磁性固相萃取结合GC－MS检测烟叶中拟除虫菊酯类农药残留

该文基于β-环糊精(β-CD)的磁性复合材料(Fe3O4@SiO2@β-CD)建立了磁固相萃取结合气相色谱－质谱法同时检测烟草中联苯菊酯、甲氰菊酯、氟氯氰菊酯和溴氰菊酯4种拟除虫菊酯类农药残留的分析方法,对比了键合不同环糊精衍生物的复合材料(Fe3O4@SiO2@α-CD、Fe3O4@SiO2@β-CD和Fe3O4@S...     

SLANT IMMERSIONS OF COMPLEX SPACE FORMS AND CHEN＇S INEQUALITY

A submanifold in a complex space form is called slant it it has constant Wirtinger angles. B, Y, Chen and Y. Tazawa proved that there do not exist minimal proper slant surfaces in CP^2 and CH^2. So it seems that the slant immersion has some interesting properties. The authors have great interest to consider slant immersions satisfying some additional conditions, such as unfull first normal bundles or Chen‘s equality holding. They prove that there do not exist n-dimensional Kaehlerian slant immersion sin CP^n and CH^n with unfull first normal bundles. Next, it is seen that every Kaehlerian slant submanifold satisfying an equality of Chen is minimal which is similar to that of Lagrangian immersions. But in contrast, it is shown that a large class of slant immersions do not exist thoroughly. Finally, they give an application of Chen‘s inequality to general slant immersions in a complex projective space, which generalizes a result of Chen.     

苦参生物成碱的二维核磁共振谱(2D-NMR)研究Ⅰ.中国东北产苦参中的N-甲基金雀儿碱与氧化槐根碱的2D-NMR研究

由我国东北产的苦参中分离出七种生物碱。由MS、IR及2D-NMR鉴定为:(+)-苦参碱、(+)-氧化苦参碱、5α-羟基苦参碱、N-甲基金雀儿碱、9α-羟基苦参碱及氧化槐根碱。另一个生物碱(6)的化学结构尚在鉴定之中。本课题采用了二种2D-NMR技术,H-H相关谱(300、400及500MHz)及C-H相关谱(H:300MHz;C:75MHz)。先发表其中两个生物碱的2D-NMR,其它将陆续发表。     

均相稀土催化配位聚合反应的特征与催化剂的结构及其生成机理

本文着重介绍了均相稀土配位催化剂的结构与能够产生顺式-1,4和反式-1,4双烯烃聚合物的催化剂活性中心的生成机理。     

Energy levels and transition data of 3p63d8 and 3p53d9 configurations in Fe-like ions (Z = 57, 60, 62, 64, 65)

Atomic data of highly charged ions (HCIs) offer an attractive means for plasma diagnostic and stars identification, and the investigations on atomic data are highly desirable. Herein, based on the fully relativistic multi-configuration Dirac-Hartree-Fock (MCDHF) method, we have performed calculations of the fine-structure energy levels, wavelengths, transition rates, oscillator strengths, and line strengths for the lowest 21 states of 3p⁶3d⁸-3p⁵3d⁹ electric dipole (E1) transitions configurations in Fe-like ions (Z = 57, 60, 62, 64, 65). The correlation effects of valence-valence (VV) and core-valence (CV) electrons were systematically considered. In addition, we have taken into account transverse-photon (Breit) interaction and quantum electrodynamics (QED) corrections to treat accurately the atomic state wave functions in the final relativistic configuration interaction (RCI) calculations. Our calculated energy levels and transition wavelengths are in excellent agreement with the available experimental and theoretical results. Most importantly, we predicted some new transition parameters that have not yet been reported. These data would further provide critical insights into better analyzing the physical processes of various astrophysical plasmas.     

几种杀螨剂对三种叶螨的毒力测定

本文测定了３种杀螨剂对３种叶螨成螨的毒力。ＩＣ５０显示：３种杀螨剂毒力强弱为螨克＞三氯杀螨醇＞蚧螨灵：３种成螨的敏感性高低为柏小爪螨＞石榴小爪螨＞柑桔全爪螨。     

利用ＳＢＡ-１５介孔内纳米碳合成含介孔的ＺＳＭ-５分子筛

SBA-15介孔分子筛内填充蔗糖并炭化后, 分别在碱性和弱酸性条件下, 用含铝源及TPABr的溶液浸渍,将SBA-15分子筛孔壁的无定形结构转化成ZSM-5分子筛的晶体结构, 除碳后得到含介孔的ZSM-5分子筛. 用X射线衍射、 N_2吸附-脱附、 ~(27)Al MAS NMR、 NH_3-TPD、 TEM、 SEM等对样品进行了表征, 考察了晶化时间等参数对样品的影响. 结果表明, 碱性条件下合成的ZSM-5分子筛晶体中含有少量孔径约3.2～4.2 nm的介孔孔道, 其酸强度接近与常规ZSM-5分子筛的酸强度;弱酸性条件下合成的ZSM-5分子筛晶体中含有大量孔径约1.4～1.6 nm的孔道, 其酸强度明显低于常规ZSM-5分子筛的酸强度.     

气相色谱-负化学电离源-飞行时间质谱测定烟草中有机氯农药残留

采用QuEChERS前处理方法,建立了气相色谱-负化学电离源-飞行时间质谱(GC-NCI-TOF-MS)检测烟草中10种有机氯农药残留的分析方法。样品采用乙酸乙酯-正己烷(1 : 1, v/v)溶液提取,提取液经N-丙基乙二胺(PSA)、无水硫酸镁分散固相萃取净化,用GC-NCI-TOF-MS检测分析。根据有机氯化合物特征离子的精确质量数、同位素离子峰簇、碎片离子丰度比和保留时间对目标物定性鉴定,外标法定量。10种有机氯农药的线性关系良好,相关系数 (r²)均大于0.997;相对标准偏差小于6.5%;检出限为0.04~0.80 μ g/kg;加标回收率为77.2%~93.0%。该方法简单快速、灵敏度高、准确性好,适用于烟草中有机氯农药残留的定性分析和定量检测。     

Volterra积分方程和离散方程的三解存在性定理

建立了 Volterra 积分方程和离散方程存在三个非负解的一些标准.问题的证明中运用了Leggett Williams不定点理论.     

遗传递增演化算法配筋优化设计

递增演化结构算法(AESO)是在初始结构上,逐步增加有效材料,进而得到优化拓扑形状,其运算速度快,但容易陷入局部最优解。为提高寻找全局最优解的能力,把递增演化结构算法(AESO)和遗传算法(GA)相结合,提出遗传递增演化算法(GAESO),在增加有效材料的选择性上引入生物进化遗传理论,并以ANSYS有限元分析软件的非线性分析为平台,采用钢筋混凝土分离式模型,探讨遗传递增演化算法(GAESO)在钢筋混凝土复杂应力构件配筋优化设计上的应用,直观地完成在荷载作用和应力约束条件下简支深梁、简支开洞深梁和开洞剪力墙等钢筋混凝土复杂应力构件的配筋优化设计,所得结果符合受力机理,演化方向正确,钢筋布置明确,与遗传演化优化算法(GESO)所得结果进行比较验证,证实了算法的可行性、速敛性和稳定性,能为钢筋混凝土配筋优化设计提供参考。