125Cs的能级结构

通过116Cd(14N,5n),Ebeam=65MeV的核反应布居了125Cs的高自旋态.利用在束γ谱学实验方法,进行了γ-γ符合测量,使已知的125Cs核能级纲图得到了扩展,并且修正了某些组态的带头激发能.High-spin states in odd-A nucleus~(125)Cs have been studied via the~(116)Cd(~(14)N, 5n) reaction at 65 MeV bombarding energy. γ-γ coincidences were recorded with the NORDBALL detector array at Niels Bohr Institute in Denmark. After careful data analysis, most of the previously-known bands have been confirmed and 5 new rotational sequences have been identified. Spin/parity and configuration assignments are tentatively proposed for all of the observed bands. In addition, the bandheads of the 9/2~(+)and (1/2~...     

新试剂3，5－二溴水杨醛苯甲酰腙（DBSBH）与镓配合物的光度法研究

本文用光度法研究了新试剂３，５－二溴水杨醛苯甲酰腙与镓所生成的配合物。选择了最适的萃取条件，用平衡移动法测定了其配合物的组成，即Ｇａ３＋：ＤＢＳＢＨ：ＣｌＯ４＝１：２：１，计算了萃取常数Ｋｅｘ＝１．２６×１０－５，并确定了符合比耳定律的浓度范围。可考虑该试剂作为测定Ｇａ３＋的显色剂。     

Electron Correlation in the Final Continuum of Ionization Hydrogen by 150-eV Electron Impact

Electron correlation in triple differential cross sections for ionization of atomic hydrogen by electron impact is analysed for the case of coplanar asymmetric geometry within the framework of the two-potential formulae. Based on the approximations of projectile and faster-electron plane wave, the transition matrix element is analytically expressed to be a product of two factors: the correlation factor of two electrons in the final channel and the structure-scattering factor. The contribution of both the factors to the angular distribution of the triple differential cross section is calculated. The present results are compared with the experimental data and the other theoretical calculations for the incident energy of 150eV.     

Wave-Front Aberrations of Cornea and Crystalline Lens

The aberrations for anterior corneal surface, posterior corneal surface and complete eyes are measured and calculated. The aberrations for the crystalline lens are obtained by subtracting the aberrations in cornea from that in complete eyes. It is shown that the combination between the crystalline lens and the cornea can be either a compensatory or an additive process. The combination between the anterior and the posterior corneal surfaces on the aberrations is complicated, compensatory or additive. The anterior corneal surface contributes mainly lower-order aberrations （astigmatism） of images, while the posterior corneal surface and the crystalline lens contribute mainly higher-order aberrations.     

显微荧光—阿达玛变换三维图象分析

把阿达玛变换多通道成象技术与荧光显微镜结合起来，首次成功地获得了细胞的阿达玛变换三维荧光图象。该图象能同时提供微小物体中某一物质的含量及分布等信息。     

钯丙烯酸酯络合物的~(13)C NMR谱的研究

用~(13)C NMR、~(31)P NMR谱研究了络合物Pd(mma,)(PMePh_2)_2(Ⅰ)、Pd(ema)(PMePh_2)_2(Ⅱ)中金属与mma、ema间配位状态及溶液中的动态行为。对比了相同配体的Pd、Ni络合物中烯基碳化学位移的变化,研究了中心金属电子反馈能力与络合物稳定性的关系。     

竹红菌甲素光敏氧化吲哚类化合物的研究 I: 关于色氨酸光敏氧化机制的初步探讨

本文利用吸收光谱、荧光光谱和闪光光解研究了竹红菌甲素和色氨酸的相互作用.通过猝灭实验、氘代效应和溶剂效应探讨了竹红菌甲素敏化的色氨酸光氧化机制, 证明该反应是以单重态氧过程为主, 并辅以电子转移的机制. 另外, 考察了反应条件对反应的影响, 发现底物浓度、溶解氧浓度、溶剂的性质和溶液的PH值均对反应有很大的影响.     

竹红菌甲素光敏氧化反应机制

本文报道了在竹红菌甲素的光敏氧化反应中,原初反应产生了~1O_2、O_2~-和H_2O_2,在一些还原性底物(5-羟基色氨酸、色氨酸、组氨酸、蛋氨酸和赖氨酸等)的存在下,体系中形成的O_2~-量大大增加。证明了体系中的~1O_2是通过三重态的竹红菌甲素和基态氧进行能量传递形成的,O_2~-是体系中的竹红菌甲素负离子自由基和基态氧进行单电子转移的结果,H_2O_2是体系中存在的竹红菌甲素二价负离子还原基态氧的产物。在一些底物存在下,次级反应产生了·OH。我们也发现竹红菌甲素具有弱的抽氢能力而生成一些有机自由基,这些有机自由基的形成促进了各种活泼态氧的相互转化,因此我们认为竹红菌甲素的光敏氧化是各种活泼态氧和一些有机自由基综合反应的结果。