首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   445篇
  免费   9篇
  国内免费   3篇
化学   258篇
力学   18篇
数学   70篇
物理学   111篇
  2024年   1篇
  2023年   5篇
  2022年   30篇
  2021年   22篇
  2020年   16篇
  2019年   13篇
  2018年   14篇
  2017年   9篇
  2016年   16篇
  2015年   7篇
  2014年   12篇
  2013年   34篇
  2012年   29篇
  2011年   37篇
  2010年   24篇
  2009年   14篇
  2008年   24篇
  2007年   10篇
  2006年   14篇
  2005年   12篇
  2004年   13篇
  2003年   14篇
  2002年   8篇
  2001年   11篇
  2000年   7篇
  1999年   2篇
  1998年   5篇
  1997年   7篇
  1996年   2篇
  1995年   4篇
  1994年   3篇
  1992年   3篇
  1991年   2篇
  1990年   4篇
  1989年   1篇
  1988年   4篇
  1987年   3篇
  1985年   8篇
  1984年   2篇
  1982年   3篇
  1981年   1篇
  1980年   1篇
  1978年   1篇
  1976年   1篇
  1975年   2篇
  1973年   2篇
排序方式: 共有457条查询结果,搜索用时 14 毫秒
141.
Watermarking is a solution to the problem of copyright protection of multimedia documents over the Internet. This paper presents a block based watermarking scheme using the singular value decomposition (SVD) algorithm to embed encrypted watermarks into digital images. The paper compares between the traditional method of Liu and the proposed method for embedding encrypted watermarks. Also, a permutation based encryption algorithm and a diffusion based encryption algorithm are compared as the watermark encryption algorithms. Experimental results show that the proposed method is superior to the traditional method of Liu for embedding encrypted watermarks and extracting them efficiently under attacks. Results also show that it is preferred to use permutation based encryption algorithms than diffusion based encryption algorithms for watermark encryption due to their lower sensitivity to attacks.  相似文献   
142.
This Letter reports on a search for narrow high-mass resonances decaying into dilepton final states. The data were recorded by the ATLAS experiment in pp collisions at √s=7 TeV at the Large Hadron Collider and correspond to a total integrated luminosity of 1.08 (1.21) fb(-1) in the e(+)e(-) (μ(+)μ(-)) channel. No statistically significant excess above the standard model expectation is observed and upper limits are set at the 95% C.L. on the cross section times branching fraction of Z' resonances and Randall-Sundrum gravitons decaying into dileptons as a function of the resonance mass. A lower mass limit of 1.83 TeV on the sequential standard model Z' boson is set. A Randall-Sundrum graviton with coupling k/M(Pl)=0.1 is excluded at 95% C.L. for masses below 1.63 TeV.  相似文献   
143.
International Journal of Theoretical Physics - Federated Learning (FL) is a promising paradigm, where the local users collaboratively learn models by repeatedly sharing information while the data...  相似文献   
144.
The development of a stereoselective one‐pot oxidative [3,3] sigmatropic rearrangement/Friedel–Crafts arylation that provides enantioenriched benzhydryl compounds is reported. The utility of this new transformation is demonstrated by the concise synthesis of several tetralone‐ and naphthyl‐type lignan natural products, many of which display anti‐malarial activity.  相似文献   
145.
A specific spectrophotometric method was developed for the determination of p-aminophenol and acetaminophen. The method is based on the reaction of p-aminophenol at ambient temperature with sodium sulphide in presence of an oxidant to produce a methylene blue-like dye. Different oxidizing agents were tried, e.g. Ce(IV) and Fe(III). The colour developed within 10 min and remained stable for at least 3 h. The method was applied successfully to the determination of p-aminophenol in the presence of acetaminophen without prior separation. The method was also applied to the analysis of various commercially available acetaminophen dosage forms and excellent recoveries were obtained comparable to those obtained by official procedures. The reaction product was isolated and a possible reaction mechanism was suggested.  相似文献   
146.
