D371树脂—火焰原子吸收光谱测定湿法冶金工艺的金

离子交换富集分离金，具有较好的动力学性能和较高的吸附容量。使金的吸附与离子交换过程在金的湿法冶金中日趋重要？本文研究用新型D371树脂在静态动态条件下吸附和解吸金的性能，拟定了一个离子交换树指分离富集火焰原子吸收光谱测定湿法冶金工艺中微量金的方法。     

Helium-hydrogen synergistic effects on swelling in in-situ multiple-ion beams irradiated steels

The development of reliable fusion energy is one of the most important challenges in this century. The accelerated degradation of structural materials in fusion reactors caused by neutron irradiation would cause severe problems. Due to the lack of suitable fusion neutron testing facilities, we have to rely on ion irradiation experiments to test candidate materials in fusion reactors. Moreover, fusion neutron irradiation effects are accompanied by the simultaneous transmutation production of helium and hydrogen. One important method to study the He-H synergistic effects in materials is multiple simultaneous ion beams (MSIB) irradiation that has been studied for decades. To date, there is no convincing conclusion on these He-H synergistic effects among these experiments. Recently, a multiple ion beam in-situ transmission electron microscopy (TEM) analysis facility was developed in Xiamen University (XIAMEN facility), which is the first triple beam system and the only in-running in-situ irradiation facility with TEM in China. In this work, we conducted the first high-temperature triple simultaneous ion beams irradiation experiment with TEM observation using the XIAMEN facility. The responses to in-situ triple-ion beams irradiation in austenitic steel 304L SS and ferritic/martensitic steel CLF-1 were studied and compared with the results in dual- and single-ion beam(s) irradiated steels. Synergistic effects were observed in MSIB irradiated steels. Helium was found to be critical for cavity formation, while hydrogen has strong synergistic effect on increasing swelling.     

Bcklund变换及其在孤立子理论中的应用

大自然中存在孤立波(solitary wave)现象,早在1834年就被英国科学家约翰·司各特·罗素(John Scott Russell)所发现了.罗素这样报道过: "我观察过一次船的运动,这条船被两匹马拉着,沿着狭窄的河道迅速前进,被船体带动的水量不算太多。突然间,船停止了前进,此时在船头周围聚集的水流处于急剧运动状态,它们离开船 ...     

运动硬化材料本构关系的精确积分及其推广应用

考虑到弹塑性有限元分析中的每一增量步长或迭代之后,需要对材料本构关系进行积分,本文导出了运动硬化材料本构关系的精确积分。算法步骤简洁。将它推广应用于各向同性硬化材料和混合硬化材料时,对于径向加载情况,此积分仍是精确解;对于非径向加载情况,此积分是具有很高精度的近似解。计算结果表明本文提出的算法在精度和效率上改进了现行的子增量法的数值积分方案。     

各向同性硬化材料弹塑性本构关系的渐近积分及其计算精度

1.引言由于材料塑性性质依赖于变形的历史,弹塑性有限无分析一般都采用增量方法。其基本点是从已知的现时(时间t,对于静力分析、t可理解为加载水平)状态出发,利用虚功原理建立到达邻近(时间t+△t))状态的变形增量的运动方程。这样逐步求解,从而得到结构在整个时间历程的变形和应力状态。为得到足够精确的结果,一般情况下,在非线性分析的每个增量步中,还要进行平衡迭代。但是无论是采用哪种迭代(例如Newton-Raphson迭代,常刚度迭代等),每个增量步或每次迭代以后都要进行状态决定,即根据求得的位移增量决定新的变形状态的应力、应变等,作为下一增量步或下次迭代求解的出发点。因此状态决定在增量有限元分析中不仅在计算量上占很大比例,而且对解的精度有直接的影响。在状态决定的计算中,从位移增量计算应变增量仅涉及几何关系,而由应变增量计算应力增量则涉及材料的本构关系。关于后者,弹塑性增量理论中建立的是应力和应变的微分关系:     

弹塑性有限元增量分析的自动选择步长和用予测本步刚度阵求解

本文利用本步刚度参数(current stiffness parameter)概念,对改进弹塑性有限元增量分析的效率和精度提出了两个具体措施。 1.自动选择每个增量步的步长,可在保证精度的前提下大量缩减总的增量步数,并有效地解决了计算结构极限载荷的问题。 2.用予测获得的本步刚度阵代替现行的起点切线刚度阵求解本步载荷增量,可大量缩减每个步长的迭代次数,提高收敛速度。     

基于重叠划分的自由网格四边形单元计算方法

提出了一种基于重叠划分的自由网格四边形单元计算方法。这一方法将四边形单元引入到自由网格计算方法中，不仅提高了计算的精度，同时还保留了自由网格计算方法的特点。方法首先对分析域内自动生成的每一个节点建立一套临时三角形单元，利用这些临时三角形单元组合生成四边形单元，以节点为单位进行计算。由于各矩阵的计算与组集均以节点为中心进行处理，因而特别适合于并行计算环境。在详细介绍自由网格四边形单元计算方法的基础上，利用数值算例证实了这一方法改善计算精度方面的有效性。     

应用单摆划痕法研究SiCp/Al合金的冲击磨损行为

本文介绍了用单摆划痕法研究材料冲击磨损性能的实验原理、装置和冲击磨损性能参量。对１５％ＳｉＣｐ／Ａｌ－９Ｓｉ复合材料及基体材料Ａｌ－９Ｓｉ的冲击磨损行为进行了研究。结果表明，１５％ＳｉＣｐ／Ａｌ－９Ｓｉ的抗冲击磨损性能优于基体Ａｌ－９Ｓｉ。冲击磨损过程中，大部分ＳｉＣｐ颗粒被压入基体并协同基体一起变形，从而提高复合材料的抗冲击磨损性能。     

表面形貌对螺旋线形跨尺度电化学葡萄糖传感器性能的影响

将键合金丝以螺旋方式紧密绕制在光纤纤芯上,用水浴法在其表面合成氧化锌纳米线,再将葡萄糖氧化酶物理吸附在纳米线上,得到了螺旋线形跨尺度葡萄糖酶电极。提取了该跨尺度结构及相应酶电极的表面形貌,表征了该批酶电极的电化学性能。结果表明,氧化锌纳米线的合成参数对跨尺度结构的表面形貌、葡萄糖氧化酶的固定效果、跨尺度电化学葡萄糖传感器的性能有显著影响;当生长液Zn2+浓度为25 mmol/L时,跨尺度结构表面形貌的粗糙度为0.10μm、相关长度0.29μm,此时葡萄糖氧化酶的固定效果最好,对应的葡萄糖传感器灵敏度为2.15μA/(mmol/L·cm2)、线性范围0~4.5 mmol/L、检出限9.2μmol/L、Michaelis-Menten常数3.68 mmol/L。研究结果不但有助于螺旋线形跨尺度酶电极的批量制备,还可显著提高其测量精度。     

NiSi Film Synthesized by Isochronal Annealing in a Magnetron Sputtering System

By repeatedly pre-cleaning the sputtering chamber with Ar gas and in-situ isochronal annealing samples, NiSi films are successfully prepared on Si （100） substrates in a radio-frequency magnetron sputtering system. A comparison between the obtained NiSi and excess oxygen-contaminated Ni/Si films has been performed by EDX analysis of oxygen atomic content in both the films. Focused ion beam milling technology is employed to make the cross-sections of the samples for characterizing the NiSi film thickness and NiSi/Si interface roughness. The influences of nickel film thickness on the NiSi-film morphology and on the NiSi/Si interface roughness are studied.