基于线性抛物化稳定性方程的后掠翼边界层内横流稳定性研究

采用有限差分法求解考虑模型曲率的线性抛物化稳定性方程(LPSE),分析无限展长后掠翼边界层内的横流驻波不稳定,并与实验结果进行对比,研究LPSE方法的模拟效果及其适用范围.研究表明,在横流驻波扰动增长的初期,LPSE能够准确的预测扰动的e^N曲线,较好地描述边界层内的流动结构和扰动形态;当扰动增长到足够大时,扰动的高阶项不能再被忽略,LPSE的线性假设不再成立,需要采用非线性的方法(NPSE)来分析该状态.计算分析发现,模型曲率和边界层非平行性对后掠翼边界层内横流驻波的稳定性分析影响很大,影响程度与雷诺数无关.对于本文研究的模型,曲率对边界层内的横流扰动起着稳定的作用,而非平行性对扰动起不稳定的影响.     

爆炸应力波作用下动、静裂纹相互作用的实验研究

采用数字激光动态焦散线测试系统,研究爆炸应力波作用下动裂纹与预制静裂纹(水平夹角为90°、150°)相互作用机理,以及裂纹扩展的动态行为。结果表明:(1)在动、静裂纹贯通之前,静裂纹两端便出现焦散斑,动、静裂纹贯通以后,静裂纹沿爆炸应力波传播方向扩展,并且扩展速度小于动裂纹扩展速度,也小于无静裂纹时动裂纹扩展速度; (2)静裂纹存在时,动裂纹扩展的总体长度减小。动裂纹起裂时间缩短,扩展速度基本不受静裂纹的影响,裂纹应力强度因子值大于静裂纹两端值; (3)随着静裂纹水平夹角的增大,动、静裂纹贯通时动裂纹沿水平方向偏转距离增大,静裂纹B端反向扩展与动裂纹相互“咬合”,C端裂纹扩展位移和速度增大。     

1.3～5μm宽波段红外成像光学系统设计

宽波段红外成像技术可以获取丰富的波段信息,在目标识别和频谱分析中具有独特的优势。设计了一种1.3~5μm宽波段短中波红外光学系统,该光学系统采用二次成像设计,包括7块透镜和2片反射镜,其中使用了2片硅非球面和1片硒化锌基底衍射面用以校正像差和色差。利用光学设计软件给出了系统的光学参数和二维外形结构图,并且对其像质和冷反射进行了系统分析。该系统可以实现在工作波段1.3~5μm宽波段中成像,其F数为2,满足100%冷光阑效率。该系统结构紧凑,像质较好,能够实现宽波段成像要求。     

Influence of misch metal content on microstructure and magnetic properties of R–Fe–B magnets sintered by dual alloy method

MM_(14)Fe_(79.9)B_(6.1)/Nd_(13.5)Fe_(80.5)B_6 magnets were fabricated by dual alloy method(MM, misch metal). Some magnets have two Curie temperatures. Curie temperatures T_(c1)corresponds to the main phase which contains more La Ce, and T_(c1) decreases from 276.5?C to 256.6?C with the content of MM increasing from 30.3 at.% to 50.6 at.%. The variation of Br with the increase of MM indicates the existence of inter-grain exchange coupling in the magnets. When MM/R ≤ 30.3 at.%,the magnetic properties can reach the level of the intrinsic coercivity Hcj≥ 7.11 kOe and the maximum energy product(BH)max≥ 41 MGOe. Compared with Nd, La and Ce are easier to diffuse to the grain boundaries in the sintering process,and this will cause the decrease of H_(cj) Due to the diffusion between the grains, the atomic ratio of La, Ce, Pr, and Nd in each grain is different and the percentage of Nd in all grains is higher than that in misch metal.     

