双层套箍式高压容器的三维弹性应力分析

本文对双层套箍式高压容器的弹性应力问题作了分析研究.文中将内、外筒的应力和位移解看作一组“初等解”和一组“修正解”的叠加;“初等解”即为一般二维理论所得的解答,而“修正解”应用拉甫(Love)位移函数法求得.通过计算实例表明,解的收敛性良好,将三维理论精确解与“初等解”比较后,可见两种解答存在较明显的差别.     

THEORY AND REFINED THEORY OF ELASTICITY FOR TRANSVERSELY ISOTROPIC PLATES AND A NEW THEORY FOR TNICK PLATES

A theory of elasticity for the bending of transversely isotropic plates has been developed from the basic equations of elasticity in terms of displacements for transversely isotropic bodies, which takes into account the loads distributed over the surfaces of the plates. Based on this theory, a refined theory of plates which can satisfy three boundary conditions along each edge of the plates and a new theory of thick plates are established. The solution of the refined theory for simply supported polygonal plates has been obtained; and its numerical result is very close to the exact solution of the three-dimensional theory of elasticity. A systematic comparison with the former theories of thick plates shows that the present theory of thick plates is closest to the result of the theory of elasticity.     

2-[3-氰基呋喃-2(5H)-亚基]丙二腈衍生物的合成及其对Pd2+的识别

通过两步反应合成了一种2-(3-氰基呋喃-2(5H)-亚甲基)丙二腈衍生物TCF-Pyn,该化合物在MeCN/磷酸缓冲容溶液(PBS)(V∶V=2∶8,PBS 2×10^-2 mol/L,pH=7.4)混合溶液中能高选择性荧光"OFF-ON"识别Pd²⁺,发射波长达到近红外区(653 nm).该探针具有较好的抗干扰能力、较宽的pH适用范围(3~8)和较低的检测限(6.92μmol/L).应用研究表明,TCF-Pyn能检测真实水样中的Pd²⁺,并可对活细胞中的Pd²⁺进行荧光成像.     

一种苯并咪唑衍生物的合成及对Mg2+的识别研究

本文利用2-氨基苯并咪唑和5-溴水杨醛反应制得一种具有聚集荧光增强性质的探针L。探针L可以在DMSO体系下对镁离子具有很好的识别效果,并且探针L随着水含量的升高荧光强度在逐渐增强,在水含量达到90%表现出明显的荧光增强现象且发射波长发生明显的红移,在495nm处出现最强发射峰,检测限达到3.49×10^-5 M,能够有效地检测Mg²⁺,同时探针L的AIE性质具有了成为发光材料的潜能。     

X射线增感屏点扩散函数的Monte Carlo模拟

研制了一通用的Monte Carlo程序来研究X射线增感屏以及成象系统的性能,该程序主要包括三部分,分别描述了所发生的相应的物理过程：X射线的散射和吸收,次级电子的作用及可见光子的扩散,对程序进行了验证,对于一种Gd2O2S:Tb增感屏,计算了其在不同入射X射线能量下的点扩散函数。     

THE GEOMETRY OF HYPERSURFACES IN A KAEHLER MANIFOLD

Let M be a complex analytic manifOld there is given a positive definite quadratic differentialform[1]dS2 = gjkdZJdZ* (1)where the Latin indices j, k take the values 1,2,' l n; 1, 2,' t n. Assume the Greek indices o, Ptake the value8 1,2,', n and.=. l cr if i= al = 1 cr if i= a, (2)t cr if i = cr.Assume now that the symmetric tensor gjk is selfadoint(see below Definitioll l), that is-- --gap = g95 = go0 = g9rr, (3)g.0 = gPcr = gap = g05. (4)and 8atisfiesgoP = gap = 0. (5)From the com…     

聚苯乙烯支载聚乙二醇二苯并-18-冠-6的合成及催化性能研究

叙述了几种聚苯乙烯支载聚乙二醇二苯并-18-冠-6高聚物冠醚的合成,并研究了它们对n-溴辛烷与碘化钾及苯酚钾盐取代反应时的相转移催化性能。     

杂多化合物膜的制备及催化作用

Heteropoly compounds (HPC), a kind of polyoxometallates, with their strong acidity and oxidative ability, are good homogeneous and heterogeneous catalysts in both acid-catalyzed and selective oxidation reactions, and have been widely used in petroleum and fine chemical industries. Owing to the diversity in their composition and structure, the catalytic properties of HPC can be altered in a wide range. Among them, the heteropolyanions with Keggin structure have been studied by far the most,especially on their applications in heterogeneous catalysis. However, since they are thermally unstable at high temperatures, their utilization in this field has been restricted. In the last ten years, inorganic membranes have been proved to be beneficial to heterogeneous catalytic processes for their high selectivity and good heat-conductivity. And the sol-gel method, one of the most common approaches to prepare inorganic membranes, is becoming mature. Here a sol-gel method to prepare a porous HPC membrane is reported. The catalytic performance of the membrane was tested through a model reaction, the selective oxidation of t-BuOH.     

混凝土剪切应力-应变曲线的研究

本文利用自行设计的混凝土剪切试件对混凝土剪切强度、剪切应力一应变曲线进行了研究,为混凝土结构的分析提供了必要的力学模型．     

加权残值法在钢筋混凝土拱桥非线性有限元分析中的应用

本文用圆弧梁离散拱肋;用圆柱拖带坐标、三次位移插值函数及平截面假定来描述单元位形;用加权残值配点法来消除曲梁单元的剪力与膜力闭锁。按基于连续介质力学的Ｕ．Ｌ．列式建立单元增量平衡方程,以考虑几何非线性。假定钢筋为理想弹塑性材料。按三参数各向同性强化塑性模型,建立混凝土的弹塑性本构矩阵。将拱单元分段分块,根据钢筋及砼的本构特性,建立拱单元及梁段单元的弹塑性刚度矩阵,以考虑材料非线性。用编制的程序对两座模型拱桥进行计算,计算结果与模型测试结果接近