希土脯氨酸配合物的合成和性质研究

通过希土氯化物与L-脯氨酸反应,制得了四种新的希土脯氨酸固体配合物。其通式为:Ln(prol)Cl_3·nH_2O(Ln=Y、La、Sm和Er).用化学分析、电导测定、热重分析、差热分析、红外光谱和核磁共振氢谱,确定了产物的组成,讨论了金属-配体的化学键性质。     

Effect of oxygen on regulation of properties of moderately boron-doped diamond films

Regulation of oxygen on properties of moderately boron-doped diamond films is fully investigated. Results show that, with adding a small amount of oxygen (oxygen-to-carbon ratio < 5.0%), the crystal quality of diamond is improved, and a suppression effect of residual nitrogen is observed. With increasing ratio of O/C from 2.5% to 20.0%, the hole concentration is firstly increased then reduced. This change of hole concentration is also explained. Moreover, the results of Hall effect measurement with temperatures from 300 K to 825 K show that, with adding a small amount of oxygen, boron and oxygen complex structures (especially B₃O and B₄O) are formed and exhibit as shallow donor in diamond, which results in increase of donor concentration. With further increase of ratio of O/C, the inhibitory behaviors of oxygen on boron leads to decrease of acceptor concentration (the optical emission spectroscopy has shown that it is decreased with ratio of O/C more than 10.0%). This work demonstrates that oxygen-doping induced increasement of the crystalline and surface quality could be restored by the co-doping with oxygen. The technique could achieve boron-doped diamond films with both high quality and acceptable hole concentration, which is applicable to electronic level of usage.     

Quantum circuits for realizing deterministic and exact teleportation via two partially entangled pairs of particles

Deterministic and exact teleportation can be achieved via two partially entangled pairs of particles [Gu Y J 2006 {\em Opt. Comm.} {\bf 259} 385]. The key point of the protocol is a generalized measurement described by a positive operator-valued measure, which can be realized by performing a unitary operation in the extended space and a conventional Von Neumann orthogonal measurement. By decomposing the evolution process from the initial state to the final state, we construct the quantum circuits for realizing the unitary operation with quantum Toffoli gates, and thus provide a physical means to realize the teleportation. Our method for constructing quantum circuits differs from the usual methods based on decomposition of unitary matrices, and is convenient for a large class of quantum processes involving generalized measurements.     

金属有机源化学气相沉积法生长氧化锌薄膜中氢气的作用及其机理

本文重点探讨了金属有机源化学气相沉积生长ZnO薄膜中氢气的作用与机理.研究表明氢气对ZnO薄膜的结构与性质具有重要的影响.当采用叔丁醇为氧源时,氢气对ZnO薄膜的晶体质量,表面结构和发光性质主要产生负面的影响,同时发现氢气的加入有助于抑制碳的沾污.而当采用笑气为氧源时,测量显示表面变光滑,晶体质量得到提高,发光强度也得到提升.氢气在笑气作为氧源生长ZnO的过程中基本起到了正面的作用.论文最后从氢气降低生长表面能量,提高表面原子迁移能力但存在表面腐蚀作用的方向以上结果给予了较好的解释.研究显示MOCVD生长高质量ZnO薄膜中氢气的优化具有特别重要的意义.     

基于低照度三基色图像去噪及融合彩色图像增强方法研究

现有的各类彩色图像增强方法,主要用于对光照不均匀或弱光条件下已获取的彩色图像进行直接增强,而低照度彩色成像系统获取的彩色图像是由单独采集的三基色图像融合而成。为此提出了基于低照度三基色图像去噪及融合彩色图像增强方法。利用小波变换对低照度条件下独立采集的三基色图像进行去噪;然后将去噪后图像融合成彩色图像,将彩色图像由RGB颜色空间转换为HSV颜色空间;在HSV空间对V进行MSR增强,再对增强后的图像进行S调整;最后再将其转换回RGB颜色空间。采用客观评价方法对选取的去噪增强后图像进行了评价。结果表明:经过去噪和增强后的彩色图像在均值、方差和熵3项指标上均优于三基色直接融合的彩色图像,平均提高幅度为均值11.37%、方差8.46%、信息熵0.44%。该方法可移植到低照度彩色成像系统中,对成像质量的提升具有指导意义。     

海底边坡稳定分析方法综述

本文指出海底边坡与陆上边坡的不同点,对一个完整的海底边坡稳定问题从几何形状和载荷情况两个方面进行了描述。由于波浪影响是海底边坡问题的最大特点,因此回顾了计算海底压力的各种方法以及在海底压力作用下海底土层产生的瞬态和残余孔隙压力。然后对极限平衡、静态变形分析和动力分析三大类边坡稳定分析方法进行了评述,并指出各自的适用范围。海底边坡破坏后的行为尤其复杂,指出用流变模型预测泥流性质的可能性。最后提出了海底边坡稳定性课题的当前致力方向。      

关于有源RLC电路的量子化

提出一种将有源ＲＬＣ电路量子化的方法,修正了有关文献中的错误。     

微波频率下Ba0.5Sr0.5TiO3薄膜的介电特性随温度及外加偏压变化的检测

提出了一种新的结构来表征钛酸锶钡薄膜在微波频率下的介电特性,即在沉积有钛酸锶钡薄膜的氧化镁基片上制作了共面带阻滤波器.借助于共面带阻滤波器的谐振频率和Q值,通过比较其测量值与仿真值,可以得出钛酸锶钡薄膜的介电常数和介电损耗.在变温测试过程中,注意到金导电层的电导率对带阻滤波器的谐振频率和Q值有较大的影响.为了准确地得到钛酸锶钡薄膜的介电特性,仔细分析了金导电层对带阻滤波器频率响应曲线的影响,并在比较求值过程中消除了这一影响.     

Implementation of nonlocal quantum swap operation on two entangled pairs

We propose a scheme for the implementation of nonlocal quantum swap operation on two spatially separated entangled pairs and we show that the operation can swap two qubits of these entangled pairs.We discuss the resources of the entangled qubits and classical communication bits required for the optimal implementation of the nonlocal quantum swap operation.We also put forward a scheme for probabilistic implementation of nonlocal swap operation via a nonmaximally entangled quantum channel.The probability of a successful nonlocal swap operation is obtained by introducing a collective unitary transformation.     

碳纳米管表面金纳米线的结构与热稳定性分析

用分子动力学方法研究了覆盖在碳纳米管表面的金原子所形成的结构及其热稳定性. 研究结果表明,金原子在碳纳米管表面能形成多样而稳定的结构：当金原子覆盖率低于15.91% 时,形成金纳米颗粒; 当原子覆盖率为15.91%~104.98% 时,形成一系列的壳层结构; 而当原子覆盖率大于104.98% 时,则呈现晶体金的面心立方结构. 在对有碳纳米管支撑的金纳米壳层结构的热稳定性进行研究后, 发现其熔点高于金纳米颗粒的熔点而且低于金纳米线的熔点.