反常蓝移单电子锂键Y…Li-CH_3[Y=CH_3,CH_2CH_3,CH(CH_3)_2,C(CH_3)_3]体系的结构与性质

在密度泛函理论B3LYP/6-311++G(d,p)及MP2/6-311++G(d,p)水平上研究了单电子锂键复合物Y…Li-CH_3[Y=CH_3,CH_2CH_3,CH(CH_3)_2,C(CH_3)_3]的结构与性质.结果表明,三种单电子锂键复合物H_3CH_2C…Li-CH_3(Ⅱ),(H_3C)_2HC…Li-CH_3(Ⅲ)和(H_3C_3)_3C…Li-CH_3(Ⅳ)单电子锂键强度依Ⅱ(-26.7 kJ·mol~(-1))<Ⅲ(-30.2 kJ·mol~(-1))<Ⅳ(-32.8 kJ·mol~(-1))的顺序递增,相对于单体Li-CH_3,复合物Ⅱ,Ⅲ及Ⅳ中Li-CH_3键虽然拉长,但其伸缩振动频率出现了反常的蓝移,且蓝移程度依次增大,分别为15.1,18.9和20.5cm~(-1).供电子体中甲基数目的递增加强了这种单电子弱键作用,而若电子受体LiH中H被CH_3取代,则减弱了弱键相互作用.利用自然键轨道(NBO)及分子中原子(AIM)分析进一步对体系的弱键相互作用进行了探讨.     

反常蓝移单电子锂键Y…Li-CH3[Y=CH3, CH2CH3, CH(CH3)2, C(CH3)3]体系的结构与性质

在密度泛函理论B3LYP/6-311++G(d,p)及MP2/6-311++G(d,p)水平上研究了单电子锂键复合物Y…Li—CH3[Y=CH3, CH2CH3, CH(CH3)2, C(CH3)3]的结构与性质. 结果表明, 三种单电子锂键复合物H3CH2C…Li—CH3(II), (H3C)2HC…Li—CH3(III)和(H3C)3C…Li—CH3(IV)单电子锂键强度依II(-26.7 kJ·mol-1)相似文献   

向量参变量的集族最大元的稳定性

在通有稳定性的方法体系下(Usco方法),本文引入向量参变量并利用集值映射方法定义广义最大元,刻画了集族最大元特有属性,讨论了最大元映射和向量参数扰动时,向量参变量的集族最大元的通有稳定性。发现了集合族公共元具有良好的性质,其交运算具有通有稳定性,并发现了向量参变量的集族最大元的稳定性。     

Water and Ion Permeation through Electrically Charged Nanopore

The behaviour of water and small solutes in confined geometries is important to a variety of chemical and nanofluidic applications. Here we investigate the permeation and distribution of water and ions in electrically charged carbon cylindrical nanopore during the osmotic process using molecular dynamics simulations. In the simulations, charges are distributed uniformly on the pores with diameter of 0.9 nm. For nanopores with no charge or a low charge, ions are difficult to enter. With the increasing of charge densities on the pores, ions will appear inside the nanopores because of the large electronic forces between the ions and the charged pores. Different ion entries induce varying effects on osmotic water flow. Our simulations reveal that the osmotic water can flow through the negatively charged pore occupied by K^＋ ions, while water flux through the positively charged pores will be disrupted by Cl^- ions inside the pores. This may be explained by the different radial distributions of K^＋ ions and Cl^- ions inside the charged nanopores.     

质谱法鉴定两种化学添加剂中阴离子表面活性剂

本文提出用ＦＡＢ－ＭＳ和ＤＣＩ－ＭＳ法对两种工业化学添加剂中阴离子表面活性剂成份的鉴定方案，方法简便，并对类似未知物的鉴定有参考价值。所得结果为其它方法和应用试验进一步证实。     

Fifth-order phase-sensitive detection of ultrafast polarization beats in cascade four-level system

We study the colour-locked twin-noisy-field correlation effects in the fifth-order nonlinear susceptibility of ultrafast polarization beats in a cascade four-level system. More importantly, the fifth-order phase-sensitive heterodyne detection of ultrafast polarization beats has been exploited. The fifth-order nonlinear optical response can be controlled and modified through the colour-locked correlation of twin noisy fields. Thus, this method with the phase dispersion information is a good way to measure the real and imaginary parts of the fifth-order nonlinear susceptibility.