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In order to shed light upon the nature and mechanism of 4f-3d magnetic exchange interactions, a series of binuclear complexes of lanthanide(3+) and chromium(3+) with the general formula [Ln(L)5(H2O)2Cr(CN)6]·mL· nH2O (Ln=La (1), Ce (2), Pr (3), Nd (4); x=5, y=2, m=1 or 2, n=2 or 2.5; L=2-pyrrolidinone) and [Ln(L)4(H2O)3Cr(CN)6] ·nH2O (Ln=Sm (5), Eu (6), Gd (7), Tb (8), Dy (9), Er (10); x=4, y=3, m=0, n= 1.5 or 2.0; L=2-pyrrolidinone) were prepared and the X-ray crystal structures of complexes 2, 6 and 7 were determined. All the compounds consist of a Ln-CN-Cr unit, in which Ln^3+ in a square antiprism environment is bridged to an octahedral coordinated Cr^3+ ion through a cyano group. The magnetic properties of the complexes 3 and 6-10 show an overall antiferromagnetic behavior. The fitting to the experimental magnetic susceptibilities of 7 give g= 1.98, J=0.40 cm^-1, zJ'= -0.21 cm^-1 on the basis of a binuclear spin system (Scd=7/2, Scr=3/2), revealing an intra-molecular Gd^3+-Cr^3+ ferromagnetic interaction and an inter-molecular antiferromagnetic interaction. For 7 the calculation of quantum chemical density functional theory (DFT), combined with the broken symmetry approach, showed that the calculated spin coupling constant was 20.3 cm^-1, supporting the observation of weak ferromagnetic intra-molecular interaction in 7. The spin density distributions of 7 in both the high spin ground state and the broken symmetry state were obtained, and the spin coupling mechanism between Gd^3+ and Cr^3+ was discussed. 相似文献
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介绍了HL-2A装置低杂波加热系统中的低压部分实时保护系统的原理和工作情况。实时保护电路工作可靠,系统低压部份响应延迟时间小于1μs。在2004年的单只速调管实验中,对波导内拉弧打火,速调管管体电流和速调管集电极过流进行了实时保护,各个保护对象都有专用的探头进行测量,其中管体电流探头精度达到0.7%。实验信号的分析表明保护系统的设计达到了实验要求,有效地保护了实验对象。 相似文献
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Femtosecond(fs) pulse laser ablation of silicon targets in air and in vacuum is investigated using a timeresolved shadowgraphic method. The observed dynamic process of the fs laser ablation of silicon in air is significantly different from that in vacuum. Similar to the ablation of metallic targets,while the shock wave front and a series of nearly concentric and semicircular stripes,as well as the contact front,are clearly identifiable in the process of ablation under 1×10 5 Pa,these phenomena are no longer observed when the ablation takes place in vacuum. Although the ambient air around the target strongly affects the evolution of the ablation plume,the three rounds of material ejection clearly observed in the shadowgraphs of fs laser ablation in standard air can also be distinguished in the process of ablation in vacuum. It is proven that the three rounds of material ejection are caused by different ablation mechanisms. 相似文献
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一幅灰度图像的相息图被隐藏于一幅宿主图像中,该相息图是采用基于相息图迭代的双随机相位加密技术得到的.由于采用仅含有位相信息的相息图作为待加密灰度图像信息的载体,因而与隐藏图像同时具有振幅和相位信息的情况相比较,需要隐藏的信息量大大降低,从而可在对宿主图像影响较小的情况下,提高提取信息的质量;并可有效地提高信息提取时的光学效率,并且对二元图像信息的隐藏也同样适用.水印图像的剪切对隐藏信息提取质量的影响也被分析,模拟实验结果证明了所采用方法的有效性. 相似文献
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农产品质量安全是社会广泛关注的重大民生问题。近年来,农产品生产过程中农药的广泛使用和滥用会导致农药残留,对人类健康和环境造成潜在危害。吡虫啉是一种硝基亚甲基类新烟碱内吸杀虫剂,因其具有广谱、高效和低毒的特性已广泛用于农业生产中,但其过量残留也给人类的健康带来了威胁。首先对超材料结构的透射谱进行了分析,对共振频率的形成原因进行了解释;其次分别在超材料结构和二氧化硅基底上涂覆了500 mg·L-1的吡虫啉溶液并进行了测量,排除了二氧化硅基底的影响;接着制备了3个梯度15个浓度的吡虫啉溶液,分别为:100~500 mg·L-1(梯度为100 mg·L-1)、10~50 mg·L-1(梯度为10 mg·L-1)、1~5 mg·L-1(梯度为1 mg·L-1);测量了喷涂在超材料结构上的吡虫啉薄膜的太赫兹时域光谱,根据太赫兹透射谱峰值频率红移量的不同实现了对不同溶液浓度的鉴别,建立了峰值频率红移量和吡虫啉浓度的函数关系。实验结果表明,借助超材料的调制特性,太赫兹光谱法可以检测到浓度低至1 mg·L-1的吡虫啉薄膜。将实验测得的不同浓度吡虫啉溶液的折射率,代入CST软件进行仿真验证,结果说明不同浓度的吡虫啉的透射曲线具有不同程度的红移,且红移量随着浓度的增大而增加。实验和仿真结果表明,超材料对太赫兹光谱透射峰值频率的调制可用于低浓度吡虫啉含量的太赫兹时域光谱检测。此研究为食品基质中农药残留的检测提供了一种新方法。 相似文献