全文获取类型
收费全文 | 722763篇 |
免费 | 7171篇 |
国内免费 | 2065篇 |
专业分类
化学 | 365505篇 |
晶体学 | 10678篇 |
力学 | 36166篇 |
综合类 | 20篇 |
数学 | 96430篇 |
物理学 | 223200篇 |
出版年
2021年 | 6526篇 |
2020年 | 7007篇 |
2019年 | 7914篇 |
2018年 | 10609篇 |
2017年 | 10876篇 |
2016年 | 15141篇 |
2015年 | 8545篇 |
2014年 | 14184篇 |
2013年 | 33116篇 |
2012年 | 25478篇 |
2011年 | 30462篇 |
2010年 | 22591篇 |
2009年 | 22537篇 |
2008年 | 28417篇 |
2007年 | 28103篇 |
2006年 | 25760篇 |
2005年 | 22945篇 |
2004年 | 21301篇 |
2003年 | 19109篇 |
2002年 | 18979篇 |
2001年 | 20983篇 |
2000年 | 16021篇 |
1999年 | 12482篇 |
1998年 | 10637篇 |
1997年 | 10404篇 |
1996年 | 9744篇 |
1995年 | 8705篇 |
1994年 | 8651篇 |
1993年 | 8345篇 |
1992年 | 8954篇 |
1991年 | 9500篇 |
1990年 | 9063篇 |
1989年 | 8934篇 |
1988年 | 8553篇 |
1987年 | 8509篇 |
1986年 | 8117篇 |
1985年 | 10362篇 |
1984年 | 10784篇 |
1983年 | 9021篇 |
1982年 | 9310篇 |
1981年 | 8734篇 |
1980年 | 8425篇 |
1979年 | 9038篇 |
1978年 | 9276篇 |
1977年 | 9115篇 |
1976年 | 9041篇 |
1975年 | 8675篇 |
1974年 | 8511篇 |
1973年 | 8808篇 |
1972年 | 6321篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
Gustavo A.Carri 《高分子科学》2015,33(4):523-539
We revisit the Simha-Somcynsky model of polymer fluids with the purpose of developing novel theoretical and computational approaches to simplify and speed up its solution as well as the fitting of experimental data, and decrease its level of mathematical complexity. We report a novel method that allows us to solve one of the two equations of the model exactly, thus putting the level of mathematical difficulty on a par with the one of other models for polymer fluids. Moreover, we describe a computational algorithm capable of fitting all five parameters of the model in an unbiased way. The results obtained reproduce literature results and fit experimental pressure-volume-temperature and solubility parameter data for three polymers very accurately. Moreover, the new techniques allow for the investigation of the model at very low temperatures. Unexpectedly, the model predicts behaviors that could be interpreted as a glass transition, as routinely observed in dilatometry and differential scanning calorimetry, and a glass phase. We compared the predicted and experimental T g’s for cis poly(1,4-butadiene) and found an excellent quantitative agreement. 相似文献
92.
Galkina E. G. Zaspel C. E. Ivanov B. A. Kulagin N. E. Lerman L. M. 《JETP Letters》2019,110(7):481-486
JETP Letters - The motion of domain walls in GdFeCo-type ferrimagnets near the point of compensation of sublattice spins s1 and s2, when the effects of the exchange increase in the limiting wall... 相似文献
93.
94.
K.M.J. Rocha R.G. Leitão E.G. Oliveira-Barros M.A. Oliveira C.G.L. Canellas M.J. Anjos L.E. Nasciutti R.T. Lopes 《X射线光谱测定》2019,48(5):476-481
Prostate cancer is a highly prevalent disease and ranks second among malignant neoplasms that affect men around the world, behind lung cancer alone. Trace elements are very important and are involved in many cellular processes. The X-ray microfluorescence technique is an advanced tool of high spatial resolution, sensitivity, multielemental analysis, and nondestructiveness for trace element study. This study aimed to investigate the elemental distribution in spheroids obtained through the following human prostate cell lines using synchrotron X-ray microfluorescence: tumor cell line androgen independent (DU145), tumor cell line androgen dependent (LNCaP), and normal cell line (RWPE-1). The measurements were performed with a standard geometry of 45° of incidence, excited by a white beam using a pixel of 25 μm and an acquisition time of 300 ms/pixel at the X-ray fluorescence beamline at the Synchrotron Light National Laboratory (Campinas, Brazil). The synchrotron X-ray microfluorescence results showed differences between groups in all elements analyzed and suggested that further studies should be performed to understand the relationship of these trace elements with the progression and development of the disease. 相似文献
95.
Dr. Jun Zeng Dr. Zhichao Wang Dr. Xin Huang Dr. Sabine S. Eckstein Prof. Dr. Xiaohui Lin Prof. Dr. Hailong Piao Prof. Dr. Cora Weigert Dr. Peiyuan Yin Prof. Dr. Rainer Lehmann Prof. Dr. Guowang Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5427-5432
Mass spectrometry (MS) driven metabolomics is a frequently used tool in various areas of life sciences; however, the analysis of polar metabolites is less commonly included. In general, metabolomic analyses lead to the detection of the total amount of all covered metabolites. This is currently a major limitation with respect to metabolites showing high turnover rates, but no changes in their concentration. Such metabolites and pathways could be crucial metabolic nodes (e.g., potential drug targets in cancer metabolism). A stable-isotope tracing capillary electrophoresis–mass spectrometry (CE-MS) metabolomic approach was developed to cover both polar metabolites and isotopologues in a non-targeted way. An in-house developed software enables high throughput processing of complex multidimensional data. The practicability is demonstrated analyzing [U-13C]-glucose exposed prostate cancer and non-cancer cells. This CE-MS-driven analytical strategy complements polar metabolite profiles through isotopologue labeling patterns, thereby improving not only the metabolomic coverage, but also the understanding of metabolism. 相似文献
96.
97.
98.
Ivanov K. A. Gubaidullin A. R. Morozov K. M. Sasin M. E. Kaliteevskii M. A. 《Optics and Spectroscopy》2019,126(6):787-787
Optics and Spectroscopy - 10.1134/S0030400X17050095 相似文献
99.
Kaplunov I. A. Kolesnikov A. I. Kropotov G. I. Rogalin V. E. 《Optics and Spectroscopy》2019,126(3):191-194
Optics and Spectroscopy - The transmission of intrinsic, antimony-doped, and gallium-doped Ge single crystals in the THz spectral range have been experimentally investigated. It is shown that the... 相似文献
100.
Dr. Liat Avram Dr. Václav Havel Ronit Shusterman-Krush Dr. Mark A. Iron Dr. Moritz Zaiss Prof. Vladimír Šindelář Dr. Amnon Bar-Shir 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1687-1690
The accumulated knowledge regarding molecular architectures is based on established, reliable, and accessible analytical tools that provide robust structural and functional information on assemblies. However, both the dynamicity and low population of noncovalently interacting moieties within studied molecular systems limit the efficiency and accuracy of traditional methods. Herein, the use of a saturation transfer-based NMR approach to study the dynamic binding characteristics of an anion to a series of synthetic receptors derived from bambusuril macrocycles is demonstrated. The exchange rates of BF4− are mediated by the side chains on the receptor (100 s−1<kex<5000 s−1), which play a critical role in receptor-anion binding dynamics. The signal amplification obtained with this approach allows for the identification of different types of intermolecular interactions between the receptor and the anion, something that could not have been detected by techniques hitherto used to study molecular assemblies. These findings, which are supported by a computational molecular dynamic study, demonstrate the uniqueness and added value of this NMR method. 相似文献