基于羟基化酞菁锌-石墨烯纳米材料的和厚朴酚电化学传感器的构建及其应用

通过非共价作用制备了可溶性四羟基酞菁锌-石墨烯纳米复合材料,并将其应用于构建新型高灵敏度和厚朴酚电化学传感器.由于水溶性四羟基酞菁锌和石墨烯的协同作用,显著提高了纳米复合材料的比表面积和导电性,增强了和厚朴酚的电化学响应.在最优实验条件下测定,和厚朴酚在0.01～1.0μmol/L和1.0～100 μmol/L范围内呈...     

交流碳弧法合成碳包碳化铁纳米晶

采用交流碳弧法高效合成碳包碳化铁纳米晶磁性微粉,磁性微粉产率达90%以上.用热重分析法(TG)测得磁性微粉中Fe的质量分数为17.5%.X射线衍射(XRD)分析结果表明,在碳包碳化铁微粉中存在Fe₃C和Fe₅C₂两种结构形式,不含纯Fe晶粒,碳层结构与石墨相似.在透射电镜(TEM)下观察了纳米晶的形貌和粒径分布,碳化铁纳米晶尺寸分布在3～10nm,并呈颗粒状分散在碳层中,碳层为巴基管和巴基葱的堆积体,形状各异,尺寸分布在几十纳米到几微米之间.讨论了碳包碳化铁纳米晶的形成机理.测定了磁性微粉的磁滞回线,其饱和磁感应强度Bs,剩磁Br和矫顽力Hc分别为2.6×10^-2T,2.5×10^-3T和5.52kA/m.     

Fatigue life of metal treated by magnetic field

This paper investigates theoretically the influence of magnetization on fatigue life by using non-equilibrium statistical theory of fatigue fracture for metals. The fatigue microcrack growth rate is obtained from the dynamic equation of microcrack growth, where the influence of magnetization is described by an additional term in the potential energy of microcrack. The statistical value of fatigue life of metal under magnetic field is derived, which is expressed in terms of magnetic field and macrophysical as well as microphysical quantities. The fatigue life of AISI 4140 steel in static magnetic field from this theory is basically consistent with the experimental data.     

Generalized constrained multiobjective games in locally <Emphasis Type="Italic">FC</Emphasis>-uniform spaces

A new class of generalized constrained multiobjective games is introduced and studied in locally FC-uniform spaces without convexity structure where the number of players may be finite or infinite and all payoff functions get their values in an infinite-dimensional space. By using a Himmelberg type fixed point theorem in locally FC-uniform spaces due to author, some existence theorems of weak Paxeto equilibria for the generalized constrained multiobjective games are established in locally FC-uniform spaces. These theorems improve, unify and generalize the corresponding results in recent literatures.     

Adsorption isotherms for benzene on diatomites from China

In this paper, benzene adsorption isotherm and their hysteresis on two important local diatomites were determined at 25℃, and their silicon hydroxyl group (SiOH) number was determined, their properties were reported, and the relationship between surface structure, surface SiOH number per nm2 and adsorption isotherm with hysteresis was discussed. The specific surface was also calculated from the isotherms, and pore-size distribution was determined.     

Al2O3—40%TiO2和Cr2O3等离子喷涂层的摩擦磨损特性

研究了AC4C铸铝合金表面等离子喷涂Al2O3-40%TiO2和Cr2O3陶瓷粉末涂层的滑动摩擦磨损特性;采用划痕试验方法测定了涂层与基体之间的结合强度;用扫描电子显微镜观察分析了磨痕形貌和涂层显微组织特征.研究结果表明:Cr2O3涂层的摩擦学性能优于Al2O3-40%TiO2涂层;涂层的结合强度、硬度和表面空隙对磨损影响较大;Al2O3-40%TiO2涂层的磨损机理主要表现为塑性变形和层状剥离;而Cr2O3涂层则主要为磨粒磨损     

第四届全国周培源大学生力学竞赛理论力学试题

题一（１０分） 立方体的边长为ａ,作用有力系如图．其中三个力的大小均为Ｆ,两个为偶的力偶矩大小均为Ｍ＝Ｆａ,方向如图．若欲使该立方体平衡,只需在某处加一个力即可,则在坐标系中, （１）所加的力为 （２）在图中画出该力的示意图．题二（１０分） Ａ、Ｂ两物块质量均为,静止如图叠放,设各接触处的摩擦系数均为． （３）若用手慢慢地去拉Ｂ块,其运动现象为 （４）若用手突然快速拉Ｂ块,其运动现象为 （５）在上述两种情况下,Ａ所能获得的最大水平加速度为题三（１０分） 设均质圆盘齿轮Ａ与一大齿轮内接,齿轮Ａ的质量为ｍ,…     

微循环系统动力学综合数学模型研究(Ⅱ)———计算方法及结果

利用解析法与有限元法相结合的“影响线算法”,求解了第一部分中建立的数学模型,分析了微循环系统动力学的若干重要问题,表明在微动脉自律运动周期内,间质流体压力将两次改变符号,因而某些理论中十分强调的间质流体压力是略高于或略低于大气压力的问题显得并不重要;微动脉自律运动能导致周期性的淋巴形成,间质总应力在这一过程中起着重要作用;微循环局部调节可以以动态平衡的方式在一定范围内满足代谢的需要.计算还表明了微动脉“阻力血管”的性质和微血管网络在热量交换过程中的高效性.这些结果说明我们建立的综合模型符合生理实际.     

对于均匀双相流体冻结音速的分析

与通常的方法不同,本文从微元封闭体系的简单模型（而非微元控制体）出发,推导出微小扰动在流体介质中的相对传播速率—音速为ａ~２＝（■ｐ／■ρ）ｓ;并强调指明该式对于双相流体介质的适用条件。对于均匀双相流体的冻结音速,文中从理论上分析并导出了存在最小音速（气隙率０＜ａ＜１））的条件及此时的气隙率的计算公式,这些理论分析的结果是与已知的实验数据相符的。     

高能强流负离子束系统束光学特性的数值模拟

基于负离于-中性束注入器中强流负离子束引出与加速系统的特点所建立的数值模拟模型和计算程序,通过数值模拟研究了强流负离子束系统电磁场位形、几何参数、等离子体参数、束流密度和负离子剥离损失对负离子束光学特性的影响。对8电极800keV强流负离子束系统的初步优化结果表明对引出流密度为2lmA·cm-2的H-离子束,当负离子初始温度为0.2eV时,由系统出射的85％束散角可达到0.23°。