维多利亚艳蓝分光光度法测定镓

以聚乙二醇辛基苯基醚为稳定剂,在pH 2.4的磷酸-磷酸二氢钠缓冲溶液中,维多利亚艳蓝Bo与Gal4-反应生成缔合物,缔合物的最大吸收波长560 nm,表观摩尔吸光率5.53×105L·mol-1·cm-1.镓(Ⅲ)的质量浓度在1.3×10-3～7.0×10-2mg·L-1范围内遵守比耳定律.应用此方法测定了煤矸石和煤灰中痕量镓,所得结果与国家标准方法测得的结果相符.其相对标准偏差(n=8)均小于3%.测得方法的回收率97%～101%.     

717型阴离子交换树脂吸附水溶性芳香族有机污染物研究

研究了717型阴离子交换树脂对苯酚、苯甲酸和十二烷基苯磺酸钠(SDBS)等水溶性芳香族污染物吸附过程的基本化学问题.研究结果表明:717型树脂对苯酚、苯甲酸和SDBS的吸附过程均符合Lagergren二级吸附动力学方程,吸附速率均随着温度的升高而加快,吸附表观活化能Ea分别为13.2kJ/mol、59.5kJ/mol和48.1kJ/mol,吸附过程△H0和△S0均为正值,△G0均为负值,吸附能够自发进行;吸附等温模型符合Langmuir等温式;318K时,717型树脂在pH=9.1对SDBS的饱和吸附容量为360mg/g;在pH=10.2,对苯酚和苯甲酸的饱和吸附容量分别为194mg/g和286mg/g.用浓度均为0.5mol/L,体积比为5∶1的NaCl-NaOH混合溶液可快速洗脱树脂上吸附的污染物,洗脱率达98％以上.该树脂对水溶性芳香族污染物吸附容量大,易于再生和循环利用,可用于环境水体中水溶性芳香族有机污染物的吸附治理.     

基于纳米粒子的比色检测及其在化学传感及生物检测的应用

基于纳米粒子的比色检测由于其简单性、多样性而备受关注。在该体系中,目标分析物直接或间接诱发纳米粒子的聚集和分散,从而可通过溶胶的颜色改变实现分析检测。该综述介绍了纳米粒子分散及聚集过程的物理现象,简单讨论了纳米粒子间的作用力,对两种作用机制(粒子间交联和非粒子间交联来调节纳米粒子的分散和聚集)进行了介绍。并对纳米粒子在重金属离子检测、生物检测等方面的应用及方法的分析特性进行了概述,对其未来发展趋势进行了展望。     

应急管理关键因素的混合型识别方法研究

如何细致识别出自然灾害下应急管理的关键因素,对于开展科学有效的应急管理具有重要的现实意义。本文提出一种新的应急管理关键因素的混合型识别方法,该方法通过构建三角模糊数为基本语言集、三角区间模糊数为补充语言集的评价尺度集,建立混合型初始直接关联矩阵并将之转化为区间数直接关联矩阵,进而实现中心度和原因度的综合排序,从而据此有效的识别出应急管理的关键因素,为制订高效科学的应急管理政策提供良好的方法论支持。同时,通过一个算例表明了本方法具有良好的识别效果。本混合型识别方法突破了已有研究单一性模糊评价尺度集的局限性,具有方法论创新价值,并在关键因素识别领域具有较好的应用普适性。     

高光谱图像的分布式近无损压缩

星载高光谱图像的有效压缩已经成为高光谱遥感领域亟待解决的难题。分布式信源编码具有较低的编码复杂度与良好的抗误码性,在高光谱图像压缩领域具有广阔的应用前景。提出了一种基于多元陪集码的高光谱图像分布式近无损压缩算法。根据多元陪集码的Slepian-Wolf无损编码的压缩过程,提出了面向高光谱图像分布式近无损压缩的最优量化方案,使得高光谱图像在给定目标码率条件下的失真达到最小,在此基础上对量化值进行Slepian-Wolf无损编码,从而实现了高光谱图像的分布式近无损压缩。实验结果表明,与典型的传统算法相比,该算法取得了较好的近无损压缩性能和较低的编码复杂度。     

