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41.
It is shown that the difference in the 1H NMR chemical shift of a protic hydrogen in DMSO and CDCl3 solvents is directly related to the overall, or summation, hydrogen bond acidity for a wide range of solutes. This provides a new and direct method of measuring the hydrogen bond acidity. For 54 compounds, the observed shifts for 72 protic hydrogens could be correlated to the Abraham solute hydrogen bond acidity parameter, A, with a correlation coefficient squared, R2, of 0.938 and a standard deviation, SD, of 0.054 units in A. A training equation that used half the data could predict A values for the remaining data with an average error of 0.001 and a standard deviation, SD, of 0.053 units, thus demonstrating the predictive power of the method. Unlike any previous method for the determination of solute hydrogen bond acidities, the NMR method allows the determination of A values for individual protic hydrogens in multifunctional solutes. 相似文献
42.
The introduction of electron rich and sterically hindered ligands has made otherwise inert aryl chlorides and hetero aryl chlorides viable coupling partners in palladium-catalyzed Suzuki-Miyaura, Sonogashira, Stille and other types of cross-coupling reactions. This review gives highlights of cross-coupling of aryl chlorides employing in situ generated palladium catalytic systems. 相似文献
43.
Dima Libster Abraham Aserin Doron Yariv Gil Shoham Nissim Garti 《Colloids and surfaces. B, Biointerfaces》2009,74(1):202-215
This paper describes the formation and characterization of liquid crystalline dispersions based on the hexagonal phase of GMO/tricaprylin/water. As a stabilizer of the soft particles dispersed in the aqueous phase, a non-ionic, non-polymeric surfactant—ethoxylated phytosterol with 30 oxyethylene units (PhEO) was utilized. In contrast to Pluronic copolymers, normally utilized in the stabilization of liquid crystalline dispersions with ordered inner structure, use of such non-polymeric surfactant is not a common practice in this field. We revealed how properties of these particles, such as internal structure, size, and stability, can be rationally modified by the concentration of the stabilizing agent and processing conditions. The physical stability of the hexosomes was further examined by the LUMiFuge technique.Structural effect of PhEO solubilization on the properties of the bulk HII mesophase system showed that phase behavior was greatly influenced following phase transitions: HII → HII + cubic → cubic + Lα → Lα. The decrease of hydrogen bonding of the hydroxyl and carbonyl groups of monoolein with water and simultaneous hydration of EO groups of PhEO appeared to be important for the observed behavior. The use of PhEO as a dispersant resulted in a soft matter multi-phase water dispersion with bimodal distribution of the particle population. Effective stabilization of hexosomes was obtained in an extremely narrow concentration range of PhEO (0.1–0.2 wt%), coexisting with small vesicles and disordered particles. At higher PhEO content, particles had disordered inner structure, and unilamellar and multilamellar vesicles, at the expense of hexosomes in consequence of incorporation of the dispersant into the hexosome structure. PhEO was found to induce lamellar phase formation, introducing disorder into the hexagonal LLC and reducing their domain size.Finally, hexosomes were evaluated as delivery vehicles for the therapeutic peptide desmopressin. Sustained release of this drug was observed during the first 10 h; however, permeation drastically increased in the 10–24 h range. 相似文献
44.
A molecular keypad lock: a photochemical device capable of authorizing password entries 总被引:1,自引:0,他引:1
Margulies D Felder CE Melman G Shanzer A 《Journal of the American Chemical Society》2007,129(2):347-354
This paper describes a new concept in the way information can be protected at the molecular scale. By harnessing the principles of molecular Boolean logic, we have designed a molecular device that mimics the operation of an electronic keypad lock, e.g., a common security circuit used for numerous applications, in which access to an object or data is to be restricted to a limited number of persons. What distinguishes this lock from a simple molecular logic gate is the fact that its output signals are dependent not only on the proper combination of the inputs but also on the correct order by which these inputs are introduced. In other words, one needs to know the exact passwords that open this lock. The different password entries are coded by a combination of two chemical and one optical input signals, which can activate, separately, blue or green fluorescence output channels from pyrene or fluorescein fluorophores. The information in each channel is a single-bit light output signal that can be used to authorize a user, to verify authentication of a product, or to initiate a higher process. This development not only opens the way for a new class of molecular decision-making devices but also adds a new dimension of protection to existing defense technologies, such as cryptography and steganography, previously achieved with molecules. 相似文献
45.
46.
Pot experiments were conducted to study the efficacy of a slow sulfur-releasing fertilizer, sulfur glass fritz (SGF 1), on
growth, photosynthesis, and sulfur, and nitrogen assimilation potentials of brown mustard (Brassica juncea L. Czern. & Coss. cv. Pusa Jaikisan). Growth as indicated by biomass accumulation slowed down in response to the application
of sulfur glass fritz. A similar trend was observed in the case of photosynthesis rate. The activity of two marker enzymes,
ATP-sulfurylase and nitrate reductase, showed very low levels of activity, indicating poor assimilation of sulfur and nitrogen
by the plant under sulfur glass fritz. It is therefore concluded that the release of sulfur by sulfur glass fritz is too slow
and that the initial nonavailability of sulfur to the plants could lead to suboptimization of both sulfur- and nitrogen-assimilating
enzymes. These factors may contribute to low rates of photosynthesis and poor growth. 相似文献
47.
48.
Ch. Anjaiah M. Nagamani Ch. Abraham Lincoln D. Ashok 《Russian Journal of General Chemistry》2018,88(10):2149-2153
An efficient microwave-assisted synthesis of 3-(arylsulfanyl)-4-hydroxy-2H-chromen-2-ones by condensation of arenesulfonohydrazides with 4-hydroxy-2H-chromen-2-one in the presence of iodine is described. The synthesized compounds were characterized by spectral data (IR, 1H and 13C NMR, and mass spectra and elemental analyses) and were tested for their in vitro antimicrobial activity against bacterial and fungal organisms. 相似文献
49.
Single crystals of the title compound are obtained from a melt of U3O8, MoO3, and excess Cs2CO3 (Pt crucible, 950 °C, 12 h, cooling rate 5 °C/h). 相似文献
50.