全文获取类型
收费全文 | 1508篇 |
免费 | 82篇 |
国内免费 | 12篇 |
专业分类
化学 | 1030篇 |
晶体学 | 10篇 |
力学 | 72篇 |
综合类 | 4篇 |
数学 | 225篇 |
物理学 | 261篇 |
出版年
2023年 | 10篇 |
2022年 | 57篇 |
2021年 | 64篇 |
2020年 | 37篇 |
2019年 | 48篇 |
2018年 | 59篇 |
2017年 | 44篇 |
2016年 | 84篇 |
2015年 | 72篇 |
2014年 | 67篇 |
2013年 | 158篇 |
2012年 | 99篇 |
2011年 | 110篇 |
2010年 | 95篇 |
2009年 | 79篇 |
2008年 | 81篇 |
2007年 | 74篇 |
2006年 | 47篇 |
2005年 | 47篇 |
2004年 | 43篇 |
2003年 | 28篇 |
2002年 | 19篇 |
2001年 | 11篇 |
2000年 | 10篇 |
1999年 | 4篇 |
1998年 | 12篇 |
1996年 | 12篇 |
1995年 | 4篇 |
1994年 | 3篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 4篇 |
1990年 | 11篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 7篇 |
1984年 | 8篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 11篇 |
1975年 | 7篇 |
1974年 | 4篇 |
1973年 | 3篇 |
1972年 | 3篇 |
排序方式: 共有1602条查询结果,搜索用时 15 毫秒
81.
Arash Shokrolahi Abbas Zali 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):454-460
Abstract Sulfonated condensed polynuclear aromatic (S-COPNA) resin was found to be a highly efficient, environmentally friendly, recyclable heterogeneous catalyst for the oxidation of alkyl and aryl sulfides to the corresponding sulfoxides or sulfones, in good yields under mild reaction conditions using 30% hydrogen peroxide as an oxidant. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental resource: Synthesis of the S-COPNA resin catalyst. Spectroscopic data for compounds. 相似文献
82.
Abbas Shockravi Esmael Rostami Ali Dehjurian Rahim Tohidi Samad Bavili Tohidi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3):535-541
Bis(dibenzosulfoxo)-27,30,35,38-tetramethyl-24-crown-6, bis(dibenzosulfoxo)-21,24,29,32-tetramethyl-18-crown-4, dibenzosulfoxo-15,18-dimethyl-12-crown-3 and dibenzosulfoxo-12,15-dimethyl-9-crown-2 macrocycles are synthesized by the reaction of 2,2′-sulfinyl-bis(4-methyl phenol)and 1,2-dibromoethane and diethyleneglycol di-p-toluenesulfonate. 相似文献
83.
Ardeshir Khazaei Shahnaz Saednia Javad Saien Masoumeh Kiani Abbas Afkhami 《Supramolecular chemistry》2013,25(2):88-93
The grafting of 4-amino benzo-9-crown-3 ether to poly (styrene-alt-maleic anhydride) has been described. The covalent grafting of crown ether has led to a considerable increase in the solubility of polymer in organic solvents such as dimethyl sulphoxide, dimethylformamide and tetrahydrofuran. The highest solubility was attained in DMF and DMSO. The covalently bonded 4-benzo-9-crown-3 ether allowed the hosting of Li+. The covalently grafted crown ether to polymer was identified by infrared spectroscopy and thermogravimetric analysis methods. 相似文献
84.
Hossein Reza Darabi Abbas Darestani Farahani Mohammad Hashemi Karouei Kioumars Aghapoor Rohoullah Firouzi Rainer Herges 《Supramolecular chemistry》2013,25(9):653-657
A new E,E-stilbenophane was synthesised and characterised. The crystal structure of this cyclophane shows that this molecule has a cup-shaped structure, which hosts a phenyl ring of neighbouring molecule as guest in its cavity with a π–π distance of about 3.7 Å. Moreover, the NMR spectra and theoretical analysis (gauge-independent atomic orbitals (GIAO) and quantum theory of atoms in molecules (QTAIM)) suggest that the silver recognition by E,E-stilbenophane host molecules is based on cation–π interactions in which the π-electrons of the double bonds play a major role. 相似文献
85.
