华根霉脂肪酶有机相酯合成活性的重塑

研究了具有较高酯合成活性的华根霉膜相关脂肪酶及其沉淀酶蛋白的重折叠处理过程, 发现膜成分及表面活性剂可能是影响其活性的关键因素. 进一步考察了影响异源表达的可溶性华根霉脂肪酶r27RCL酯合成活性重塑的关键因子及作用阶段. 研究结果表明, 表面活性剂对脂肪酶的酯合成活性具有关键影响, 直接添加表面活性剂可使酯合成活性显著提高. 在7种不同表面活性剂中, 两性离子表面活性剂LPC14将r27RCL的酯合成活性提高了5.75倍. 分子动力学模拟结果表明, 在有机相反应中, 表面活性剂的添加使脂肪酶催化三联体之间的氢键作用力得到加强, 从而提高了脂肪酶的有机相酯合成能力.     

表面活性剂对华根霉脂肪酶有机相酯合成活性的激活

利用表面活性剂结合无机盐与华根霉(Rhizopus chinensis)脂肪酶(RCL)共冻干,以提高RCL在有机相中的酯合成活性.结果表明,n-十二烷基-β-D-麦芽糖苷(DDM)可以显著激活RCL的酯合成活性.DDM激活效果的关键影响因素是DDM与RCL的摩尔比,而非DDM浓度;当二者摩尔比大于30时,RCL酯合成活性随着该比值的增大而提高.此外,添加适量无机盐可以进一步强化DDM对脂肪酶酯合成活性的激活效果.利用激活的RCL分别在有机溶剂和无溶剂体系中催化生物香料己酸乙酯和生物柴油油酸乙酯的合成,酯合成效率得到明显提高,表明该方法的有效性和适用性.     

N-甲基-N-(2-甲基丙烯酰氧乙基)-对-甲苯胺对甲基丙烯酸甲酯聚合的影响

<正> 我们曾报道可聚合的芳叔胺N-甲基-N-(2-甲基丙烯酰氧乙基)苯胺(MEMA)与有机过氧化物如过氧化二苯甲酰(BPO)、过氧化二月桂酰(LPO)组成氧化还原引发体系用于甲基丙烯酸甲酯的聚合。虽然文献报道了N-甲基-N-(2-甲基丙烯酰氧乙基)-对-甲苯胺(MEMT)的合成,但没有研究它对甲基丙烯酸甲酯自由基聚合的影响。本文研究了MEMT对BPO或LPO引发MMA聚合的影响,从聚合动力学研究表明BPO/MEMT组成氧化还原引发体系。其引发机理与BPO/MEMA很相似。     

THE EFFECTS OF N-2-HYDROXYETHYL-N-METHYL-p-TOLUIDINE ON METHYL METHACRYLATE RADICAL POLYMERI-ZATION AND ACRYLONITRILE PHOTOINDUCED POLYMERIZATION

The effects of N-2-hydroxyethyl-N-methyl-p-toluidine (HMT) on MMA polymerization using organic peroxide as an initiator and on AN photoinduced polymerization have been investigated respectively. The kinetics of polymerization and the overall activation energy of polymerization were determined. Based on kinetics study and the end group analysis of the polymer obtained by UV spectrum method, the initiation mechanism is proposed.     

Dynamically tunable terahertz passband filter based on metamaterials integrated with a graphene middle layer

The dynamic tunability of a terahertz(THz) passband filter was realized by changing the Fermi energy(E_F) of graphene based on the sandwiched structure of metal-graphene-metal metamaterials(MGMs). By using plane wave simulation, we demonstrated that the central frequency( f_0) of the proposed filter can shift from 5.04 THz to 5.71 THz; this shift is accompanied by a 3 dB bandwidth(? f) decrease from 1.82 THz to 0.01 THz as the EFincreases from 0 to 0.75 eV.Additionally, in order to select a suitable control equation for the proposed filter, the curves of ? f and f_0 under different graphene EFwere fitted using five different mathematical models. The fitting results demonstrate that the Dose Resp model offers accurate predictions of the change in the 3 dB bandwidth, and the Quartic model can successfully describe the variation in the center frequency of the proposed filter. Moreover, the electric field and current density analyses show that the dynamic tuning property of the proposed filter is mainly caused by the competition of two coupling effects at different graphene EF, i.e., graphene-polyimide coupling and graphene-metal coupling. This study shows that the proposed structures are promising for realizing dynamically tunable filters in innovative THz communication systems.     

基于石墨烯编码超构材料的太赫兹波束多功能动态调控

提出了一种基于石墨烯带的太赫兹波段的1 bit编码超构材料,可以实现太赫兹波束的数目、频率、幅度等参数多功能动态调控.该结构由金属薄膜、聚酰亚胺、硅、二氧化硅、石墨烯带组成.通过对石墨烯带施加两种不同的电压,可以实现一定频率范围内相位差接近180?的"0"和"1"数字编码单元,进而构成1 bit动态可控的编码超构材料.全波仿真结果表明,不同序列的编码超构材料能够实现波束数目从单波束、双波束、多波束到宽波束的调控.相同序列的编码超构材料,通过施加石墨烯带的不同电压能够实现宽频段波束频率的偏移.对于000000或者111111周期序列的编码超构材料,通过施加石墨烯带的不同电压还能够实现波束幅度的调控.因此这种基于石墨烯带的编码超构材料为灵活调控太赫兹波提供了一种新的途径,将在雷达隐身、成像、宽带通信等方面具有重要的意义.