Pd/C-HCOONH4还原体系在苯佐卡因及类似物合成中的应用

以对硝基苯甲酸乙酯为原料,Pd/C为催化剂,甲酸铵为供氢体,乙醇为溶剂,对在室温下反应得到对氨基苯甲酸乙酯的催化转移氢化反应进行了研究.在相同的催化体系下,本佐卡因的类似物也得以高效合成.该催化转移氢化反应除温和的反应条件和高催化活性外,还兼具良好的放大前景.     

柱面微通道板的制备及其性能研究

针对未来空间天文学应用的超分辨率光谱成像仪器的需求,对低噪声柱面微通道板（MCP）的制备方法及其性能进行了研究. 提出了一种将光学抛光与热成型相结合的新的柱面MCP制备方法,利用不含放射性元素的低噪声MCP玻璃,制备出曲率半径为400mm、尺寸为30mm′46mm、长径比为80:1、通道直径12.5mm、通道间距15mm的柱面MCP,并将其与感应电荷楔条形阳极（WSA）组成光子计数探测器,对其暗计数率、分辨率进行了检测,暗计数率约为0.1counts/cm2×s.     

Realization of an All-Fibre Self-Organization Intra-Cavity Coherent Erbium-Doped Fibre Laser

An intra-cavity coherent coupling Michelson Er-doped fibre （EDF） laser （MCEDFL） is proposed and demonstrated. Characteristics of the MCEDFL are investigated. It is found that the MCEDFL with a polarizer can be coherent combined effectively. By the experiment based on fibre Bragg gratings （FBGs） with different reflectivity, we find that the reflectivity of the FBG play a vital role in improving the performance of the MCEDFL. This outcome adequately shows many favourable features, such as high efficiency, easy operation, and simple all-fibre configuration.     

New exact solitary wave solutions to generalized mKdV equation and generalized Zakharov--Kuzentsov equation

In this paper, based on hyperbolic tanh-function method and homogeneous balance method, and auxiliary equation method, some new exact solitary solutions to the generalized mKdV equation and generalized Zakharov--Kuzentsov equation are constructed by the method of auxiliary equation with function transformation with aid of symbolic computation system Mathematica. The method is of important significance in seeking new exact solutions to the evolution equation with arbitrary nonlinear term.     

非线性发展方程的Riemann theta 函数等几种新解

为了构造非线性发展方程的复合型无穷序列精确解, 获得了第二种椭圆方程的Riemann theta 函数等几种新解.在此基础上,利用第二种椭圆方程与Riccati方程的Bäcklund变换和解的非线性叠加公式, 借助符号计算系统 Mathematica, 以mKdV方程为应用实例, 构造了该方程的复合型无穷序列新精确解.这里包括Riemann theta 函数、Jacobi椭圆函数、双曲函数、 三角函数和有理函数,通过几种形式构成的复合型无穷序列新精确解. 关键词： 第二种椭圆方程 Riccati方程 非线性发展方程 Riemann theta 函数无穷序列解     

介孔杭锦2~#土的制备及其光谱特性研究

以天然杭锦2#土为原料,进行酸化活化,得到酸化杭锦2#土,并进一步以十六烷基三甲基溴化铵作为有机插层剂制备了有机改性杭锦2#土。其FTIR谱图中出现—CH的振动峰,说明插层剂已进入到杭锦2#土层间。再经高温焙烧有机改性杭锦2#土制得介孔杭锦2#土,并应用X射线衍射和扫描电子显微镜对样品进行了晶相和形貌分析,用N2吸附脱附测定其比表面积和孔径,通过傅里叶变换红外光谱和紫外-可见漫反射光谱对样品进行了光谱表征。     

极紫外微通道板光子计数成像探测器性能研究EI北大核心CSCD

基于CE-3极紫外（EUV）相机最高工作温度为70 ℃的要求,对EUV相机的微通道板（MCP）位置灵敏阳极光子计数成像探测器实验件在70 ℃时的性能进行了研究,该探测器主要由工作在脉冲计数模式下的MCP堆、楔条形感应电荷阳极及相关的模拟和数据处理电路组成。为了获得稳定的MCP堆电子增益及较小的暗计数率,对MCP堆进行了预处理,包括380 ℃条件下真空高温烘烤18 h,以及电子清刷100 μA·h,并测量了预处理前后暗计数率;测量了探测器工作在室温和70 ℃时的暗计数率、空间分辨率、增益,测量结果表明探测器的空间分辨率为5.66 lp/mm,与室温下空间分辨率相同,暗计数率虽然小于1 counts/（s·cm2）,但70 ℃暗计数率是室温的2~5倍;对探测器的使用寿命进行了初步分析。实验结果和分析表明探测器在空间分辨率、暗计数率、使用寿命等方面均满足EUV相机的要求。     

双向视ICP-OES法同时测定褐煤中锗和一些主要成灰元素

描述了ICP-OES(高频电感耦合等离子体光学发射光谱)同时测定褐煤中Ge和一些主要成灰元素Fe,Al,Ca,Mg,K,Na,Ti的方法。所使用的仪器是一台安装有双向视等离子体炬管和一个同时检测器的ICP光谱仪,这种技术允许分别在侧视和端视方式下同时测定主成分和微量元素。作者选取了适宜的仪器工作条件、选择了无干扰的分析谱线和合理地扣除了光谱背景,样品灰化后用HNO₃/HF/HClO₄混合酸消解,测定结果与国标方法吻合。仪器的检出限为0.000 39～0.10 μg·mL-1,方法的精密度RSD为0.79%～2.84%,样品平均回收率为92.38%。建立的方法可简便、快速、准确地对褐煤中锗及其他多种元素同时进行测定。     

Frequencies-Selected Enhancement of the Extended High-Order Harmonic Generation Plateau from a United Two-Atom System Irradiated by a Combined Pulse

We present a high-order harmonic generation (HHG) spectrum from a united two-atom system exposed to a combined laser pulse, by numerically solving a one-dimensional time-dependent Schr6dinger equation. The combined laser pulse is composed of a low-frequency femtosecond pulse and a high-frequency attosecond one with respective appropriate amplitudes. For a suitable inter-nuclear separation, the harmonic emission efficiencies near the second cutoff of the extended plateau can be effectively enhanced by more than four orders of magnitude compared with the case of the low-frequency pulse alone. Such a combined pulse irradiating on the united twoatom system ionizes each atom, in a large rate (but not to a too large ionization yield), mainly at a particular time-interval. When the ionized electron from an atom reaches at the vicinity of the other atom and recombines with it, significant HHG enhancement is achieved for particular harmonics. This result, to our knowledge, is one of the best up to now in the endeavor for dramatically extending the width and simultaneously enhancing the height of the plateau.