PREPARATION AND ELECTROCHEMICAL CHARACTERISTICS OF POLYMER ELECTROLYTE MEMBRANES BASED ON SAN/PVDF-HFP BLENDS

A copolymer of poly(acrylonitrile-co-styrene) (SAN) was synthesized via an emulsion polymerization method. Novel polymer electrolyte membranes cast from the blends of poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP), SAN and fumed silica (SiO2) are microporous and can be used in polymer lithium-ion batteries. The membrane shows excellent characteristics such as high ionic conductivity and good mechanical strength when the mass ratio between SAN and PVDF-HFP and SiO2 is 3.5/31.5/5. The ionic conductivity of the membrane soaked in a liquid electrolyte of 1 mol/L LiPF6/EC/DMC/DEC is 4.9×10-3 S cm-1 at 25℃. The membrane is electrochemical stable up to 5.5 V versus Li /Li in the liquid electrolyte. The influences of SiO2 content on the porosity and mechanical strength of the membranes were studied. Polymer lithium-ion batteries based on the membranes were assembled and their performances were also studied.     

Pd/C-HCOONH4还原体系在苯佐卡因及类似物合成中的应用

以对硝基苯甲酸乙酯为原料,Pd/C为催化剂,甲酸铵为供氢体,乙醇为溶剂,对在室温下反应得到对氨基苯甲酸乙酯的催化转移氢化反应进行了研究.在相同的催化体系下,本佐卡因的类似物也得以高效合成.该催化转移氢化反应除温和的反应条件和高催化活性外,还兼具良好的放大前景.     

NONCOMMUTATIVE ORLICZ-HARDY SPACES

Let(Φ, Ψ) be a pair of complementary N-functions and HΦ(A) and HΨ(A) be the associated noncommutative Orlicz-Hardy spaces. We extend the Riesz, Szeg and innerouter type factorization theorems of Hp(A) to this case.     

N-soliton solution of a coupled integrable dispersionless equation

<正>A new coupled integrable dispersionless equation is presented by considering a spectral problem.A Darboux transformation for the resulting coupled integrable dispersionless equation is constructed with the help of spectral problems.As an application,the N-soliton solution of the coupled integrable dispersionless equation is explicitly given.     

非线性发展方程的Riemann theta 函数等几种新解

为了构造非线性发展方程的复合型无穷序列精确解, 获得了第二种椭圆方程的Riemann theta 函数等几种新解.在此基础上,利用第二种椭圆方程与Riccati方程的Bäcklund变换和解的非线性叠加公式, 借助符号计算系统 Mathematica, 以mKdV方程为应用实例, 构造了该方程的复合型无穷序列新精确解.这里包括Riemann theta 函数、Jacobi椭圆函数、双曲函数、 三角函数和有理函数,通过几种形式构成的复合型无穷序列新精确解. 关键词： 第二种椭圆方程 Riccati方程 非线性发展方程 Riemann theta 函数无穷序列解     

重金属团簇(M2Te)3(M=Au, Ag, Cu)赝势从头算研究

使用相对论和非相对论赝势,在HF和MP2理论水平上研究了重金属混合/掺杂团簇(M2Te)3(M=Au, Ag, Cu) 的几何构型和稳定性.结果显示,团簇存在具有D3h,C2v和C3v对称性的三种稳定异构体,并且各异构体之间能量相差很小.电子相关效应对M-M键长的修正十分显著,而对M-Te键长和Te-M-Te键角的修正非常小.相对论效应使所有键长变短、Te-M-Te键角变大.两种效应都提高振动频率、降低能量,使团簇结构变得更加紧凑,使多聚物趋于更加稳定.     

解二阶椭圆本征值问题的有限元插值校正方法

§1.引言 本文介绍解二阶椭圆本征值问题的有限元插值校正方法.理论分析和数值实验都表明,此方法具有低代价和高精度的特点.这个方法是超收敛和迭代伽略金法的思想相结合的产物。 考虑二阶椭圆本征值问题:     

脉冲激光沉积的金属原子团簇的电子状态及生长的研究

 介绍了采用X射线光电子谱(XPS)等技术研究脉冲激光沉积在Ni、Mo、C、NaCl(100)表面的Cu、Au原子团簇的电子状态;结合Cu₂p_3/2 X射线光电子谱峰和Cu L₃M_4,5M_4,5俄歇跃迁分离了电子结合能的初态和终态贡献,得出了它们随Cu表面浓度变化的关系,并对之作出了解释。使用XPS、RBS、TEM三项技术研究了Au在NaCl(100)表面的生长过程,通过计算得出了在不同表面浓度下Au原子团簇的平均高度和表面覆盖率。     

辅助方程构造(2+1)维Hybrid-Lattice系统和离散的mKdV方程的精确解

给出双曲函数型辅助方程和函数变换相结合的一种方法，借助符号计算系统Mathematica构造了(2+1)维Hybrid-Lattice系统和离散的mKdV方程新的精确孤波解和三角函数波解. 关键词： 辅助方程 函数变换 (2+1)维Hybrid-Lattice系统 mKdV方程')" href="#">离散的mKdV方程     

Realization of an All-Fibre Self-Organization Intra-Cavity Coherent Erbium-Doped Fibre Laser

An intra-cavity coherent coupling Michelson Er-doped fibre （EDF） laser （MCEDFL） is proposed and demonstrated. Characteristics of the MCEDFL are investigated. It is found that the MCEDFL with a polarizer can be coherent combined effectively. By the experiment based on fibre Bragg gratings （FBGs） with different reflectivity, we find that the reflectivity of the FBG play a vital role in improving the performance of the MCEDFL. This outcome adequately shows many favourable features, such as high efficiency, easy operation, and simple all-fibre configuration.