全文获取类型
收费全文 | 158篇 |
免费 | 6篇 |
专业分类
化学 | 77篇 |
晶体学 | 3篇 |
力学 | 3篇 |
数学 | 13篇 |
物理学 | 68篇 |
出版年
2024年 | 1篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 4篇 |
2018年 | 5篇 |
2017年 | 1篇 |
2016年 | 6篇 |
2015年 | 5篇 |
2014年 | 4篇 |
2013年 | 13篇 |
2012年 | 14篇 |
2011年 | 12篇 |
2010年 | 8篇 |
2009年 | 10篇 |
2008年 | 11篇 |
2007年 | 10篇 |
2006年 | 9篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 2篇 |
1998年 | 4篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 3篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1976年 | 3篇 |
1971年 | 2篇 |
1965年 | 1篇 |
排序方式: 共有164条查询结果,搜索用时 31 毫秒
51.
Dr. Edmond Gravel Abha Harfouche Dr. Rim Salame Karine Leblanc Dr. Alexandre Maciuk Prof. Dr. Erwan Poupon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(43):14515-14520
Mixtures of tryptamine and reactive C5 units, presumably derived from lysine in nature, were studied to ascertain the spontaneous formation of the complex polycyclic alkaloid nitrarine. Several indolic compounds tracing the unified metabolism within the Nitraria genus were also characterized. 相似文献
52.
JPC – Journal of Planar Chromatography – Modern TLC - A new quantitative method using thin-layer chromatography silica gel 60F254 plates as the stationary phase and the mobile phase... 相似文献
53.
In the absence of an experimentally determined 3D structure of CDK4 (Cyclin-Dependent Kinase 4), QSARs (Quantitative Structure Activity Relationship) have been explored to rationalize binding affinity in terms of physicochemical and structural parameters. Further, docking on a homology model of CDK4 validated the derived QSARs and predicted the binding mode of this series of inhibitors. Relevant parameters and leave-one-out (LOO) cross-validation (q (2)) as well as an external test set validation (r (2) pred) judged the statistical significance and predictive ability of the models. Docking enabled a better understanding of protein-ligand interaction and provided a mechanistic interpretation in terms of physicochemical characteristics. It identified a unique hydrogen bonding between the imidazole of His-95 and the pyridine nitrogen in the ligand. It rationalized the need for R 2 substituents to be bulky and polar, while the substituent at R 8 to be hydrophobic and comparatively less steric. It also explained why at R 6 a variety of substituents are tolerated and how the presence of methyl at R 5 enhances binding affinity. 相似文献
54.
Phase inversion method is applied to prepare flat sheet asymmetric polymeric membranes from homogeneous solution of 12 wt% polysulfone (PSf) with two different solvents--N-methyl-2-pyrrolidone (NMP) and dimethyl acetamide (DMAc). 5.0 wt% polyethylene glycol (PEG) of three different molecular weight (400, 6000, and 20,000 Da) is used as the polymeric additives in the casting solution. Membranes are characterized by two different techniques viz. scanning electron microscopy (SEM) and gas permeation tests. Finally, the results of both the techniques are compared with those calculated from pure water permeation tests using Hagen-Poiseuille equation. It is found that though the values obtained from all the techniques vary from each other, their trend with increase in molecular weight of PEG seems to be the same. It is seen that when molecular weight of PEG increases from 400 to 20,000 Da, the mean pore size of the prepared membranes decreases, while the porosity and pore density show an increasing trend; the pressure normalized gas flux rises significantly and the thickness of the top layer of the prepared membrane sheet increases. 相似文献
55.
Two new copper(II) complexes {[Cu(H2biim)(H2O)(suc)](H2O)}n (1) and {[Cu(H2biim)2(H2O)][Cu(H2biim)2(glut)](glutH)(NO3) · 2.5H2O}n (2) (H2biim, 2,2′-biimidazole; suc, succinate dianion; glut, glutarate dianion) have been synthesized and characterized by single crystal X-ray diffraction study and thermal analysis. Complex 1 comprises of 1D zigzag coordination polymers, elongated along the crystallographic b-axis, connected through H-bonding and face-to-face π–π interactions to form a robust 3D network. Whereas complex 2 is built up of bischelated [Cu(II)(H2biim)2]2+ units, glutarate and nitrate anions and water molecules, held together through an extensive H-bonded system. The resulting 3D supramolecular architecture defines channels which are filled by lattice water molecules and disordered nitrate anions. 相似文献
56.
