血卟啉及金属血卟啉对嘌呤衍生物识别作用的研究

采用紫外光谱法、荧光光谱法和核磁共振谱法研究了嘌呤与血卟啉及金属血卟啉的作用情况,并对影响因素(酸度和离子强度等)进行了试验。结果表明在pH 11.2 的Kolthoff缓冲溶液中,嘌呤有很强的荧光峰,且血卟啉及金属血卟啉对嘌呤有明显的识别作用,结合常数在104～105, 结合比均为1∶1。金属血卟啉的结合常数：K_Ni(Ⅱ)-HP＞K_Co(Ⅱ)-HP＞K_Zn(Ⅱ)-HP＞K_Cu(Ⅱ)-HP,同时对识别机理进行了讨论,提出了两点和三点作用模式的识别机理。     

集中载荷作用下薄壁开口曲杆的稳定性

本文研究了薄壁开口曲杆的稳定性问题.该曲杆的边界条件比较复杂,一端固支,另一端既有对位移的限制,又有集中力和集中力矩作用.本文从薄壁开口曲杆的平衡方程出发,应用假想分布载荷法,导出一组关于曲杆稳定性的变系数常微分方程.为了解特征值问题,应用有限差分法,将特征方程用矩阵形式表达.对某一产品结构中的实际构件进行了数值计算与稳定性试验,构件为一Ⅰ字形截面的薄壁开口曲杆,对特征方程应用矩阵迭代法求得临界载荷的理论计算值.应用Southwell法结合最小二乘法整理了重复试验所获得的数据,得到临界载荷的实验值,理论计算值与实验值接近.     

变形—损伤耦合的超塑性恒压轴对称充模胀形的有限元模拟

采用大变形刚粘塑性有限元法模拟超塑性恒压轴对称充模胀形过程，分析了模具几何参数及材料参数对胀形过程中材料的流变行为、胀形制件厚度分布和成形时间的影响规律，给出了质点的流动轨迹，不同时刻制件的剖面形状及应力、应变分布；基于修正的Ｇｕｒｓｏｎ粘塑性势推导了内部空洞体积分数累积增大模型并据此进行了变形－损伤耦合计算。     

镍基合金—碳化铬复合涂层耐磨特性的研究

用真空烷烧法在４５＃钢表面制取了镍基合金－碳化铬复合涂层，用扫描电子显微镜和Ｘ射线衍射仪分析了这种涂层的微观结构，物相组成和性能，并对这种涂层的耐磨性进行了试验研究。     

Effect of Topological Connectivity on Firing Pattern Transitions in Coupled Neurons

By using the coupled model of Hindmarsh-Rose neuronal systems, we numerically investigate the effect of topology structures on the firing patterns transition （FPT）. A four-cell coupled system with all possible configurations are studied. We select the membrane current Iext as a controllable parameter, and set it to be near the left side for one of the bifurcation points. It is found that to have a response from some external stimuli with the proper amplitude and frequencies, the transition will appear between different firing states only when the cells in the system are coupled with some proper topological structures, which implies the occurrence of FPT induced by the configuration in the coupled system. Similar FPT phenomena could also be observed in a five-cell coupled system. Fbrthermore, we find that such transition behaviors may have some inherent relevance with the synchronization error and the average connective number among cells in the coupled system for different topology structures. These results suggest that the biological neuron systems may achieve an effective response to the external feeble stimulus by selecting the proper configuration and using the corresponding transition mode.     

F原子吸附TiO_2:Mn(001)稀磁半导体薄膜电子结构和磁性的第一性原理计算

利用第一性原理方法计算Mn离子掺杂纯净TiO2(001)和F原子吸附的TiO2(001)薄膜的形成能、态密度和磁矩.F原子吸附明显降低TiO2∶Mn薄膜体系的形成能.F原子的吸附导致Mn离子的磁矩减小,而表面O原子的磁矩增大.表面O原子的磁矩主要来源于O原子p x和p y轨道的自旋极化,研究表明表面吸附F原子更有利于Mn离子的掺杂,在一定程度上有利于获得结构稳定的铁磁态半金属特性的TiO2∶Mn薄膜.     

具偏差变元的广义平均曲率方程同宿解的存在性

In this paper, by using Mawhin＇s continuation theorem and some analysis methods,the existence of a set with 2kT-periodic solutions for a kind of prescribed mean curvature equation with a deviating argument is studied, and then a homoclinic solution is obtained as a limit of a certain subsequence of the above set.     

Topological quantum-phase coherence in full counting statistics of transport electrons with two-body interaction

The full counting statistics of electron transport through two parallel quantum dots with antiparallel magnetic fluxes is investigated as a probe to detect the topological quantum-phase coherence （TQPC）, which results in the characteristic oscillation of the zero-frequency cumulants including the shot noise and skewness. We show explicitly the phase transition of cumulant spectrum-patterns induced by the topology change of electron path-loops while the pattern period, which depends only on the topology （or Chern number）, is robust against the variation of Coulomb interaction and interdot coupling strengths. Most importantly we report for the first time on a new type of TQPC, which is generated by the two- particle interaction and does not exist in the single-particle wave function interference. Moreover, the accurately quantized peaks of Fano-factor spectrum, which characterize the super- and sub-Poissonian shot noises, are of fundamental importance in technical applications similar to the superconducting quantum interference device.     

N-甲基哌嗪与乙酸乙酯、乙酸丁酯二元混合体系在298.15～313.15K的体积及黏度性质

测定了N-甲基哌嗪+乙酸乙酯和N-甲基哌嗪+乙酸丁酯2个二元混合体系在298.15,303.15,308.15和313.15 K的密度和黏度数据,并计算了N-甲基哌嗪+酯二元混合体系的超额摩尔体积(VEm)和黏度偏差(Δη),用Redlich-Kister多项式关联了二元体系的超额摩尔体积与组成的关系,用4个半经验公式关联黏度数据并关联了二元体系的黏滞性活化参数.结果表明,N-甲基哌嗪+乙酸乙酯和N-甲基哌嗪+乙酸丁酯二元体系在所测温度范围内的超额摩尔体积为正值,黏度偏差为负值,且二元混合体系在混合过程中焓驱动居于主导地位.     

以4’-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷构筑的一维锌配位聚合物的晶体结构与荧光性质

水热条件下采用Zn(NO3)2.6H2O,4′-羟基-联苯-4-羧酸和1,3-二(4-吡啶基)丙烷作为反应物合成出一个新的一维锌金属配位聚合物{[Zn(Hhbc)2(bpp)].H2O}n(1)(Hhbc=4′-羟基-联苯-4-羧酸,bpp=1,3-二(4-吡啶基)丙烷),并分别用元素分析、红外光谱、差热分析、X-射线粉末衍射和X-射线单晶衍射等表征了该结构。晶体结构分析结果表明:化合物1为一维链状锌(Ⅱ)配位聚合物,通过分子间的O-H…O氢键作用,一维链进一步被连接成二维超分子结构。荧光分析表明常温固态下配合物1发射蓝色荧光,荧光寿命为3.08 ns(480 nm)。