无机物离子对CuS微晶形态结构的有效调控

以CuCl2·3H2O,Cu（CH3COO）2·H2O和CuSO4·5H2O作为铜源,并向反应体系中引入少量NaCl或NaNO3,通过乙二醇溶剂中的溶剂热反应,合成了形貌各异的CuS微晶．结合XRD和SEM表征,初步探讨了阴离子Cl-、CH3COO-、SO4^2-和阳离子Na’对CuS微晶生长过程的影响．结果表明,Na＋对CuS微晶的生长过程没有显著影响,而Cl、CH3COO-、SO4^2-由于在{1012}晶面上选择性吸附能力的差异,显著影响CuS微晶的形貌．本研究为进一步有效调控CuS微晶的形貌及性能奠定了基础．     

Constructing a Maximally Entangled Seven-Qubit State via Orthogonal Arrays

Huber et al.[Phys.Rev.Lett.118(2017) 200502] have proved that a seven-qubit state whose three-body marginal states are all maximally mixed does not exist.Here,we propose a method to build a maximally entangled state based on orthogonal arrays to construct maximally entangled seven-qubit states.Using this method,we not only determine that a seven-qubit state whose three-body marginals are all maximally mixed does not exist,but also find the condition for maximally entangled seven-qubit states.We ...     

硅纳米管负载的钌基催化剂费-托合成催化性能研究

以模板法合成的硅纳米管（SNT）为载体,用浆态浸渍法制备了钌基催化剂,采用氮气物理吸附、透射电子显微镜（TEM）、X射线粉末衍射（XRD）和氢气程序升温还原（H₂-TPR）等手段对其进行了表征。在固定床反应器上（503K,1.0MPa）考察了该催化剂的费-托合成反应活性及产物选择性,并与用商业二氧化硅为载体制备的催化剂上的反应结果进行了比较。结果表明,SNT和SiO₂负载的氧化钌在623K可被H₂完全还原;SNT负载的钌基催化剂上,钌氧化物颗粒较小、分散性好,还原后钌颗粒被较好地分散在硅纳米管上,且几乎所有的钌颗粒都分布在管内。与以SiO₂为载体的催化剂相比,以硅纳米管为载体的钌基催化剂具有较高的费-托合成活性。     

“新教材解读”之（6）——算法初步

为贯彻实施《普通高中数学课程标准（实验）》的基本精神,体现现代科学的发展,加强数学教学与现代信息技术的结合,新编高中数学教材增加了《算法初步》的内容．下以湖北教育出版社出版（简称鄂教版）的教材为主,对《算法初步》的编写理念、主要内容与呈现方式作简单介绍,也对教材作些必要的说明,并对教材教法提出一些建议以供参考．     

Efficient scheme for remote preparation of arbitrary n-qubit equatorial states

Recently,a scheme for deterministic remote preparation of arbitrary multi-qubit equatorial states was proposed by Wei et al.[Quantum Inf.Process.1770(2018)].It is worth mentioning that the construction of mutual orthogonal measurement basis plays a key role in quantum remote state preparation.In this paper,a simple and feasible remote preparation of arbitrary n-qubit equatorial states scheme is proposed.In our scheme,the success probability will reach unit.Moreover,there are no coefficient constraint and auxiliary qubits in this scheme.It means that the success probabilities are independent of the coefficients of the entangled channel.The advantage of our scheme is that the mutual orthogonal measurement basis is devised.To accomplish the quantum remote state preparation(RSP)schemes,some new sets of mutually orthogonal measurement basis are introduced.     

算法及其特征

1　算法的重要性数学本身包含两个方面,一是逻辑的推理、归纳,比如由某几个公理发展成的欧氏几何;另一方面则是算法.现代科学技术的飞速发展,尤其是计算机的应用的日益扩大化,使科学计算已成为科学研究和工程设计的重要因素,甚至已成为一种基本方式.选择恰当的数值求解方法和技巧去求解或模拟科学和工程,及其社会、经济的问题是现代科学的重要组成部分.在过去的几十年里,利用大型、巨型机进行科学计算已经为我国以技术为基础的国民经济部门创造了巨大的效益,对我国航天造船、石油、半导体和核工业等的发展作出了实质性的贡献.实际上,诸多应…     

同轴等大圆形载流线圈的磁场和磁感应线的分布

根据毕奥-萨伐尔定律求出了同轴等大圆形载流线圈的磁场分布，运用数学软件Maflab绘出了其磁感应线的分布图。     

A Polymeric Iodiplumbate（Ⅱ） Directed by Heterocyclic Monoprotonated Quaternary Ammonium

A new iodiplumbate polymer [（AOD）（Pb216）]n 1 （AOD = O-protonated 4-azonia-7- oxaspiro（4,5） decane quaternary ammonium） was synthesized by self-assembly reaction of AOD-I, Pb（NO3）2 and NaI, and structurally determined. Compound 1 crystallizes in the hexagonal system, space group P3, with a = 18.2704（8）, c = 8.1663（6） A, V= 2360.8（2） A3, Z = 3, De = 2.783 g/cm^3, F（000） = 1686, C8H17I6NOPb2, Mr = 1319.03, μ（MoKa） = 16.562 mm^-1, the final R = 0.0535 and wR = 0.1793 for 4943 observed reflections with I 〉 2σ（I）. In compound 1, three independent （PbEI6）^2-n infinite chains in each unit cell shape the sketch of compound 1 under the template of AOD-H^2＋ cation. Each （PbaI6）^2-n chain generates from the face-sharing of distorted PbI6 octahedra. （PbEI6）^2-n polyanions interact with AOD-H^2＋ cations by electrostatic interaction in the crystal to feature a so-called hybrid structure. Compound 1 was further characterized with IR, elemental analysis, fluorescence spectrum and thermal analysis. Based on the crystal structure data, DFT calculation was carried out to reveal the electronic structure of compound 1.     

微波场协同提取野菊花黄色素的研究

研究了微波提取野菊花 (Chrysanthemumindicum)黄色素的新工艺并确定了最佳工艺条件 :原料为 2 0 0 0 0g野菊干花 ,提取剂为无水乙醇 ,提取剂比例为 1 /70 ,微波功率为 80 0W ,提取时间为 45 0s,提取次数为 3次 ,最佳工艺条件下色素的提取率为 91 1 % ,产率为 1 4 6% ,色价E ( 1 % ,3 2 1nm)为 42 2 ,产品pH值为 6 5。与溶剂浸提法相比 ,微波提取野菊花黄色素的每次提取时间由 1 2h减小为 45 0s,提取率从 88 6%增加到 91 1 %。