共轭荧光分子光子晶体发光材料的可控制备与性能研究

利用自组装技术结合溶胶-凝胶法成功制备了高度有序且光子带隙可控的聚甲基丙烯酸甲酯蛋白石光子晶体样品,并对其表面形貌、透射光谱和发射光谱进行了表征,研究了光子带隙与微球直径、带隙位置与入射光角度之间的依赖关系。     

大鼠去势后肾上腺与前列腺中Cypl7al基因的表达

通过定量检测大鼠去势前后肾上腺和前列腺中Cypl7al基因的表达,试图从分子水平解释去势手术后大鼠机体内雄性激素水平的变化。     

全渠道服务商在线上自助服务技术背景下的定价策略研究

在线上自助服务技术兴起的背景下,研究餐饮业服务商整合全渠道的定价策略。分析归纳了三种提供服务的渠道(线下取号排队、线上取号排队、线上预定);利用排队论以及依据消费者效用对服务系统进行理论建模,并结合数值分析,为服务商如何应对不同的消费者与市场环境指明了方向。研究发现:(1)给出了三种服务渠道的最优定价模型表示,并结合市场情况分析不同的定价策略,如在服务高峰期可以采取歧视定价策略;(2)指明了线上取号与线上预定两种渠道不宜同时提供,并给出了最优的线上预定的预留容量比例,对商家设计渠道具有指导意义;(3)发现了不管线下消费者比例如何,服务商营收曲线必定经过同一点,对服务商采取措施引流具有启发意义。本文对服务商全渠道理论建模具有启发意义。     

在线固相萃取-毛细管高效液相色谱联用测定奶酪中的生物胺

采用双二元泵毛细管液相色谱,通过六通阀实现了样品的在线净化与分离定量的自动切换,建立了同时测定奶酪中的15种生物胺的在线固相萃取-毛细管高效液相色谱联用方法。通过优化毛细管高效液相色谱的分离条件,考察在线固相萃取流动相的组成、上样溶液pH值以及六通阀的切换时间对生物胺回收率的影响,确定最佳分析条件为：5%乙腈-水作为固萃柱(Zorbax SB-C18)的流动相,上样溶液pH=11,上样3 min后切换六通阀。采用内标法定量,15种生物胺标准曲线的线性范围为0.25~50.0 mg/L,检出限( LOD)为0.05~0.25 mg/L,定量限(LOQ)为0.15~0.80 mg/L。除了甲胺、乙胺、3-甲基丁胺和5-羟基色胺外,其余生物胺的不同添加水平(1,20和40 mg/kg)下的加标回收率为79.6%~118.7%;除3-甲基丁胺和5-羟基色胺外,其余生物胺的RSD在0.3%~14.9%之间,可用于奶酪中多种生物胺的快速检测。     

Study on the spectral response of the Schottky photodetector of GaN

The Schottky photodetector was fabricated on GaN epilayers grown by metalorganic chemical vapour deposition (MOCVD). The spectral response of the Schottky photodetector was characterized. A new model is proposed to interpret the characteristic of the spectral response curve of the Schottky photodetectors by introducing a penetrating distance of an incident light at a certain wavelength in the current continuity equation and the interface recombination at the metal--semiconductor rectifying contact. The expressions for the spectral response of the Schottky photodetector are deduced and used successfully to fit the experimental data.     

Morphological study of the localized growth of materials in dielectric barrier discharge

The localized growth of materials has been realized in a dielectric barrier discharge reactor in the mixture of acetylene and argon in previous work. In this paper, the morphology of the materials synthesized in the process is studied. The results indicate that the polymer's structure consists of three layers. The layer near the substrate is homogeneous with thickness of several micrometres; the middle layer is composed of dense bulges with height of about more than 10μm in average. The distance between two neighbouring bulges is about 230μm; the top layer is made up of a few large columns with the height up to 2mm, and with the average distance of about 3.5mm. The growth of the three layers corresponds to three types of discharge. The discharge mechanism is analysed through studying the morphology of the polymer. It can be deduced from the morphology that the first and second discharge phases should belong to the Townsend breakdown, and the last discharge phase should be explained on the basis of the streamer mechanism.     

高效液相色谱法测定番泻甙及其代谢产物番泻素

采用高效液相色谱法分离测定番泻甙A和B及其代谢产物番泻素A和B,其色谱条件为：色谱柱Spherisorb C 18 不锈钢柱(250 mm×4.6 mm i.d., 10 μ m),柱温40 ℃;检测波长 360 nm;流动相A为1.25%(体积分数)乙酸水溶液,流动相B为甲醇,线性梯度程序为100%A20 min100%B。该方法快速、准确,能够对番泻甙的整个代谢过程进行实时分析。     

模糊层次分析法在矩阵论教材评价方面的应用

基础学科的教材直接影响学生的基本功,尤其是几乎每个学科都会涉及的数学类教材,如矩阵论.矩阵论是研究生的基础课程,在对学生以后的学术道路有举足轻重的作用.所以选择一本合适的教材,对学生和教师来说都有不小的帮助.然而,对教材的评价而言,不能单单从一个方面入手,因此将模糊综合分析法与层次分析法结合,在矩阵论教材的评价方面建立评价体系,为高校选择合适的教材提供依据.     

Light-Induced Agglomeration and Diffusion of Different Particles with Optical Tweezers

The dynamic process of light-induced agglomeration of carbon nanotubes （CNTs）, C60 and Escherichia coli （E.eoli） in aqueous solutions is demonstrated using an optical tweezers system. Based on the results, the diameter of the agglomerated region and the agglomeration rate increase with the increasing laser power. After the saturation-stable period, CNTs diffuse completely, C60 clusters only diffuse partially, and E. coli never diffuses in the agglomeration region. Theoretical analyses show that the molecular polarization and thermal diffusion of particles play crucial roles in the diffusion process. The and sort nanoparticles. results indicate the possibility of using light to aggregate     

滑动接枝聚合物对聚乳酸的增韧改性

通过熔融共混的方法,在聚乳酸(PLA)中加入不同质量分数的滑动接枝聚合物(SGC),对其进行增韧改性。使用扫描电子显微镜(SEM)用来表征PLA和SGC共混物的相结构,冲击断裂样条断面SEM考察聚合物的增韧机理,差示扫描量热分析(DSC)和广角X-射线衍射(XRD)用来考察PLA以及PLA/SGC共混物的热性能和结晶性能。结果表明:PLA和SGC粒子呈现典型的"海-岛"结构,SGC粒子尺寸为0.8μm~4.1μm。含20%(wt)SGC的PLA/SGC共混物的断裂伸长率和缺口冲击强度较纯PLA分别提高了6倍和2倍,说明SGC能够有效地对PLA进行增韧改性。体外细胞毒性测试表明,PLA/SGC共混物的细胞毒性等级为1级,为无毒材料,因此可应用在生物医学领域。