Theoretical study of stereodynamics for the N+H2/D2/T2 reactions

The effects of isotopic variants on stereodynamic properties for the title reactions have been investigated using a quasi-classical trajectory method based on the first excited state NH2（I^2A＇） potential energy surface [Li Y Q and Varandas A J C 2010 J. Phys. Chem. A 114 9644]. The forward–backward symmetry scattering of the differential cross section can be observed, which demonstrates that all these reactions follow the insertion mechanism. Three angle distribution functions P（θr）, P（φr）, and P（θr, φr） with different collision energies and target molecules H2/D2/T2 are calculated. It is shown that the product rotational angular momentum is not only aligned, but also oriented along the direction perpendicular to the scattering plane. The title reaction is mainly governed by the ＂in-plane＂ mechanism through the calculated distribution function P（θr, φr）. The observable influences on the rotational polarization of the product by the isotopic substitution of H/D/T can be demonstrated.     

Fourth-Order Spatial Correlation of Thermal Light

We investigate the fourth-order spatial correlation properties of pseudo-thermal light in the photon counting regime, and apply the Klyshko advanced-wave picture to describe the process of four-photon coincidence counting measurement. We deduce the theory of a proof-of-principle four-photon coincidence counting configuration, and find that if the four randomly radiated photons come from the same radiation area and are indistinguishable in principle, the fourth-order correlation of them is 24 times larger than that when four photons come from different radiation areas. In addition, we also show that the higher-order spatial correlation function can be decomposed into multiple lower-order correlation functions, and the contrast and visibility of low-order correlation peaks are less than those of higher orders, while the resolutions all are identical. This study may be useful for better understanding the four-photon interference and multi-channel correlation imaging.     

锯齿型石墨烯带缺陷改性方法研究

采用基于密度泛函理论的非平衡格林函数, 对具有不同缺陷构型的锯齿型石墨烯带(zigzag graphene nanoribbon, ZGNR) 的输运性质进行了理论计算与模拟. 研究表明, 相同数目、 不同构型缺陷结构对ZGNR的导电特性将产生不同的影响. 如A-B构型双空缺对ZGNR电导的影响最为显著, 而A-A构型双空缺对其电导的影响最小. 更为重要的是, 当引入碳环构型缺陷时, ZGNR将被改性, 即由原本的金属性质转变为半导体性质, 为缺陷调控石墨烯导电特性提供了理论依据.     

确定磁性体在绝热磁化过程中达到最高温度的方法

在磁性体磁化过程中, 决定其能够达到的最高温度, 对磁热材料的优化选取是重要的. 本文以钆镓石榴石(Gd₃Ga₅O₁₂) 为例, 根据高磁场下趋近饱和定律的思想, 给出了低温、超强磁场下, Gd₃Ga₅O₁₂晶体等效磁化率的定量形式. 在外磁场从0---40 T范围内, 计算了该晶体的磁熵变、声子熵变以及磁性体温度随外磁场的变化, 结果均与实验值符合较好. 利用声子熵变与饱和磁熵变曲线交点的唯一性, 给出了在磁性体磁化过程中, 确定其温度达到最大值的方法, 预言了Gd₃Ga₅O₁₂晶体在绝热磁化过程中达到的最高温度为64.7K. 该方法还可以对所加外磁场大小进行预言或估计.     

基于像素灰阶熵的自适应增强算法在乳腺CR图像中的应用

乳腺完全是由密度接近软组织构成,因此乳腺CR(Computed Radiography)放射图像对比度小,轻微的差别变化都可能是肿瘤的表现,要对其进行增强处理方能满足医生临床诊断的需要。而目前通用的乳腺CR图像增强算法对比度和噪声增强过度,丢失细节,为此提出了采用一种基于像素灰阶熵的自适应边缘增强算法对乳腺CR图像进行增强。该算法使用模糊影像增加对选择空间频率的响应,以增强乳腺CR图像结构边缘和细节;算法能根据乳腺CR图像灰度特性即像素灰阶熵来自适应的调节增强程度的加权因数K。实验证明,该算法处理后的乳腺CR图像细节丰富,信噪比高,增强后的图像具有良好的视觉效果,该算法是一种有效的适合乳腺CR医学图像的边缘细节增强算法。     

Group Foliation Method and Functional Separation of Variables to Nonlinear Diffusion Equations

Generalized functional separation of variables to nonlinear diffusion equations is studied in terms of the extended group foliation method. A complete classification for the nonlinear diffusion equation with source term which admits functional separable solutions is presented.     

Thermal Properties of Materials Characterized by Scanning Electron-Acoustic Microscopy

A modified technique of scanning electron-acoustic microscopy is employed to determine thermal diffusivity of materials. Using the dependence of the electron-acoustic signal on modulation frequency of the electron beam, the thermal diffusivity of materials is characterized based on a simplified thermoelastic theory. The thermal diffusivities of several metals characterized by the modified scanning electron-acoustic microscopy are in good agreement with the referential values of the corresponding materials, which proves that the scanning electronacoustic microscopy can be used to characterize the thermal diffusivity of materials effectively. In addition, for micro-inhomogeneous materials, such as biological tissues, the macro-effective （average） thermal diffusivities are characterized by the technique.     

一种新型桥路型HTSFCL的实验研究

在研究一种新型桥路型高温超导限流器的限流原理的基础上，研制开发了一台三相600V、故障电流峰值100A的实验室样机．本文介绍了该限流器的功率电路、控制器、低温容器和高温超导磁体等部分的结构特点和功能．在三相系统中进行了各种短路故障限流实验，结果表明该限流器有较强的限流能力和重合闸能力，说明新型高温超导限流器的研究对改善电网动态性能和提高电网电能质量有十分重要的意义．     

聚合物前驱体衍生SiC纳米棒的光学性质

采用聚硅氮烷前驱体热裂解方法制备SiC纳米棒,并利用SEM、XRD和EDX表征了SiC纳米棒的结构和组成,表明得到的SiC的组分比C：Si接近1：1。用微区Raman和光致发光方法研究了纳米棒的光学性质。观测到SiC的TO模式对应的Raman峰和相邻肩峰。对SiC纳米棒观测到其紫外3．25eV附近强的光致发光峰,我们认为它归结为α型SiC带间的跃迁。通过XRD、Raman和光发射谱,我们推测前驱体热裂解得到的SiC纳米棒是一个混晶,纳米棒的表层是立方晶,而内层主要为a—SiC。     

连续变量量子离物传态的实验研究

利用单个Ⅱ类相位匹配OPA产生的双模压缩态实现连续变量压缩纠缠态，完成了连续变量量 子离物传态. Ⅱ类相位匹配OPA参量反放大过程可以实现正交振幅反关联、正交位相关联的 压缩纠缠态，这不同于一般运转于阈值以下的OPO产生的正交振幅关联、正交位相反关联的 压缩纠缠态，可以采用直接平衡测量的方法完成Bell态测量. 利用双KTP补偿非线性过程的 离散效应，获得了最大压缩大于2dB的双模压缩纠缠态，实现保真度06，考虑到探测效率 实际保真度为057. 这种方案简化了测量方法与纠缠光源产生装置，有利于进行量子通信 的实验研究与应用. 同时，讨论了探测过程中的一些非理想因素. 关键词： 量子离物传态 压缩纠缠态 Bell态测量