Fe、Ni共掺杂ZnO基稀磁半导体光学性能与铁磁性研究

采用水热法成功制备了不同掺杂浓度的Zn_1-2xFe_xNi_xO（x=0,0.025,0.05,0.1）稀磁半导体材料,利用X射线衍射（XRD）、透射电子显微镜（TEM）和X射线能量色散分析仪（XEDS）对样品进行表征,并结合拉曼（Raman）光谱、光致发光光谱（PL）和振动样品磁强计（VSM）研究样品的光学性能和磁学性能。结果表明,水热法制备的样品具有结晶性良好的纤锌矿结构,没有杂峰出现,形貌为纳米棒状结构,分散性良好。Fe²⁺、Ni²⁺是以替代的形式进入ZnO晶格中,Fe和Ni的掺杂使得晶体中的缺陷和应力增加,拉曼光谱峰位发生红移,光致发光光谱发生猝灭现象。另外,共掺杂样品在室温条件下存在明显的铁磁性,饱和磁化强度随着掺杂量的增加而增强。     

Investigation on the Percutaneous Enhancing Permeation Mechanism of Azone for Ketoprofen Based on the Intermolecular Hydrogen-bonding Interaction

The permeation enhancing activity of Azone for ketoprofen through excised cavia skins was investigated using Franz diffusion cell. The possible hydrogen-bonded complexes formed between ketoprofen and the model molecule of Azone as azacyclopentane-2-one were fully optimized at the B3LYP/6-311++G** level. The intermolecular hydrogen-bonding interactions were calculated using the B3LYP/6-311++G**, B3LYP/6-311++G(2df, 2p), MP2(full)/6-311++G** and MP2(full)/6-311++G(2df, 2p) methods, respectively. The results show that the steady-state permeation rate of ketoprofen through excised cavia skins enhances over 9 times in the solvent with 2% Azone as compared with the solvent without Azone. The stable O–H···O=C and N–H···O=C hydrogen-bonded complexes could exist between azacyclopentane and ketoprofen. The hydrogen-bonding interaction energy follows the order of(a) (b) (c) (d) (g)(e) (h) (f). The formation of the complexes leads to the change of the conformation and molecular polarity of ketoprofen, and thus causes a better percutaneous permeation for the drug. The analyses of AIM(atom in molecule) and shift of electron density were used to further reveal the nature of the enhancing permeation activity of Azone for ketoprofen. The investigations of the temperature and solvent effects confirm that ketoprofen might enter into the skin by means of the Azone complex.     

小型空气源热泵热水机组实验研究

针对目前空气源热泵热水器存在的问题,建立了以制冷剂R134A为工质的实验台进行实验研究,在不同的环境温度、供水温度的不同、制冷剂的种类、制冷剂流量的大小、制冷剂的充注量的多少、换热器和压缩机及节流装置等因素影响下得出数据.通过分析空气源热泵的工作原理和实验装置,提出了提高空气源热泵热水器性能的优化措施,为设计高效热泵热...     

金表面巯基化DNA单层性能的影响因素研究

巯基化DNA在金表面上吸附构建的自组装单层（self-assembled monolayers,SAMs）为DNA研究的理想异相体系,在DNA内电子传递的机制探讨、高灵敏DNA传感器设计以及DNA碱基错配点识别等方面有着广泛的应用。对于不同的研究对象应构建性能适合的DNA单层,以满足研究需要。为了可控构建DNA单层,应理解不同因素对金表面上DNA单层性能的影响。本文从金表面状况、DNA特性以及周围环境三个方面对金表面上巯基化DNA单层性能的影响因素研究进行了系统综述。     

Fe、Ni掺杂ZnO纳米棒的水热法制备与磁性能研究

采用水热法制备稀磁半导体材料,样品Zn0.95 Fe0.05O和Zn0.95Fe0.03Ni0.02O的XRD图谱和TEM图谱发现,样品具有纤锌矿结构,形貌为纳米棒状结构.XEDS分析显示,掺杂的Fe和Ni元素进入到了ZnO晶体中.RAMAN光谱表明,Zn2+被Fe2+、Ni2+替换,晶体发生拉曼光谱红移.PL光谱分析发现,在室温条件下,随着Fe2+和Ni2+的掺杂,出现了猝灭现象.VSM测量显示,掺杂样品在室温条件下存在明显的铁磁性,且这种铁磁性属于稀磁半导体的内禀属性.实验结果表明在水热法条件下,获得了ZnO基稀磁半导体材料样品,且样品具有良好的光学和磁学特性,为进一步研究稀磁半导体材料提供了一定的参考.     

