anion 10a with one vinyllithium and one allyllithium group, is a true intermediate in this rearrangement, its synthetic potential is employed in the reaction with dichlorosilanes to form 2-isopropylidene-2,5-dihydrosilols 8 .  相似文献   
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