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61.
    
The efficiency of charge transfer at the interface of transition metals loaded on TiO2 as well as the active reduction site undoubtedly define the kinetics of H2 production. Here, we report the interfacial charge process of various transition metals (Fe, Ni, Cu, and Au) embedded in mesoporous core-shell nanostructures, which provides further insight into the photocatalytic H2 evolution. Au was found to be the most active cocatalyst for the H2 evolution. Au nanoparticles (NPs) collect electrons and become a very efficient reduction site, promoting both charge separation and H2 evolution. The scavenging capacity of Au was found to be the highest compared to other NPs. Cu(I), which is as active as Au, but at a higher loading, also shows an ability for electron scavenging and acts as an active site under UV excitation, or rather injects electrons into the TiO2 conduction band under visible excitation. Ni(II) NPs were found to be involved in charge-carrier separation through hole collection and their contribution to hydrogen evolution is expected to be limited to visible absorption and electron injection. The same behavior occurs with Fe(III), however, it is less efficient for H2 generation due to the weak charge-carrier lifetime. We show that only Cu(I) could compete with noble metals such as Au, presenting electron-scavenging behavior. Understanding the charge-carrier dynamics will help design a very efficient system for photocatalytic H2 generation system.  相似文献   
62.
A recent nonlinear alternative for contraction maps in Frechet spaces due to Frigon and Granas (Resultats de type Leray-Schauder pour des contractions sur des espaces de Frechet, Ann. Sci. Math. Quebec 22, (2), 161-168 (1998)), combined with semigroup theory, is used to investigate the existence and uniqueness of mild solutions for first- and second-order functional semi linear and neutral damped differential equations in Frechet space.  相似文献   
63.
In this article, we study the existence of mild solutions to stochastic impulsive evolution equations with time delays, driven by fractional Brownian motion with the Hurst index H > 1/2 via a new fixed point analysis approach.  相似文献   
64.
We report here a novel direct method for the syntheses of primary aminoalkyl methacrylamides that requires mild reagents and no protecting group chemistry. The reversible addition‐fragmentation chain transfer polymerization (RAFT) of the aminoalkyl methacrylamide revealed to be highly efficient with 4‐cyanopentanoic acid dithiobenzoate (CTP) as chain transfer agent and 4,4′‐azobis(4‐cyanovaleric acid) (ACVA) as initiator. Cationic amino‐based homopolymers of reasonably narrow polydispersities (Mw/Mn < 1.30) and predetermined molecular weights were obtained without recourse to any protecting group chemistry. A range of block and random copolymers were also synthesized via the RAFT process. The homopolymers and copolymers were characterized by aqueous conventional and triple detection gel permeation chromatography systems. Furthermore, the primary amine‐based methacrylamide monomers and polymers revealed to be highly stable both with the primary amino group in the protonated and deprotonated form. We have also demonstrated that stabilized gold nanoparticles can be generated with the RAFT‐synthesized amine‐based polymers via a photochemical process. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4984–4996, 2008  相似文献   
65.
A detailed study about the synthesis, characterization and properties of poly(o-methylaniline)(PoMea)/maghnite nanocomposites has been performed. Changes in the characteristics of the nanocomposites, depending on the intercalated cation between the clay layers before the synthesis, have been observed. Intercalated morphology has been detected by TEM in nanocomposites containing copper-treated maghnite (Magh-Cu), while when maghnite treated with strong acids was used (Magh-H); an exfoliated material has been obtained. Also, remarkable differences in the properties of the polymers have been observed by TG-MS and FTIR, suggesting that the polymer produced with Magh-H has a higher degree of branching. The electrochemical behavior of the polymers extracted from the nanocomposites has been studied by cyclic voltammetry. Good electrochemical response has been observed for PoMea grown into Magh-Cu but not for the one polymerized into Magh-H.  相似文献   
66.
In this paper, we discuss local and global existence and uniqueness results for first order impulsive functional differential equations with multiple delay. We shall rely on a nonlinear alternative of Leray–Schauder. For the global existence and uniqueness we apply a recent nonlinear alternative of Leray–Schauder type in Fréchet spaces, due to M. Frigon and A. Granas [Résultats de type Leray–Schauder pour des contractions sur des espaces de Fréchet, Ann. Sci. Math. Québec 22 (2) (1998) 161–168]. The goal of this paper is to extend the problems considered by A. Ouahab [Local and global existence and uniqueness results for impulsive differential equations with multiple delay, J. Math. Anal. Appl. 323 (2006) 456–472].  相似文献   
67.
We announce the following result: every maximal globally hyperbolic 3-dimensional spacetime with compact Cauchy surface, and with nonpositive constant curvature admits a unique time function whose fibers are constant mean curvature surfaces. We discuss the extension of this result in higher dimensions. To cite this article: T. Barbot et al., C. R. Acad. Sci. Paris, Ser. I 336 (2003).  相似文献   
68.
Consider a single server queueing system with several classes of customers, each having its own renewal input process and its own general service times distribution. Upon completing service, customers may leave, or re-enter the queue, possibly as customers of a different class. The server is operating under the egalitarian processor sharing discipline. Building on prior work by Gromoll et al.?(Ann. Appl. Probab. 12:797?C859, 2002) and Puha et al.?(Math. Oper. Res. 31(2):316?C350, 2006), we establish the convergence of a properly normalized state process to a fluid limit characterized by a system of algebraic and integral equations. We show the existence of a unique solution to this system of equations, both for a stable and an overloaded queue. We also describe the asymptotic behavior of the trajectories of the fluid limit.  相似文献   
69.
    
The design of dendrimers with various chromophores has attracted significant attention in light of the dual effect of the luminescence of the chromophores and the morphology of the synthesized dendrimers. Recent developments in this field stem from their wide potential applications, including organic light‐emitting diodes, photonic switches and upconversion lasers, as well as sensors and electronic devices. The focus of this comprehensive review is on the design and properties of various classes of light‐harvesting dendrimeric materials.  相似文献   
70.
The reaction of polyamines with phosphorous acid and formaldehyde in water under focused microwave irradiation provides a facile and rapid synthesis of poly(aminomethylenephosphonic) acids.  相似文献   
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