Uniform Acoustic Cavitation of Liquid in a Disk

A dynamical propagation model coupled to the oscillation of cavitation bubbles is applied to describe the imploding acoustic field in a cavitating liquid where the acoustic waves transmit from the outside to the inside of a circle disk. Numerical simulation shows that the imploding ability of a ring source can elevate the sound pressure or partly eliminate the decay due to both the bulk attenuation and the attenuation caused by cavitation. However,the imploding ability is limited and there exists a critical radius. When the radius of the disk is larger than the critical one, the imploding ability is not enough to eliminate the attenuation. Fortunately, the cavitation region can be effectively expanded if a hot plate is attached under the center of the disk because the cavitation threshold is related to the temperature of the liquid, which means that a region with good uniformity of cavitation can be enhanced by adjusting the temperature difference between the central and side liquid.     

基于FPGA自主控制浮点加减控制器设计

为实现一种能够自主完成浮点数加/减运算功能的浮点数加/减运算执行控制器,提出了一种基于采用FPGA并行操作电路硬连接的浮点数加/减运算控制电路及其时序控制方法;该控制器在接收到操作数类型与参与运算的操作数后,在内部时序脉冲作用下,可以自主完成操作数的配置以及浮点数加/减法运算的功能,运算结果传输到系统数据总线;论述了该控制器的电路构成和基本原理,分析操作数类型与操作数在内部时序脉冲作用下的执行过程,应用Verilog HDL语言实现相关硬件的构建和连接;设计完成后通过仿真测试可知,该控制器运行的最高频率可达178.317 M,从输入端口到输出端口的延时数据为:最小延时是3.185 ns,最大延时是15.336 ns,耗用的IO输入输出端口占总资源的27.92%,数据表明该控制器提高了运算器的运算速度,且能够自主完成浮点数加/减运算。     

清热解毒口服液中微量元素的测定

用HNO3-HClO4(4+1)混酸消解液对三种清热解毒口服液进行消化处理,采用火焰原子吸收光谱法测定了消化液中微量元素Cu、Zn、Fe、Mn、Ca、Mg的含量。结果表明,三种不同品质的清热解毒口服液中微量元素含量差别较大,微量元素的含量可以作为清热解毒口服液质量监控体系的重要指标之一。方法的加标回收率在96.7%—104.0%之间,相对标准偏差RSD小于1.79%,测定方法准确快速,结果可靠。此测定结果为建立和健全中药的质量监控体系提供了重要的科学依据。     

二元紧支撑正交小波的构造

§ 1.　Introduction　　SinceDAUBECHIES [1 ]gavethewellknownconstructionofunivariatecompactlysup portedorthonormalwavelets,considerableattertionhasbeenspentonconstructingmultivariatecompactlysupportedorthonormalwavelets [2— 5etc.] .Althoughmanyspecialbivariatenon separablewaveletshavebeenconstructed ,itisstillanopenproblemhowtoconstructbivariatecompactlyorthonormalwaveletsforanygivencompactlysupportedscalingfunction .Thepur poseofthispaperistoconstructcompactlysupportedorthogonalwaveletass…     

中空碳材料用于钠离子电池负极的研究进展

实现钠离子电池等储能设备的大规模应用对于能源的可持续发展以及完成“碳达峰碳中和”目标具有重要意义.开发高性能的负极材料可提升钠离子电池的能量密度和循环稳定性,是实现钠离子电池大规模应用的关键性因素.中空碳材料因其独特的结构而具有优异的倍率性能与循环稳定性,作为钠离子负极材料具有广阔的应用前景.本文从多角度出发,综合评述了中空碳材料的合成方法,以及其形貌、杂原子修饰策略与储钠性能之间的关系,并对其未来发展方向进行了展望.