二组元酞菁固相混合法裂解合成直立碳纳米管

通过向两种金属酞菁的混合物添加一定量的硫粉,在800～950 ℃裂解合成了大面积的直立碳纳米管。采用场发射扫描电镜(FE-SEM)、高分辨透射电镜(HRTEM)和拉曼光谱对产物进行了观察和表征,结果显示：所合成的碳纳米管(直径为15～35 nm,长度为200～800 nm)管身平直,具有很好的石墨化程度,且杂质很少。采用两种金属酞菁((M(Ⅱ)Pc, M=Fe, Co))进行混合裂解时,既可以提供碳源,而且可以产生相当均匀的催化剂颗粒,有利直立碳纳米管的沉积。这种将两种酞菁进行固相混合裂解的方法,相当安全高效,有利于大规模生产直立碳纳米管。     

对"联邦滤波器信息分配系数的优选算法"一文的商榷

介绍了联邦滤波算法和信息分配原理，指出《中国惯性技术学报》第11卷第6期“联邦滤波器信息分配系数的优选算法”一中存在一些问题，说明使用该优选算法进行信息分配，可能使主滤波器方差阵失去正定性；将联邦滤波用于GPS姿态测量，实验表明动态选择信息分配因子，相对于固定信息分配因子的算法并没有明显优势。     

ROBUST WEAK ERGODICITY AND STABLE ERGODICITY

In this paper, we define robust weak ergodicity and study the relation between robust weak ergodicity and stable ergodicity for conservative partially hyperbolic systems. We prove that a Cr(r > 1) cons...     

Effect of strain on charge density wave order in α-U

The effect of strain on charge density wave (CDW) order in $\alpha$-U is investigated within the framework of relativistic density-functional theory. The energetical stability of $\alpha$-U with CDW distortion is enhanced by the tensile strain along $a$ and $b$ axes, which is similar to the case of negative pressure and normal. However, the tensile strain along $c$ axis suppresses the energetical stability of CDW phase. This abnormal effect could be understood from the emergence of a new one-dimensional atomic chain along $c$ axis in $\alpha$-U. Furthermore, this effect is supported by the calculations of Fermi surface and phonon mode, in which the topological objects and the dynamical instability show opposite behaviors between strains along $a$/$b$ and $c$ axes.     

新型抗肿瘤卡铂类衍生物的氢谱特征

卡铂是第二代铂类金属抗癌药物最重要的药物之一,广泛应用于临床. 为发现抗肿瘤活性更强的卡铂类药物,我们合成了6个新的卡铂类衍生物. 本文详细报道4个合成的新型卡铂衍生物的氢谱特征和归属.      

Nitrogen Dioxide Sensing Properties and Mechanism of Copper Phthalocyanine Film

Copper phthalocyanine film, a p-type organic semiconductor, is synthesized by vacuum sublimation and its surface morphology is characterized by SEM. A silicon-based copper phthalocyanine film gas sensor for NO2 detection is fabricated by MEMS technology. The results show that the resistance and sensitivity of copper phthalocyanine film decrease obviously as the NO2 concentration increases from Oppm to lOOppm. However, the sensitivity nearly keeps a constant of O. 158 between 30 ppm and 70 ppm. The best working temperature of the gas sensor is 90℃ for NO2 gas concentrations of lOppm, 20ppm and 30ppm, which is much lower than that of general metal oxide gas sensor.     

重复脉冲闪光灯抽运的染料激光器

调频激光器,特别是染料激光器,作为光谱光源,在激光光谱学中起十分重要的作用。染料激光器的抽运方式很多。其中闪光灯抽运的染料激光器,由于装置较简单和总效率较高而被广泛地应用。本文报道一台重复脉冲闪光灯抽运的染料激光器的初步实验结果。 一、激发机理 虽然染料分子是由许多原子组成的,但是它的能级以及吸收和发射过程可以模仿简单的双原子分子而画成如图1所示的能级图[1].染料激光器的吸收和发射过程与染料分子的四个能态有关:分子吸收抽运辐射后,从基态激发到第一(或第二)激发单态S1(或S2)的较高振动能级,并很快地通过非辐射跃迁…     

Explicit Determination of Torsion Subgroups of Elliptic Curves Over Multi-Quadratic Fields

LotKbeanalgebraicnUmberfield,EanellipticcurveoverK.Thewell-knownMordelLWeiltheOemassertsthattheK-rationalpointsE(K)ofEisafinitelygeneratedabeliangroup(MordelgrouP):E(K)2E(K)torsxZ,whereE(K)torsisthetorsionsubgroup,ristherank(anonnegativeinteger),Zistheadditivegroupofrationalintegers.TheaboveisomorphismsometimesisaIsowrittellasequality:E(K)=E(K)torsxZ".TherearemanyliteraturesstudyingthetorsionsubgrouPE(K)tors'EspeciallyL.Merelrecenilyprovedthe"uniformb0undednessconjecture":F0ranyp…