排序方式: 共有42条查询结果,搜索用时 15 毫秒
31.
近十几年来 ,结晶性间同立构 1 ,2 -聚丁二烯引起人们的广泛关注 ,但绝大多数研究工作集中在聚合物的制备、物理性质和应用方面[1~ 3] ,对于其结晶行为和晶体结构则未见报道 .原因是间同立构 1 ,2 -聚丁二烯分子侧链含有大量的双键 ,在较高温度下很容易交联 ,特别是高间规度的聚合物 ,由于其熔融温度高 (>2 0 0℃ )则更易产生交联 ,这给结晶行为和结构研究带来很大困难 .结晶性间同立构 1 ,2 -聚丁二烯的晶体结构为平面锯齿链正交堆砌 ,Pacm空间群[4 ] .我们曾报道了结晶性间同立构 1 ,2 -聚丁二烯的合成和溶液浇铸膜的板条状结构[5] ,本… 相似文献
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作为一种半结品性的聚烯烃材料.全同立构聚丁烯-1(iPB-1)的结晶存在Ⅰ,Ⅱ.Ⅲ和Ⅰ’4种品型,其中,晶型Ⅰ和Ⅰ’是由3/1螺旋链堆砌的六方晶胞结构,晶型Ⅱ是由11/3螺旋构象链堆砌的四方晶胞结构,晶型Ⅱ则是由4/1螺旋链堆砌而成的正交品胞结构.通常溶液结晶得到品型Ⅲ和晶型Ⅰ’,在高压条件下从本体结品也可得到晶型. 相似文献
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Analysis and design of the taper in metal-grating periodic slow-wave structures for rectangular Cerenkov masers 下载免费PDF全文
The hybrid-mode dispersion equation of the metal-grating periodic slow-wave structure for a rectangular Cerenkov maser is derived by using the Borgnis function and field-matching methods.An equivalent-circuit model for the taper of the groove depth that matches the smooth waveguide to the metal-grating structure is proposed.By using the equivalentcircuit method,as well as the Ansoft high frequency structure simulator(HFSS) code,an appropriate electromagnetic mode for beam-wave interaction is selected and the equivalent-circuit analysis on the taper is given.The calculated results show that a cumulative reflection coefficient of 0.025 for the beam-wave interaction structure at a working frequency of 78.1 GHz can be reached by designing the exponential taper with a TE z10 rectangular waveguide mode as the input and the desired TE x10 mode as the output.It is worth pointing out that by using the equivalent-circuit method,the complex field-matching problems from the traditional field-theory method for taper design can be avoided,so the taper analysis process is markedly simplified. 相似文献
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Linear theory of a dielectric-loaded rectangular Cerenkov maser with a sheet electron beam 下载免费PDF全文
A three-dimensional model of a dielectric-loaded rectangular Cerenkov maser with a sheet electron beam for the beam-wave interaction is proposed.Based on this model,the hybrid-mode dispersion equation is derived with the Borgnis potential function by using the field-matching method.Its approximate solution is obtained under the assumption of a dilute electron beam.By using the Ansoft high frequency structural simulator(HFSS) code,the electromagnetic field distribution in the interaction structure is given.Through numerical calculations,the effects of beam thickness,beam and dielectric-layer gap distance,beam voltage,and current density on the resonant growth rate are analysed in detail. 相似文献
35.
In this review article, we give a brief overview of heavy fermions, which are prototype examples of strongly correlated electron systems. We introduce the application of physical pressure in heavy fermion systems to construct their pressure phase diagrams and to study the close relationship between superconductivity(SC) and other electronic instabilities, such as antiferromagnetism(AFM), ferromagnetism(FM), and valence transitions. Field-angle dependent heat capacity and point-contact spectroscopic measurements under pressure are taken as examples to illustrate their ability to investigate novel physical properties of the emergent electronic states. 相似文献
36.
利用透射电子显微学(TEM)和示差扫描量热学(DSC)等方法研究了含少量丁烯-1组分(摩尔分数为0.64%)的聚乙烯共聚物(PE100)熔体拉伸高取向薄膜的形态结构. 结果表明, 在PE100熔体拉伸薄膜中, 除存在高取向片晶结构外, 还含有大量的纤维晶, 纤维晶平行于拉伸方向, 穿过几个片晶区, 平均直径约为12 nm. 模拟实验结果表明, 纤维晶的生成源于聚乙烯共聚物中的超高分子量组分, 但不同于传统意义上的伸直链纤维晶, 其形态特征应为晶桥结构. 由此提出了晶桥结构纤维晶模型, 该模型不但有助于深入理解和认识聚合物取向结晶机理, 同时也为该材料的高性能化提供了理论依据. 相似文献
37.
空位缺陷黄铁矿的电子结构及其浮选行为 总被引:7,自引:0,他引:7
采用第一性原理平面波赝势计算了含有空位缺陷的黄铁矿的电子结构,同时讨论了空位缺陷对黄铁矿浮选行为的影响.研究结果表明:硫空位对晶胞体积影响不大,铁空位使黄铁矿晶胞膨胀了1.29%;空位缺陷主要影响黄铁矿费米能级附近的电子能带结构,并在禁带中出现了新能级;空位的存在使黄铁矿的费米能级升高,不利于黄铁矿的浮选.另外,有效质量计算表明,空位的存在增强了黄铁矿导带底电子的定域性.Mulliken键布居分析表明,理想黄铁矿的S—Fe键的共价性大于S—S键的,空位导致周围原子的键之间的共价性增强,有利于黄铁矿浮选.综合考虑空位的存在对矿物费米能级及原子间共价性的影响,我们认为空位的存在不利于黄铁矿的浮选. 相似文献
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我们曾研究超速淬火温度对聚偏氟乙烯(PVF_2)薄膜结晶结构的影响,在不同温度下淬火可分别得到α、β和γ三种晶型结构。本工作从非晶的玻璃态PVF_2出发,通过超速升温的方法,进一步研究结晶温度对PVF_2晶型结构的影响。 相似文献