Analytical solution of optimal Meixner-like pole

In this paper, we prove the possibility of optimization of some free parameters of Meixner-like discrete-time linear filters using orthonormal basis functions (OBF) in an analytical way. Since the z-transform of the Meixner filters is impossible and it is possible for Meixner-like filters, we are motivated to study closely the optimization of the Meixner-like's pole. As a result, the differential equation associated with Meixner-like filters has been developed. On the other hand, the effective width of the energy distribution in the transformation domain is a function of the free parameter (Meixner-like pole) and simple signal measurements and can be calculated by the second-order moment. Analytic minimization of the second-order moment gives an optimal value of the free parameter. To validate the effectiveness of the proposed approach, numerical results are used to determine the free parameters.     

Novel hybrid materials based on poly (4,4′-Diaminodiphenyl sulfone) and TiO2 nanoparticles: synthesis,characterization, physical and electrochemical properties

Research on Chemical Intermediates - Innovative hybrid composites based on poly (4,4'-Diaminodiphenyl sulfone) (PDDS) and TiO2 nanoparticles have been synthesized. The samples have been...     

Microwave-assisted palladium-catalyzed cross-coupling of aryl and vinyl halides with H-phosphonate diesters

A general and efficient method for the microwave-assisted formation of the C-P bond was developed. Using a prevalent palladium catalyst, Pd(PPh3)4, a quantitative cross-coupling of various H-phosphonate diesters with aryl and vinyl halides was achieved in less than 10 min. The reactions occurred with retention of configuration at the phosphorus center and in the vinyl moiety. Using this protocol, several C-phosphonates, including those bearing nucleoside and cholesteryl moieties, were prepared in high yields.     

Distances entre exponentielles et puissances d’éléments de certaines algèbres de Banach

Let A be a Banach algebra which does not contain any nonzero idempotent element, let γ > 0, and let . We show that if then . We also show, assuming a suitable spectral condition on x, that if , then Received: 12 July 2006 Revised: 31 January 2007     

Characterization of extracts from Papaver rhoeas and potential valorization of these extracts in dyeing applications

The aim of our work is to study the dyeing properties of extracts from natural sources such as Papaver rhoeas by modifying the conditions of the dyeing process, choosing other substrates that could be pretreated by innovative and environmentally friendly processes. The results obtained show a fairly high fixation of the extracts on the natural and artificial fibers. The use of mordants allowed the dye to be better fixed on the dyed fibers and to give several shades to the fabric. The rate of essential oil contained in Papaver rhoeas was considered important by the Clevenger process. Screening of extractive revealed the presence of polyphenols, saponins, sterols, alkaloids and flavonoids. In this study, the extractive from Papaver rhoeas was investigated as textile dyestuff.     

The Effect of Conducting Boundaries on the Onset of Convection in a Porous Layer Which is Heated from Below by Internal Heating

The onset of convection in a porous layer heated from below is considered, and we determine how the presence of two solid but heat-conducting bounding plates of finite thickness alters the manner in which convection ensues. Heat is generated by the lower plate (with an insulating lower boundary), but the upper one is passive with a fixed upper boundary temperature. It is shown that this composite layer may mimic in turn one of the three different types of classical single-layer onset problems which are well-known in the literature. The type which is selected (or indeed whether it corresponds to a transitional case) depends quite critically on the precise values of the relative thickness of the solid layers and their conductivity ratio. It is also shown that care needs to be taken over declaring that the solid plates are thin: extreme values of the conductivity ratio can yield a stability criterion which appears to be different from that suggested by the imposed boundary conditions.     

Synthesis and Molecular Structure Investigation by DFT and X-Ray Diffraction of ARNO

Abstract  

We report here the synthesis of (Z)-5-(4-nitrobenzyliden)-3-N(2-ethoxyphenyl)-2-thioxo-thiazolidin-4-one (ARNO) compound. The crystal structure has been determined by X-ray diffraction. The compound crystallizes in the triclinic system with space group P[`1] P\bar{1} and cell parameters: a = 9.1289(19), b = 9.3717(7), c = 12.136(3) ?, α = 102.133(11)°, β = 90.99(2)°, γ = 117.165(9)°, V = 895.4(3) ?³ and Z = 2. The structure has been refined to a final R = 0.05 for 2591 observed reflections. The refined structure was found to be significantly non planar. The molecule exhibits intermolecular hydrogen bond of type C–H⋯O and C–H⋯S. ab initio calculations were also were performed at Hartree–Fock and density functional theory levels. The full HF and DFT geometry optimization was carried out using LANL2DZ, 6-31G* and B3LYP/6-31+G** basis sets. The optimized geometry of the title compound was found to be consistent structure determined by X-ray diffraction. The minimum energy of geometrical structure is obtained by using level HF/LANL2DZ basis sets.     

First-principles calculations of adhesion,bonding and magnetism of the Fe/HfC interface

First-principles plane-wave pseudopotential calculations of the adhesion, bonding and magnetism of the interface between the ferromagnetic bcc Fe and non-magnetic HfC are performed. The work of adhesion for C- and Hf-site Fe/HfC interfaces is calculated. High adhesion at C-site interface is found and Fe–C polar covalent bonds are formed across the interface. The magnetic moments of Fe atoms at interface are increased in both interfaces. The effect of the magnetism on the electronic structure of Fe/HfC interface is also investigated. It is shown that the change in band of majority-spin leads to enhance the magnetic moment of Fe.     

Laminar bubbly flow in an open capillary channel in microgravity

The study of a bubbly laminar two-phase flow in an open capillary channel under microgravity conditions was conducted aboard the sounding rocket, Texus-45. The channel consists of two parallel plates of width b = 25 mm and distance a = 10 mm. The flow along the length l = 80 mm is confined by a free surface on one side and a plate on the opposite side. The bubbles are injected at the nozzle of the capillary channel via six capillary tubes of 100 μm in inner diameter. Different liquid and gas flow rates were tested leading to different liquid free surface shape and bubble size.     

Control analysis for water quality problem

The optimal control of water quality model is considered. We analyze a regularized version of the pointwise control. A numerical algorithm is presented. The solution approach is a combination of a TVD scheme for the shallow water equations and a purley deterministic particle method for the pollutant problem. We present some computational results. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)