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91.
Zakaria Benzekri Sara Sibous Houda Serrar Ali Ouasri Said Boukhris Ali Rhandour Abdelaziz Souizi 《Journal of the Iranian Chemical Society》2018,15(12):2781-2787
In this work, the condensation of aromatic aldehydes with different two-substituted aniline catalyzed by NH3(CH2)5NH3BiCl5 as heterogeneous and recyclable catalyst was reported. It was demonstrated that NH3(CH2)5NH3BiCl5 can act as an efficient and active catalyst and is reusable for six runs without a significant loss of their catalytic activity. Simple preparation of the catalyst, high catalytic activity and good reusability are noteworthy advantages of this catalytic system in the synthesis of benzoxazole, benzimidazole and benzothiazole heterocycles at room temperature under solvent-free conditions. 相似文献
92.
Soraa Bouattour Taher Mhiri Abdelwaheb W. Kolsi Abdelaziz Daoud 《Journal of chemical crystallography》1998,28(5):335-338
The structure of Rb0.7(NH4)0.3HSO4 has been determined by X-ray analysis. The mixed compound crystallizes in the monoclinic space group P21/n with unit cell parameters a = 14.374(6) Å, b = 4.618(6) Å, c = 14.412(2) Å, = 118.03(2)°, V = 844.4(4) Å3, and D
cal = 1.536 g cm–3 for Z = 8. The mixed compound Rb0.7(NH4)0.3HSO4 is a chain-based structure. The Rb+ and NH4
+ cations are intercalated between chains, formed of HSO4
- groups linked with OHO hydrogen-bonding. Rb0.7(NH4)0.3HSO4 presents a new type of structural arrangement different from those of pure RbHSO4 and NH4HSO4. 相似文献
93.
Zakaria Benzekri Khalid El Mejdoubi Brahim Sallek Brahim Lakhrissi Abdelaziz Souizi 《合成通讯》2016,46(5):442-451
We have described the catalytic activities of dicalcium phosphate dihydrate (DCPD) in the condensation reaction of various substituted benzaldehydes with active methylene compound malononitrile. The influences of reaction conditions on the corresponding catalytic behavior have been investigated. The results showed that the DCPD exhibited high catalytic activity and versatility and that it can be recycled without significant loss of its activity for the condensation reactions, which shows the material is a promising new type of heterogeneous catalyst for the condensation reactions. Meanwhile, the catalytic results of DCPD compared favorably with those of other materials for Knoevenagel reactions reported previously. 相似文献
94.
Swapnil Chavan Ahmed Abdelaziz Jesper G. Wiklander Ian A. Nicholls 《Journal of computer-aided molecular design》2016,30(3):229-236
A series of 172 molecular structures that block the hERG K+ channel were used to develop a classification model where, initially, eight types of PaDEL fingerprints were used for k-nearest neighbor model development. A consensus model constructed using Extended-CDK, PubChem and Substructure count fingerprint-based models was found to be a robust predictor of hERG activity. This consensus model demonstrated sensitivity and specificity values of 0.78 and 0.61 for the internal dataset compounds and 0.63 and 0.54 for the external (PubChem) dataset compounds, respectively. This model has identified the highest number of true positives (i.e. 140) from the PubChem dataset so far, as compared to other published models, and can potentially serve as a basis for the prediction of hERG active compounds. Validating this model against FDA-withdrawn substances indicated that it may even be useful for differentiating between mechanisms underlying QT prolongation. 相似文献
95.
In this paper, simple analytical state-to-state rate coefficients for the dissociation–recombination and chemical exchange reactions are presented on the basis of kinetic theory in nonequilibrium excited diatomic gases. They take into account the excited vibrational and electronic states of the chemical species and are expressed according to the preferential character of the chemical reactions. Evolution of these rate coefficients varying according to the translational temperature, bringing into play molecules CO and C2, are discussed. 相似文献
96.
This paper presents a review of the extended finite element method X-FEM for computational fracture mechanics. The work is dedicated to discussing the basic ideas and formulation for the newly developed X-FEM method. The advantage of the method is that the element topology need not conform to the surfaces of the cracks. Moreover, X-FEM coupled with LSM makes possible the accurate solution of engineering problems in complex domains, which may be practically impossible to solve using the standard finite element method. 相似文献
97.
Pigni NB Berkov S Elamrani A Benaissa M Viladomat F Codina C Bastida J 《Molecules (Basel, Switzerland)》2010,15(10):7083-7089
The Amaryllidaceae family is well known for the presence of an exclusive group of alkaloids with a wide range of biological activities. Narcissus serotinus L. is a plant belonging to this family and its geographical distribution is mainly located along the Mediterranean coast. In the present work, specimens collected near Casablanca (Morocco) were used to study the alkaloid content of this species. Starting with 350 g of the whole plant we used standard extraction and purification procedures to obtain fractions and compounds for GC-MS and NMR analysis. As well as five known alkaloids, we isolated two new compounds: 1-O-(3′-acetoxybutanoyl)lycorine and narseronine. The latter has been previously published, but with an erroneous structure. 相似文献
98.
Fouad Ben Abdelaziz 《European Journal of Operational Research》2012,216(1):1-16
We survey in this paper various solution approaches for multiobjective stochastic problems where random variables can be in both objectives and constraints parameters. Once a problem requires a stochastic formulation, a first step consists in transforming the problem into its deterministic formulation. We propose to classify and evaluate such transformations with regards to the many proposed concepts of efficiency. The paper addresses also some applications of the multiobjective stochastic programming models. 相似文献
99.
100.