微量元素平衡失调危害人体健康

根据元素平衡理论指出,影响人体健康的主要因素是微量元素平衡失调。正确认识微量元素在人体内的作用,知道人体的各种疾病都与人体内的元素平衡失调有关,通过检测血液和头发相关微量元素的含量,可知道体内元素是否平衡,实现治病效果,做好防病治病的工作,提高人类健康水平。     

Impact of microsecond-pulsed plasma-activated water on papaya seed germination and seedling growth

The seed of Carica papaya consists of a hard shell-like testa with inhibitors in vivo causing slow, erratic and asynchronous germination. In this work, plasma-activated water prepared by microsecond-pulsed plasma jets (μPAW) was applied to treat papaya seeds. The μPAW after plasma activation of 30 min was about 40 ℃. The reactive species such as NO₂, NO₃, and H₂O₂ in the μPAW activated from deionized water were measured and correlated to the seed germination rate and the seedling growth performance. The μPAW-treated papaya seed achieved a higher germination rate of 90%, which is 26% higher than the control group using deionized water. Comparing the results with a hot water (40 ℃) reference group showed that the reactive species in μPAW played primary roles in germination improvement, with little effect caused by the heat shock. The μPAW also sterilized the treated seeds, reducing the germination stress. The morphological change in the seeds was observed by SEM, showing an effect of physical etching after treatment promoting seed imbibition. The biochemical mechanism of the seed germination was deduced with reference to the evolution of surface chemistry, functional groups, and ABA content. The accelerated seed metabolism observed was corresponded to the chemical modification pathway. Besides, early seedlings developed from treated seeds were observed to be healthy, grow more leaves, and have better root structures. The content of MDA in the treated papaya seedlings decreased along with increased SOD and higher ion concentration. The μPAW that can be prepared at atmospheric pressure for bulk production offers a low-risk and cost-effective seed priming technology that may significantly increase the production of agricultural crops.     

Cu-Fe基催化剂上合成气直接制取低碳烯烃的研究

我们采用浸渍法制备了γ-Al2O3负载的Cu-Fe基催化剂,并结合其反应性能和XRD、H2-TPR和XPS等表征结果研究了其催化合成气直接制低碳烯烃的反应行为.结果表明,合成气直接制低碳烯烃Cu-Fe基催化剂的活性组分Cu和Fe之间存在明显的协同效应,Cu-Fe基催化剂表现出优异的合成气直接制低碳烯烃反应性能;Cu基催化剂中引入少量Fe组分明显提高了活性组分Cu的分散度,促进了Cu活性组分的还原,进而有利于催化剂反应性能的改进.初步推断Cu-Fe基催化剂上合成气转化生成低碳烯烃的主要反应历程为CO加氢生成含氧化合物(醇醚等)后再脱水生成低碳烯烃.     

椭圆平顶高斯光束及其传输特性

用张量光学方法定义了三维不可分离变量的椭圆平顶高斯光束(EFGB),导出了这种光束经过非轴对称光学系统的传输公式及相应的张量ABCD定律, 并对EFGB经过自由空间的传输作了数值计算。结果表明, EFGB的传输特性依赖于阶次, 而且耦合EFGB的光强分布在传输过程中会发生旋转。     

Propagation of Partially Coherent Twisted Anisotropic Gaussian—Schell Model Beams in the Spatial—Frequency Domain

The generalized Collins formula for partially coherent beams through axially non-symmetrical optical systems in the spatial-frequency domain is derived by means of the tensor method.Based on this formula,the tensor ABCD law in the spatial-frequency domain for partially coherent twisted anisotropic Gaussian-Schell model (GSM) beams is derived,which governs the transformation of the twisted anisotropic GSM beams in the spatialfrequency domain.An example of an application is provided.