Asmahani Awang S.K. Ghoshal M.R. Sahar M. Reza Dousti Raja J. Amjad Fakhra Nawaz 《Current Applied Physics》2013,13(8):1813-1818
Glasses with composition 70TeO2–20ZnO–10Na2O–0.5Er2O3–(x)Au are synthesized by melt-quenching technique. Their spectroscopic and optical characterizations are made. The presence of gold nanoparticles (Au NPs) with average size ~9 nm is confirmed from TEM micrograph. The value of Edir is found to lie between 3.082 and 3.073 eV, while Eindir lies within 2.765 to 2.724 eV. The observed visible up-conversion (UC) emission under 779 nm excitation wavelength exhibits two bands centered at 546 nm (green) and 637 nm (red) in all samples. The glass with 0.4 mol% Au NPs shows dominant enhancement in the UC emission intensity of the order of 3.5 times for the green band (4S3/2 → 4I15/2) and a weaker enhancement for the red (4F9/2 → 4I15/2) band. The optical properties of the system are affirmed to depend strongly on the Au concentration in the dielectric medium. The absorption spectra consist of six bands attributed to absorption from ground state (4I15/2) to 4I13/2, 4I11/2, 4I9/2, 4F9/2, 2H11/2, and 4F7/2 excited states. The structural reveals that the types of bonding and difference in electro-negativity can be manipulated by the presence of metallic NPs in glass matrix. Judd–Ofelt analysis asserts the increase in Ω2 and Ω6 parameters with the addition of Au NPs and the enhancement of green and red emissions. The enhancement is mainly attributed to large plasmonic effect of Au NPs. The proposed glasses can be nominated as potential materials for solid state laser developments. 相似文献
57.
We have investigated the properties of hydrogen molecular ion (H) interacting with screened Coulomb potentials. Two types of potentials have been considered, namely, static screened Coulomb potential and exponential cosine‐screened Coulomb potential. Simulating the localized motion of the nuclei by using high powers of the internuclear coordinate in the generalized Hylleraas‐type wave function we have been able to obtain reasonably accurate binding energies for 11S(J = 0, ν = 0) and 21S(J = 0, ν = 1) states for various values of the screening parameter within the frame work of Ritz variational method. Borromean bindings are found to exist in the ion for a wide range of the screening parameter. Furthermore, expectation values for various operators and cusp condition have been calculated. Results for the unscreened case are in nice agreement with some of the accurate results available in the literature. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2010 相似文献
58.
Atanu Ghoshal Asit R. Sarkar R. Senthil kumaran Subramanya Hegde Govindaswamy Manickam Jayadevan Jayashankaran 《Tetrahedron letters》2012,53(14):1748-1752
We have reported here a facile stereoselective synthesis of julolidine hybrid analogs by employing domino Knoevenagel intramolecular hetero Diels–Alder reaction on symmetrical 1,3-diones and unsymmetrical 1,3-diones It was found that the cycloaddition proceeded efficiently under microwave irradiation to afford highly stereoselective cycloadducts in good yields 相似文献
59.
Sharma VK Sahare PD Rastogi RC Ghoshal SK Mohan D 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(8):1799-1804
The magnitude of the Stokes shift (frequency shifts in absorption and fluorescence spectra) is observed on changing the solvents and further has been used to calculate experimentally the dipole moments (ground state and excited state) of acriflavine and acridine orange dye molecules. Theoretically, dipole moments are calculated using PM 3 Model. The dipole moments of excited states, for both molecules investigated here, are higher than the corresponding values in the ground states. The increase in the dipole moment has been explained in terms of the nature of the excited state. Acriflavine dye overcomes the non-lasing behaviour of acridine orange due to quaternization of the central nitrogen atom. 相似文献
60.
Cadmium hydroxide (Cd(OH)2) and cadmium oxide (CdO) nano and micro crystals were synthesized in ethanol-water medium using cadmium foil both as a source and substrate under solvothermal condition. Different concentrations of ammonium hydroxide, hydrazine hydrate, sodium hydroxide and potassium hydroxide were added to study the structural and morphological variations in the products. Synthesis was carried out at different temperatures to study the growth stages of the nano/microstructures. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The as-prepared Cd(OH)2 products were transformed to CdO by thermal treatment in air. The possible growth mechanism for the formation of different morphologies at different basic medium has been proposed. The optical absorption measurement was carried out to determine the values of the band gap of CdO. 相似文献