姜黄素对酪氨酸-过氧化氢-酶催化产物的荧光猝灭机理研究

酪氨酸在辣根过氧化物酶催化下被H2O2氧化为强荧光物质(产物S),姜黄素对其荧光产生猝灭作用,根据Stern-Volmer方程和荧光寿命法研究了姜黄素对产物S的荧光猝灭为静态猝灭.姜黄素与产物S的形成常数K=9.51×108 L/mol(25℃),结合点数n=1.94.探讨了产物S与姜黄素的反应机理,该反应的热力学参数△G=-56.11 kJ\5mol-1,△H=57.37 kJ\5mol-1,△S=365.9 J\5K-1\5mol-1,说明该反应是自发进行的吸热过程.     

SINGULAR LIMITS FOR INHOMOGENEOUS EQUATIONS OF ELASTICITY

Based on the framework introduced in [4] or [5], the singular limits of stiff relaxation and dominant diffusion for the Cauchy problem of inhomogeneous equations of elasticity is studied. We are able to reach equilibrium even though the nonlinear stress term is not strictly increasing.     

基于结构元方法的模糊数互补判断矩阵排序法

利用模糊结构元方法,研究了决策信息以模糊数互补判断矩阵形式给出的有限方案决策问题。给出了模糊数互补判断矩阵的定义,介绍了模糊数排序的一种简捷方法——组合序。在该序的基础上,对模糊有序加权平均(FOWA)算子的若干性质进行证明。利用该算子能够将模糊数互补判断矩阵转换为实数矩阵,进而,对模糊数互补矩阵的排序问题转换成实数矩阵的排序问题。只要矩阵中的元为有界闭模糊数,就可以利用FOWA算子进行排序。最后通过算例对比分析,算例表明利用本文的方法进行排序更为简捷。     

Influence factor analysis of field-free molecular orientation

The effects of the characteristics of molecules and external fields on field-free molecular orientation are investigated through the comparison of HBr with LiH driven by the combination of a two-color laser pulse and a time-delayed THz laser pulse. It is shown that the dipole interaction has greater influence on field-free orientation than the hyperpolarizability interaction. In addition to the temperature dependence of orientation degree, the effects of the amplitudes of the two-color laser pulse and THz laser pulse, rising time, and THz laser frequency on molecular orientation are also discussed.     

Laser cooling of CH molecule: Insights from ab initio study

The feasibility of laser cooling a CH molecule is investigated theoretically by employing the ab initio method. The potential energy curves for the five ∧-S states and eight Ω states of CH are determined by the multi-reference configuration interaction with the Davidson corrections(MRCI+Q) level of theory. The results agree well with the available experimental data and other theoretical values. Also, the permanent dipole moments and transition dipole moments of the CH molecule are calculated at the multi-reference configuration interaction(MRCI) level. We find highly diagonally distributed FranckCondon factors(f_(00) = 0.9950 and 0.9998) and branching ratios(R_(00) = 0.983 and 0.993) for the A~2△→ X2Π and C~2∑~+→X~2Π transitions. Moreover, the values of suitable radiative lifetime τ of the A2 A and C~2∑~+ states are evaluated to be9.64×10~(-7) s and 2.02×10~(-7) s, respectively, for rapid laser cooling. A scheme for laser cooling the CH molecule is designed. In the proposed cooling scheme, three wavelengths for A~2△→X~2Π and C~2∑~+→X~2Π transitions are used, and the main pump lasers are λ_(00)=430.86 nm and 313.45 nm, respectively. The feasibility of laser cooling the CH molecules is demonstrated for each of these schemes, and this study offers a theoretical basis for experimental research into preparation of cold CH molecules.     

基于Zigbee的高层火灾定位及语音报警系统

近年来,我国高层建筑火灾发生率呈逐年上升趋势,高层建筑防火和火灾报警的研究,显得尤为迫切和重要,其中火灾报警系统已成为必要的装置,对现代建筑起着极其重要的安全保障作用。提出了一种高层火灾定位及语音报警系统,该系统由Zigbee无线传感器网络、火灾探测器、语音单片机组成。当高层建筑发生火灾时,系统将通过火灾探测器自动判断火灾的发生,然后利用无线传感器网络在第一时间发送给各楼层终端设备,自动触发各楼层语音单片机播报火灾发生的具体楼层和逃生注意事项,可以让人们更快做出反应、选择更合理的逃生方式,为楼内人员的逃生赢得宝贵时间,由此可最大程度地保护人们的生命安全。因此,对高层防火系统的研究可大大降低居民住宅、写字楼、宾馆、饭店等高层建筑的火灾损失。     

激光冷却OH分子的理论研究

采用高精度的多参考组态相互作用方法计算OH分子基态和第一激发态的势能曲线.为获得更精确的计算结果,在计算过程中考虑Davidson修正、标量相对论效应、核价相关效应和自旋轨道耦合效应.基于计算的Λ-S和?态的势能曲线,对一维径向薛定谔方程进行数值求解,得到各个电子态的光谱数据,与已报道的实验值和理论值相符合.获得OH分子的永久偶极矩、跃迁偶极矩、振动能级、Franck-Condon因子及辐射寿命,结果表明,A~2Σ~+→X~2Π跃迁具有高度对角化的Franck-Condon因子(0.9053)和短的辐射寿命(5.8363×10~(-7)s),符合激光冷却分子的条件.制定了激光冷却OH分子的具体方案,计算得到激光冷却跃迁A~2Σ~+→X~2Π所需的三束激光波长,主光束波长为307.1532 nm,两束重抽运激光波长为344.9163和349.7659 nm.计算结果为超冷OH分子的实验制备提供重要的理论依据.     

柔性低温多晶硅薄膜晶体管的弯曲稳定性

研究了以聚酰亚胺为基板的p型低温多晶硅薄膜晶体管在不同弯曲半径下的偏压稳定性。当曲率半径从15 mm变到3 mm时,在拉伸弯曲状态下,阈值电压和平坦时保持一致(Vth=-1.34 V),迁移率μsat从45.65 cm~2/(V·s)降到45.17 cm~2/(V·s),开关比增大;在压缩弯曲状态下,转移特性曲线和平坦状态保持了非常好的一致性。在最小弯曲半径为3 mm时,进行了正负偏压稳定性测试,结果表明,器件依然具有很好的稳定性。     

修正的Kadomtsev-Petviasvili方程的对称和守恒律

修正Kadomtsev-Petviasvili (MKP)方程是非线性偏微分方程和物理学中的一个重要模型. 最近楼森岳教授指出从可积系统的一个点李对称出发, 可以得到无穷多的守恒律. 应用楼教授的思想, 首先研究MKP方程的经典的李点对称, 然后根据二阶延拓结构(Lie-Bäcklund算子), 构造MKP方程的无穷多守恒律.     

227-W output all-fiberized Tm-doped fiber laser at 1908 nm

In this paper, we report that a diode-pumped thulium-doped double clad silica fiber laser can provide powers of up to 227 W at 1908 nm, corresponding to a slope efficiency of 54.3%, and an optical-to-optical efficiency of 51.2%. The output power, to the best of our knowledge, is the highest output at 1908 nm. The beam quality M2 factor is about 1.56. Also discussed in this paper is the dependence of the laser performance on fiber length.