The objective of the present study is to identify possible adsorption configurations of pyrrole on Mo(110) using density functional theory (DFT) calculations. Several adsorption configurations were studied including pyrrole and pyrrolyl adsorption as parallel, perpendicular, and tilted adsorption modes relative to the Mo(110) surface plane. Based on the DFT calculations, pyrrole is suggested to adsorb in a parallel mode with respect to the Mo(110) surface through its pi-orbital as mu3,eta(5)-Pyr-0 degrees with an adsorption energy of -28.7 to -31.5 kcal mol(-1). The possibility of a coexisting mode where pyrrole adsorbs on the surface with a slightly tilted molecular plane as mu3,eta(4)(N,C2,C3,C4)-Pyr-5 degrees is also likely to occur, particularly at higher pyrrole coverages. The slightly tilted configuration is suggested to arise from the lateral interactions of adsorbed pyrrole on Mo(110), and not the result of a phase transformation on the surface since this requires a relatively high activation energy as indicated by additional linear synchronous transit (LST)/quadratic synchronous transit (QST) calculations. Both adsorption geometries bond to three surface Mo atoms, and Mo(110) did not promote hydrogen abstraction. Pyrrolyl adsorption on Mo(110) is energetically possible, but unlikely to occur because gas-phase hydrogen has not been previously experimentally observed as a pyrrole decomposition product on Mo(110).  相似文献   
147.
Makkah city, Saudi Arabia, represents the most attractive place for religious tourism for Muslims all over the world. More than 15 million visitors come to the city per year, especially during Hajj (pilgrimage) and Ramadan seasons. Due to the lack of air quality assessment data for Makkah, measurement of different pollutants in Makkah is of great interest. In the present work, airborne particulate matter with aerodynamic diameter equal to or less than 2.5 µm (PM2.5) has been collected from two different sites in the city, namely the Grand mosque and Al‐Shraie, from December 2012 to January 2014 covering the different seasons of the year. The average mass concentrations at the sites are comparable, 48 ± 28 µg/m3 and 53 ± 27 µg/m3 for the Grand mosque and Al‐Shraie sites, respectively. For quantitative elemental analysis, energy dispersive X‐ray fluorescence (EDXRF) spectrometry was used. Twenty elements (Si, S, Cl, K, Ca, Sc, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Se, Br, Rb, Sr and Pb) were quantified in the PM2.5 samples. Fortunately, the obtained results of Pb and S are below the maximum allowance level of European commission for air quality. However, the average concentration of Ni in both sites is close to the maximum allowance level 20 ng/m3 and the Ni concentration reaches 25 ng/m3 at Grand mosque site during August 2013. Based on the Positive Matrix Factorization (PMF) analysis, four source factors were found, some signalling mixed sources, showing the main influence from mineral dust, anthropogenic/industrial sources and a marine source. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
148.
Journal of Thermal Analysis and Calorimetry - Polymorphic transformation in Trimethoprim (TMP) drug has been studied employing differential scanning calorimetry (DSC), TG/DSC, X-ray diffraction and...  相似文献   
149.
150.
We report on atomic kinetics and X-ray line spectra modeling work of plasmas generated by high-intensity, ultrashort-duration pulsed lasers. Our work is motivated by the need to analyze and interpret experiments with laser-irradiated layered targets performed at the Max-Planck-Institut für Quantenoptik. The focus of this Paper is on the theoretical characterization of the properties of X-ray line emissions as signatures of plasma conditions. Our model considers several spectral features with detailed attention paid to atomic kinetics, intrinsic spectral lineshapes in a high-density plasma environment (in particular Stark broadening and line shift effects), and spectroscopic-quality radiation transport (opacity effects). We apply our model to the analysis of time-integrated K-shell aluminum X-ray line spectra and time-resolved total line intensities obtained from the layered targets. Modeling calculations indicate that red line shifts observed in these experiments cannot be explained by shifts in the centers of gravity of composite spectral features due to blending with enhanced satellite contributions, but are consistent with intrinsic line shift effects in both resonance and satellite lines. We also investigate the sensitivity of our results to the selection of one of three adopted models for laser-energy deposition and transport within the target.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号