The non-isothermal differential scanning calorimetry (DSC) experiments revealed that linkage isomerization of both pure trans-[Co(en)2(ONO)2]PF6 (dinitrito isomer) and trans-[Co(en)2(NO2)2]PF6 (dinitro isomer) occurs in the solid state at elevated temperatures. The process was found to be exothermic for the dinitrito isomer and endothermic for dinitro isomer. The pure isomers could be considered to be in metastable states at ambient temperatures which would be converted to an equilibrium mixture of both isomers (stable state) upon heating. Since the isomerization of both isomers may be described as a two stages process, the corresponding DSC peaks have been resolved into two peaks by means of nonlinear curve fitting tools of PeakFit® software. The resolution of the peaks helped us to determine enthalpy changes of stepwise isomerization of both isomers. A first-order initial rate and Kissinger methods have been employed to estimate kinetic parameters of the stepwise isomerization reactions. The Kissinger method provided more reliable kinetic results. The high activation energy and positive entropy changes of isomerization of both isomers are considered as indication of a dissociative mechanism in solid state. 相似文献
86.
Elaheh Esmaeili Ali Morad Rashidi Yadollah Mortazavi Abbas Ali Khodadadi Mehdi Rashidzadeh 《天然气化学杂志》2013,(5):717-725
In the present study,CNFs,ZnO and Al2O3 were deposited on the SMFs panels to investigate the deactivation mechanism of Pd-based catalysts in selective acetylene hydrogenation reaction.The examined supports were characterized by SEM,NH3-TPD and N2adsorption-desorption isotherms to indicate their intrinsic characteristics.Furthermore,in order to understand the mechanism of deactivation,the resulted green oil was characterized using FTIR and SIM DIS.FTIR results confirmed the presence of more unsaturated constituents and then,more branched hydrocarbons formed upon the reaction over alumina-supported catalyst in comparison with the ones supported on CNFs and ZnO,which in turn,could block the pores mouths.Besides the limited hydrogen transfer,N2 adsorption-desorption isotherms results supported that the lowest pore diameters of Al2O3/SMFs close to the surface led to fast deactivation,compared with the other catalysts,especially at higher temperatures. 相似文献
87.
Growth orientation of fluorapatite–zirconia nanopowders was investigated after mechanical activation and thermal annealing process in the range of 600–1,300 °C for 1 h. Results revealed that during heating of the composite nanopowders the transition of the monoclinic zirconia to tetragonal form and its stabilization by calcium fluoride originating from the decomposition of fluorapatite as well as the formation of a solid solution of calcium fluoride in zirconia occurred. The influence of annealing on the growth orientation of fluorapatite–zirconia composite nanopowders indicated that the crystal growth of fluorapatite was preferentially accentuated on the (002) face in the direction of the crystallographic c-axis after heat treatment. Based on FE–SEM observations, the experimental outcome was composed of both agglomerates and fine particles (~33 nm) after 600 °C, while annealing of the sample at 1,300 °C demonstrated the occurrence of abnormal grain growth. 相似文献
88.
Alireza Najafi Chermhini Hossein Farrokhpour Abbas Teimouri Fatemah Pourmoghaddas 《Structural chemistry》2013,24(4):1215-1227
The tautomerism of all possible forms of imidazole selenone (ISe1–ISe6), induced by proton transfer was studied theoretically in different environments including gas phase, continuum solvent, and microhydrated environment with one explicit water molecule. The calculations were performed at the MP2 and CAM-B3LYP levels of theory, separately. It was found that the imidazole selenone, in the form of ISe3, is the most stable isomer in both gas phase and solvent. The activation energy for conversion of ISe3 to imidazole selenol (ISe6), as the second stable form, is 41.72 and 43.0 kcal/mol in the gas phase and water, respectively. The infrared spectral frequencies as well as the vibrational frequency shifts were reported and assigned to their corresponding vibrational modes. In addition, the variation of dipole moments and charges on the atoms with change of solvent was studied. The energies of HOMO, LUMO, and HOMO–LUMO gap were calculated in both gas phase and solvent. Specific solvent effects with addition of water molecule near the electrophilic centers of tautomers and the transition states of proton transfer, assisted by water molecule, were investigated. It was found that the water molecule can form different hydrogen bonds with the molecule. Aggregation of the isomers with water molecule does not change the order of stability of isomers, but proton transfer reaction assisted by a water molecule needs less energy than when the proton shifts through the intramolecular process. 相似文献
89.
90.
Abbas Rahmati Ali Hossein Rezayan Meysam Alizadeh Ali Nikbakht 《Journal of the Iranian Chemical Society》2013,10(3):521-525
A simple and eco-friendly synthesis of the biologically important spirooxindole scaffold was done by the reaction of isatin with activated pyrazolones in the presence of a catalytic amount of p-toluenesulfonic acid in water at room temperature. A variety of symmetrical spirooxindole derivatives were obtained with excellent yields within short reaction time. This method is of great value because of its environmentally benign character, high yield, and easy handling. 相似文献