Resonant Tunnelling and Storage of Electrons in Si Nanocrystals within a-SiNx/nc-Si/a-SiNx Structures

The a-SiNx/nanocrystalline silicon （nc-Si）/a-SiNx sandwiched structures with asymmetric double-barrier are fabricated in a plasma enhanced chemical vapour deposition （PECVD） system on p-type Si substrates. The nc-Si layer in thickness 5nm is fabricated from a hydrogen-diluted silane gas by the layer-by-layer deposition technique. The thicknesses of tunnel and control SiNx layers are 3nm and 20nm, respectively. Frequency-dependent capacitance spectroscopy is used to study the electron tunnelling and the storage in the sandwiched structures. Distinct frequency-dependent capacitance peaks due to electrons tunnelling into the nc-Si dots and capacitance-voltage （C - V） hysteresis characteristic due to electrons storage in the nc-Si dots are observed with the same sample. Moreover, conductance peaks have also been observed at the same voltage region by conductance-voltage （G - V） measurements. The experimental results demonstrate that electrons can be loaded onto nc-Si dots via resonant tunnelling and can be stored in our a-SiNx/nc-Si/a-SiNx structures.     

有机电致发光器件的界面问题研究进展

低驱动电压下有机电致发光器件(0ELD)中的界面结构对器件效率和寿命有重要影响。本文简要介绍近年来以多种分析技术和方法研究0ELD界面分子结构、能带结构、激发态特性及反应等获得的主要结果,并提出了目前该领域存在的一些问题及发展趋势。     

压电智能结构拓扑优化研究进展

压电材料因其变形精度高、反应速度快、易于制作成小型化元件已经被广泛应用于精密驱动、振动控制、精确定位等领域。改变压电智能结构中压电元器件的位置、大小、形状等参数能够有效地改善系统的力学性能,因而吸引了许多学者和工程师的关注和研究。拓扑优化作为有效的优化工具,已经成功应用于压电智能结构的优化设计中。本文首先阐述了压电智能结构拓扑优化的背景和意义,简要回顾了压电智能结构主动控制及分析方法,并综述了面向结构静变形控制的压电智能结构优化、面向振动控制的压电智能结构优化、压电俘能器的设计与优化等三个方面的研究进展。最后,简单归纳压电智能结构拓扑优化研究中值得关注的几个问题。     

余函数_(2n)(X)的一些性质

设给定函数F(t),它在〔0,1〕上有各阶导数.作级数     

压力下的CeBi电子传导特性

在4.2—273K温区内,0—18kbar压强下,测量了CeBi单晶的电阻率。实验表明,尼尔温度随压强增大而增大,且温度T>T_N后,磁性电阻率ρ_s与lnΤ成正比。计及p-f作用,我们用Anderson模型计算了与压强有关的CeBi磁性电阻率,并将计算结果与实验比较。结果表明,4f电子能级与费密能级的距离随压强增大而减小,压强增大导致p-f作用的增强。 关键词：     

克尔型介质平板波导中的弱非线性横向电场波

对芯子为克尔型非线性介质、覆盖层和衬底为线性介质的平板波导，在弱非线性近似下，导出了这类波导横向电场波满足的色散方程和场分布，其物理意义清晰，且大大降低了数值计算的强度。     

Conservation of Hydrophobic and Hydrophilic Residues in Four-Helix Bundle

The conservation of the hydrophobic and the hydrophilic residue sites obtained from 1000 designed sequences with the Z-score method for a four-helix bundle has been studied. The folding dynamic and thermodynamic features of the designed sequences and their different mutations are also studied. It is found that this conservation is related to the stability and the fast folding of the model proteins. Our results are consistent with the experimental results.     

生物氧化还原反应中的立体化学问题

本文在具体介绍了立体化学中对映和非对映配位体及面的基础上阐述了生物体系中在辅酶——烟酰胺腺嘌呤二核苷酸作用下所进行的立体专一性的氧化还原反应。并具体分析了Krebs三羧酸循环中的立体化学问题。     

卡宾活性中间体在有机合成中的应用——Ⅱ.马鞭草烯醇类似物的合成

本文以α-蒎烯与二氯卡宾的加成物3为原料,合成了马鞭草烯醇的类似物2,7,7-三甲基三环[4.1.1.0~(2,4)]-5-辛醇及其酯类和醚类衍生物。